Pesticide risk assessment: A study on inhalation and dermal exposure to 2,4-D and paraquat among Malaysian paddy farmers

A cross-section analytical study was conducted to evaluate the risk of pesticide exposure to those applying the Class II pesticides 2,4-D and paraquat in the paddy-growing areas of Kerian, Perak, Malaysia. It investigated the influence of weather on exposure as well as documented health problems commonly related to pesticide exposure. Potential inhalation and dermal exposure for 140 paddy farmers (handlers of pesticides) were assessed. Results showed that while temperature and humidity affected exposure, windspeed had the strongest impact on pesticide exposure via inhalation. However, the degree of exposure to both herbicides via inhalation was below the permissible exposure limits set by United States National Institute of Occupational Safety and Health (NIOSH). Dermal Exposure Assessment Method (DREAM) readings showed that dermal exposure with manual spraying ranged from moderate to high. With motorized sprayers, however, the level of dermal exposure ranged from low to moderate. Dermal exposure was significantly negatively correlated with the usage of protective clothing. Various types of deleterious health effects were detected among users of manual knapsack sprayers. Long-term spraying activities were positively correlated with increasing levels of the gamma-glutamyl transpeptidase (GGT) liver enzyme. The type of spraying equipment, usage of proper protective clothing and adherence to correct spraying practices were found to be the most important factors influencing the degree of pesticide exposure among those applying pesticides.     

A Review on the Present Scenario of Air Quality Associated with Indian Mining Operations

Compositional changes to air quality from coal mining are not only the most visible impact from these activities on the environment, they can also immediately affect the health of mine professionals and adjoining populations. The presence of gases and suspended solids emitted by mining activities affects the human respiratory system and decreases production in mines. This article summarizes a case study of several Northern Coalfields Limited (NCL) coal mines with an emphasis on particulate matter (PM) to report the status of air quality connected to coal production and overburden removal. The concentrations of sulfur dioxide (SO₂), nitrogen oxides (NO_x), and suspended particulate matter (SPM) reported in the literature are also summarized in table form to allow comparisons to the permissible standards set by the Indian Central Pollution Control Board (CPCB) and other standards used around the world. An up‐to‐date status of air quality at coal mines is compared for mines located in different parts of India. Subsequently, all coal mines were divided into different classes in regard to the severity of their emissions. These classes are, in increasing order of severity, green, yellow, red, and black. SPM measurements were tabulated in regard to concentration and composition. Our article concludes with the recommendation that an environmental impact assessment (EIA) to be conducted to better characterize changes in the environment from mining emissions to develop integrated mitigation measures and to identify additional parameters to define air quality at mines.     

Energy consumption and emission projection for the road transport sector in Malaysia: an application of the LEAP model

This study has attempted to estimate the energy consumption and emission of pollutants namely carbon dioxide (CO₂), carbon monoxide (CO), nitrogen oxides (NOx) and non-methane volatile organic compounds (NMVOC) from the road transport sector in Malaysia from the year 2012 till 2040. This was done using the long-range energy alternatives planning (LEAP) model. Estimates of energy consumption and emissions were evaluated and analysed under a business-as-usual scenario and three other alternative fuel policy scenarios of biodiesel vehicles (BIO), natural gas vehicles (NGV) and hybrid electric vehicles (HEV). The aim of this study has been to identify the potential alternative fuel policies that would be effective in reducing the future growth of road transport energy consumption and emission in Malaysia. Results indicate that the NGV scenario contributes towards the highest reduction in road transport energy consumption followed by BIO and HEV. The NGV scenario also achieves highest mitigation of emission of all the four pollutants. In the case of CO₂ emission, BIO scenario attains second highest mitigation, whereas in the event of CO, NOx and NMVOC emission, HEV scenario achieves second highest mitigation.     

Drying of salted silver jewfish in a hybrid solar drying system and under open sun: Modeling and performance analyses

This study investigated the thin-layer drying kinetics of salted silver jewfish in a hybrid solar drying system and under open sun. Ten drying models were compared with experimental data of salted silver jewfish drying. A new model was introduced, which is an offset linear logarithmic (offset modified Page model). The fit quality of the models was evaluated using the coefficient of determination (R²), root mean square error (RMSE), and sum of squared absolute error (SSAE). The result showed that Midilli et al. model and new model were comparable with two or three-term exponential drying models. This study also analyzed energy and exergy during solar drying of salted silver jewfish. Energy analysis throughout the solar drying process was estimated on the basis of the first law of thermodynamics, whereas exergy analysis during solar drying was determined on the basis of the second law of thermodynamics. At an average solar radiation of 540 W/m² and a mass flow rate of 0.0778 kg/sec, the collector efficiency and drying system efficiency were about 41% and 23%, respectively. Specific energy consumption was 2.92 kWh/kg. Moreover, the exergy efficiency during solar drying process ranged from 17% to 44%, with an average value of 31%. The values of improvement potential varied between 106 and 436 W, with an average of 236 W.     

On a combined theory of pay level satisfaction

For decades, research on pay level satisfaction has focused on two theories and one approach: the direct link theory, the discrepancy theory, and the no‐difference‐scores approach. However, there are still unsolved puzzles facing pay level satisfaction research. We develop a combined theory to consider the impact of the interaction of reported pay and pay discrepancy. With this newly developed theory, we expect that (a) both reported pay and pay discrepancy have main effects on pay level satisfaction; (b) reported pay and pay discrepancy also interact with each other, in that the effect of pay discrepancy on pay level satisfaction decreases as pay level increases; (c) equitable payment is more related to pay level dissatisfaction when pay level is low; and (d) overpayment in general is related to pay level satisfaction, not dissatisfaction. An empirical study (N = 481) using four types of comparison standards was conducted, and the results supported our predictions. The findings of our study have important implications for both academic research and management practice.     

Fate of napropamide herbicide in selected Malaysian soils

This study was carried out to determine the sorption-desorption, degradation and leaching of napropamide in selected Malaysian soils. The sorption capacities of the selected Malaysian soils for napropamide were the following in descending order: Linau > Teringkap > Gunung Berinchang > Jambu > Rudua > Baging soil. The results indicate that napropamide degradation decreased with increasing soil sorption capacity. Napropamide was leached out earlier in the Baging soil than the other soils. Overall, the application of napropamide in the selected Malaysian soils would not pose a threat to the environment except in soil with low organic matter and clay content and high hydraulic conductivity, such as the Baging soil.     

Comparison and Verification of Bacterial Water Quality Indicator Measurement Methods Using Ambient Coastal Water Samples

During the summers of 2002 and 2004, in-stream integrated flow and concentration measurements for the total dissolved solids in the Cheyenne River, South Dakota, USA was conducted in order to compare the obtained actual field measurements with the predictions values made by the Bureau of Reclamation in the Environmental Impact Statement. In comparison to the actual field measurements conducted in this study, The Bureau of Reclamation extension of a small database used in the analysis for the impact of operations at the Angostura Unit over the past 50 years and into the future to predict the annual total dissolved solid loadings doesn't represent the actual loading values and various conditions in the study area. Additional integrated flow and concentration sampling is required to characterize the impact of the current Angostura Dam operations and Angostura Irrigation District return flows on the Cheyenne River in different seasons of the year.     

Impact of mining industries on the groundwater level fluctuation in Singrauli coalfield area by using remote sensing and GIS,India

The coal mining industries influence hydro-geological parameters, which affect the aquifer recharge in the coal mining areas. This research aimed to evaluate the impact of various hydro-geological parameters on fluctuation of groundwater level in the study area. The various hydro-geological parameters such as soil, geology, drainage pattern, elevation and slope have been considered to accomplish the objective. A comparative analysis was performed by comparing the groundwater level fluctuation (WLF) map with the GIS-based various hydro-geological parameter maps to assess the combined influence of different hydro-geological parameters on groundwater level fluctuation. A total of eighty-six (86) dug-wells were chosen to monitor the level of the groundwater for around ten blocks of Singrauli coalfield, and these wells were examined during the months of dry and wet seasons for 2016. Based on the comparative analysis between the WLF map and thematic maps of various hydro-geological parameters, it has been found that WLF in the south-western and some portions of the north-eastern showed moderate to a higher value. This may be because most of the non-hilly areas come under gentle to moderate slope category, with lower elevation in the area forming the suitable hydro-geological condition for recharging groundwater. It was observed that the northwest, south-east and central part of the study area showed lower WLF, which may be due to the presence of overburden dump, presence of higher elevation and steep slope. Thus, the combined effect of slope, elevation, geology, drainage and mining activities on the WLF in the study region is moderate.     

Graphene and its derivatives: synthesis,modifications, and applications in wastewater treatment

Graphene was discovered in 2004 and has attracted intensive interests because of its unique mechanical, electric, thermal, optical, and structural properties, which makes graphene a potential candidate for various applications. Graphene is being used as a composite or filler material with metals, metal oxides, and polymers for potential advanced applications in solar cells, lithium-ion batteries, photocatalysis and sensing. These applications depend upon the distinctive properties of graphene, which in turn depend on the adopted synthetic approach. This article reviews the recent developments in synthesis of graphene and related composite materials. The synthesis of graphene through exfoliation, epitaxial growth and direct growth via carbon source, and modification approaches by covalent and noncovalent methodologies are discussed. Graphene-based metal and metal oxide composites for the purification of wastewater using photolytic process are also presented.