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291.
Jasmin Shah M. Rasul Jan Farhat-un-nisa Shehzad Behisht Ara 《Environmental Chemistry Letters》2010,8(3):253-259
A simple spectrophotometric method was developed for determination of trifluralin in commercial formulation and food samples.
The method was based on the hydrolysis of trifluralin with sodium hydroxide to form 2,6-dinitro-4-trifluoromethylaniline.
The resultant aniline group was diazotized with nitrate in acidic media and the diazotized product was coupled with β-naphthol
to form red colored product having λmax 550 nm. The reaction conditions were optimized for hydrolysis as well as for the diazotization reaction. The Beer’s law was obeyed over the range of 0.2–17 μg mL−1 with molar absorptivity of 1.5 × 104 L mol−1 cm−1. The relative standard deviation was found to be 3.6%. A two level factorial design of 23 was used for optimization of all parameters. The influence of different factors and their interactions on the final azo dye
formation were also studied from these factorial designs. The method has been applied successfully for the analysis of commercial
formulations and agricultural samples. The recovery for the determination of trifluralin was found to be in the range 95–97%. 相似文献
292.
Anna Bohman Tina-Simone Neset Tomasz Opach Jan Ketil Rød 《Journal of Environmental Planning and Management》2015,58(12):2193-2211
This study explores the role of geographic visualization for supporting the implementation of climate change adaptation. Interviews and group discussions with planners and decision makers indicate that geographic visualization bears primary potential for communicative purposes. In order to respond to analytical needs a high level of interactivity including the exploration of background data and the ability to link the tools with own databases were some of the key requirements made by the participants. The study concludes that more than better climate predictions, awareness and involvement may be precisely what is needed to narrow the implementation gap in climate change adaptation. 相似文献
293.
Biodiversity–ecosystem functioning experiments (BEF) typically manipulate sown species richness and composition of experimental communities to study ecosystem functioning as a response to changes in diversity. If sown species richness is taken as a measure of diversity and aboveground biomass production as a measure of community functioning, then this relationship is usually found to be positive. The sown species richness can be considered the equivalent of a local species pool in natural communities. However, in addition to species richness, realized diversity is also an important community diversity component. Realized diversity is affected by environmental filtering and biotic interactions operating within a community. As both sown species richness and the realized diversity in BEF studies (as well as local species pool vs observed realized richness in natural communities) can differ markedly, so can their effects on the community functioning. We tested this assumption using two data sets: data from a short-term pot experiment and data from the long-term Jena biodiversity plot experiment. We considered three possible predictors of community functioning (aboveground biomass production): sown species richness, realized diversity (defined as inverse of Simpson dominance index), and survivor species richness. Sown species richness affected biomass production positively in all cases. Realized diversity as well as survivor species richness had positive effects on biomass in approximately half of cases. When realized diversity or survivor species richness was tested together with sown species richness, their partial effects were none or negative. Our results suggest that we can expect positive diversity–productivity relationship when the local species pool size is the decisive factor determining realized observed diversity; in other cases, the shape of the diversity–functioning relationship may be quite opposite. 相似文献
294.
Soil and water conservation (SWC) contests among farmer groups were organized in five rural villages in the Bolivian mountain
valleys. The contests were aimed at quickly achieving widespread sustainable results. This article analyzes the effectiveness
of these contests as an extension tool. Mixed results were obtained. In three villages, participation rates in the SWC activities
introduced in the contests were still high even 2 years after project withdrawal. These were all villages where a solid foundation
for sustainable development had been laid before the contests were held. Two years later, most families were still involved
in maintenance of the SWC practices introduced in the contests, and many farmers had started to experiment with different
soil management practices. However, replications of these SWC practices were not widespread, Conservation Leaders did not
continue with their training activities, and the quality of maintenance of the practices was often not satisfactory. In order
to become a more effective extension tool and achieve widespread impact, SWC contests must receive continued support by a
catalyst agency. Moreover, other SWC contests should also be organized in which practices are not predefined. Given that SWC
contests are a low-budget extension tool, local municipalities could become more actively involved. 相似文献
295.
Danz NP Niemi GJ Regal RR Hollenhorst T Johnson LB Hanowski JM Axler RP Ciborowski JJ Hrabik T Brady VJ Kelly JR Morrice JA Brazner JC Howe RW Johnston CA Host GE 《Environmental management》2007,39(5):631-647
Integrated, quantitative expressions of anthropogenic stress over large geographic regions can be valuable tools in environmental research and management. Despite the fundamental appeal of a regional approach, development of regional stress measures remains one of the most important current challenges in environmental science. Using publicly available, pre-existing spatial datasets, we developed a geographic information system database of 86 variables related to five classes of anthropogenic stress in the U.S. Great Lakes basin: agriculture, atmospheric deposition, human population, land cover, and point source pollution. The original variables were quantified by a variety of data types over a broad range of spatial and classification resolutions. We summarized the original data for 762 watershed-based units that comprise the U.S. portion of the basin and then used principal components analysis to develop overall stress measures within each stress category. We developed a cumulative stress index by combining the first principal component from each of the five stress categories. Maps of the stress measures illustrate strong spatial patterns across the basin, with the greatest amount of stress occurring on the western shore of Lake Michigan, southwest Lake Erie, and southeastern Lake Ontario. We found strong relationships between the stress measures and characteristics of bird communities, fish communities, and water chemistry measurements from the coastal region. The stress measures are taken to represent the major threats to coastal ecosystems in the U.S. Great Lakes. Such regional-scale efforts are critical for understanding relationships between human disturbance and ecosystem response, and can be used to guide environmental decision-making at both regional and local scales. 相似文献
296.
Polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) are a group of halogenated hydrocarbons, comprising 210 different, theoretically possible congeners. They are relatively hydrophobic and persistent to biodegradation, thereby rendering them subject to bioaccumulation. This study was conducted in Frierfjord and Eidangerfjord in the Grenland fjord system, Norway, heavily polluted by PCDD/PCDF discharges from the magnesium production at Herøya from 1951 to 2001. Pooled samples of surface-sediments and the following organisms were collected for the Frierfjord and Eidangerfjord study areas: common shrimp (Crangon crangon), polychaetes (mainly Nereis diversicolor), shore crab (Carcinus maenas), cod (Gadus morhua), flounder (Platichthys flesus), trout (Salmo trutta), herring (Clupea harengus), benthic amphipods and zooplankton. Concentrations of 2,3,7,8-PCDD/Fs were quantified in pooled samples for all species. The relative abundances of stable isotopes of nitrogen (δ15N) were evaluated in the organisms as a measure of chemically-derived trophic level. Contrary to earlier studies on other persistent organochlorines, it was found that the concentrations of PCDD/Fs declined with increasing trophic level. Principal Component Analysis (PCA) also showed differences between species in the pattern of PCDD/Fs. Higher chlorinated congeners constituted lower percentages of the PCDD/F-concentrations higher in the food chain as compared to lower trophic levels. In general, congener patterns did not differ between fjords. Infauna (polychaetes) and zooplankton had congener patterns most similar to the pollution source. The results indicate lower accumulation of higher chlorinated congeners in species at higher trophic levels (fish), presumably due to low membrane permeability (high molecular size) and possibly slow transport through intestinal aqueous phases because of low aqueous solubility. 相似文献
297.
Species of macrofungi (mushrooms) were collected from clean areas and analyzed for their antimony content. These were compared to species collected from extremely polluted areas in the vicinity of a lead smelter and on mine and slag dumps. Antimony content was determined using long-term instrumental neutron activation analysis (INAA). Ectomycorrhizal and terrestrial saprobic macrofungi were examined. Antimony content of macrofungi from the clean areas was mostly less than 100 μg kg−1 (dry mass). The highest concentrations (units of mg kg−1) were found in various species of the ectomycorrhizal genera Chalciporus and Suillus. Antimony contents of macrofungi growing in the polluted areas were considerably higher. The highest content was found in a single collection of Chalciporus piperatus (1423 mg kg−1). 相似文献
298.
A ventricular diameter of 10 mm correlates with more than two standard deviations of the normal and hence is qualified as ventriculomegaly. The relevance of this is dependent on whether there are associated infectious, genetic, or structural problems. The chance for neurodevelopmental delay in isolated ventriculomegaly less than 15 mm is 7.9% (4.7-11.1), and less if it is unilateral. It can be further divided in mild (10-12) or moderate (13-15), though this is not widely accepted. As part of the workup, structural assessment today may include ultrasound or magnetic resonance imaging, or both. Discussants agreed that the diagnostic performance of both methods is as good as the expertise with which the images are acquired and interpreted. Discussants agreed that when the initial neurosonogram is normal, the likelihood of finding significant findings on MRI is low. Nevertheless, some anomalies may only be picked up or better worked out by fetal MRI. In utero follow-up is advocated, as progression may indicate a poorer outcome, and some conditions are only obvious late in pregnancy. Most benefit for future patients is expected from appropriate training in prenatal neuroimaging. 相似文献
299.
300.