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441.
Gas–particle concentration,distribution, and health risk assessment of polycyclic aromatic hydrocarbons at a traffic area of Giza,Egypt 总被引:1,自引:0,他引:1
Atmospheric particulate and gaseous polycyclic aromatic hydrocarbons (PAHs) samples were collected from an urban area in Dokki
(Giza) during the summer of 2007 and the winter of 2007–2008. The average concentrations of PAHs were 1,429.74 ng/m3 in the particulate phase, 2,912.56 ng/m3 in the gaseous phase, and 4,342.30 ng/m3 in the particulate + gaseous phases during the period of study. Dokki has high level concentrations of PAH compounds compared
with many polluted cities in the world. The concentrations of PAH compounds in the particulate and gaseous phases were higher
in the winter and lower in the summer. Total concentrations of PAHs in the particulate phase and gaseous phase were 22.58%
and 77.42% in summer and 36.97% and 63.03% in winter of the total (particulate + gaseous) concentrations of PAHs, respectively.
The gaseous/particulate ratios of PAHs concentration were 3.43 in summer and 1.71 in winter. Significant negative correlation
coefficients were found between the ambient temperature and concentrations of the total PAHs in the particulate and gaseous
phases. The distribution of individual PAHs and different categories of PAHs based on aromatic ring number in the particulate
and gaseous phases during the summer and winter were nearly similar, indicating similar emission sources of PAHs in both two
seasons. Benzo(b)fluoranthene in the particulate phase and naphthalene in the gaseous phase were the most abundant compounds. Diagnostic concentration
ratios of PAH compounds indicate that these compounds are emitted mainly from pyrogenic sources, mainly local vehicular exhaust
emissions. Health risks associated with the inhalation of individual PAHs in particulate and gaseous phases were assessed
on the basis of its benzo(a)pyrene equivalent concentration. Dibenzo(a,h)anthracene and benzo(a)pyrene in the particulate phase and benzo(a)pyrene and benzo(a)anthracene in the gaseous phase were the greatest contributors to the total health risks. The relative mean contributions
of the total carcinogenic activity (concentrations) of all PAHs to the total concentrations of PAHs were 29.37% and 25.15%
in the particulate phase and 0.76% and 0.92% in the gaseous phase during the summer and winter, respectively. These results
suggest that PAHs in the particulate phase in the ambient air of Dokki may pose a potential health risk. 相似文献
442.
Fernandes CE Das A Nath BN Faria DG Loka Bharathi PA 《Environmental monitoring and assessment》2012,184(5):2677-2689
We investigated the influence on bacterial community and biochemical variables through mechanical disturbance of sediment-akin
to small-scale mining in Kalbadevi beach, Ratnagiri, a placer-rich beach ecosystem which is a potential mining site. Changes
were investigated by comparing three periods, namely phase I before disturbance, phase II just after disturbance, and phase
III 24 h after disturbance as the bacterial generation time is ≤7 h. Cores from dune, berm, high-, mid-, and low-tide were
examined for changes in distribution of total bacterial abundance, total direct viability (counts under aerobic and anaerobic
conditions), culturability and biochemical parameters up to 40 cm depth. Results showed that bacterial abundance decreased
by an order from 106 cells g − 1 sediment, while, viability reduced marginally. Culturability on different-strength nutrient broth increased by 155% during
phase II. Changes in sedimentary proteins, carbohydrates, and lipids were marked at berm and dune and masked at other levels
by tidal influence. Sedimentary ATP reduced drastically. During phase III, Pearson’s correlation between these variables evolved
from non-significant to significant level. Thus, simulated disturbance had a mixed effect on bacterial and biochemical variables
of the sediments. It had a negative impact on bacterial abundance, viability and ATP but positive impact on culturability.
Viability, culturability, and ATP could act as important indicators reflecting the disturbance in the system at short time
intervals. Culturability, which improved by an order, could perhaps be a fraction that contributes to restoration of the system
at bacterial level. This baseline information about the potential mining site could help in developing rational approach towards
sustainable harnessing of resources with minimum damage to the ecosystem. 相似文献
443.
Cruceru I Iancu V Petre J Badea IA Vladescu L 《Environmental monitoring and assessment》2012,184(5):2783-2795
A simple, sensitive and reliable HPLC-FLD method for the routine determination of 4-nonylphenol, 4-NP and 4-tert-octylphenol, 4-t-OP content in water samples was developed. The method consists in a liquid–liquid extraction of the target analytes with dichloromethane at pH 3.0–3.5 followed by the HPLC-FLD analysis of the organic extract using a Zorbax Eclipse XDB C8 column, isocratic elution with a mixed solvent acetonitrile/water 65:35, at a flow rate of 1.0 mL/min and applying a column temperature of 40°C. The method was validated and then applied with good results for the determination of 4-NP and 4-t-OP in Ialomi?a River water samples collected each month during 2006. The concentration levels of 4-NP and 4-t-OP vary between 0.08–0.17 μg/L with higher values of 0.24–0.37 μg/L in the summer months for 4-NP, and frequently <0.05 μg/L but also between 0.06–0.09 μg/L with higher values of 0.12–0.16 μg/L in July and August for 4-t-OP and were strongly influenced by sesonial and anthropic factors. The method was also applied on samples collected over 2 years 2007 and 2008 from urban wastewaters discharged into sewage or directly into the rivers by economic agents located in 30 Romanian towns. Good results were obtained when the method was used for analysis of effluents discharged into surface waters by 16 municipal wastewater treatment plants, during the year 2008. 相似文献
444.
Kharroubi A Gargouri D Baati H Azri C 《Environmental monitoring and assessment》2012,184(6):4001-4014
Concentrations of selected heavy metals (Cd, Pb, Zn, Cu, Mn, and Fe) in surface sediments from 66 sites in both northern and
eastern Mediterranean Sea–Boughrara lagoon exchange areas (southeastern Tunisia) were studied in order to understand current
metal contamination due to the urbanization and economic development of nearby several coastal regions of the Gulf of Gabès.
Multiple approaches were applied for the sediment quality assessment. These approaches were based on GIS coupled with chemometric
methods (enrichment factors, geoaccumulation index, principal component analysis, and cluster analysis). Enrichment factors
and principal component analysis revealed two distinct groups of metals. The first group corresponded to Fe and Mn derived
from natural sources, and the second group contained Cd, Pb, Zn, and Cu originated from man-made sources. For these latter
metals, cluster analysis showed two distinct distributions in the selected areas. They were attributed to temporal and spatial
variations of contaminant sources input. The geoaccumulation index (I
geo) values explained that only Cd, Pb, and Cu can be considered as moderate to extreme pollutants in the studied sediments. 相似文献
445.
Impact of socioeconomic development on ecosystem services and its conservation strategies: a case study of Shandong Province,China 总被引:1,自引:0,他引:1
Ecosystems and their components provide a lot of benefits for the welfare of human beings. Coupled with increasing socioeconomic
development, most of the rapidly developing and transitional countries and regions have been experiencing dramatic land use
changes. This has resulted in a large amount of forestland, grassland, and wetland being occupied as residential and industrial
land or reclaimed for arable land, which in turn results in a sharp deterioration of ecosystem services around the world.
Shandong Province, an economically powerful province of China, was chosen as a case study in order to capture the impact of
socioeconomic development on ecosystem services. By way of the study, land uses and their changes were categorized between
1980 and 2006, and the ecosystem services capital and changes of 111 counties of Shandong Province in different phases were
evaluated, as well as the total ecosystem services capital, followed by the zoning of ecosystem services function region of
Shandong Province. We found that the counties in mountainous areas and wetlands, where generally the prefectural-level cities
are located with a rapid socioeconomic development, experienced a successive deterioration of ecosystem services especially
during the 2000s. Finally, three conservation strategies for managing and improving ecosystem services were proposed and discussed
with the aim of achieving coordinate and sustainable development of the socioeconomy, environment, and ecosystems not only
in Shandong Province but also in other provinces of China, as well as in other developing and transitional countries and regions. 相似文献
446.
Chen B Pan Y Wang J Fu Z Zhang Y Zhou Y 《Environmental monitoring and assessment》2012,184(6):3545-3556
Evenly distributed sampling design is generally considered as an efficient sampling design. It is widely used in sampling
for the environmental survey. In this paper, we present a novel method for generating N evenly distributed samples within a given irregular polygon via simulating the movements of some ideal homogeneous point
charges. Initially, charges are randomly put into the sampling region; then, they are freed and held orderly; and after enough
runs, the charges will finally reach a stable state with all of them having a zero resultant force and velocity; and so they
distribute evenly within the region. Their layout can thus be considered as an evenly distributed sampling design. The main
advantages of this method are: (1) it is easy to understand and implement; (2) it is efficient in both running and generating
better designs. Analysis and experimental results indicate that this method is an efficient and robust method for generating
even sampling designs for 2D polygonal sampling region. 相似文献
447.
Smederevac-Lalić M Pešić R Cvejić S Simonović P 《Environmental monitoring and assessment》2012,184(5):2633-2646
The multidisciplinary socio-economic study of fisheries in the bordering part of the Danube River between Serbia and Croatia (at the following sites: Apatin, Ba?ka Palanka, Ba?ko Novo Selo, Bezdan, and Sombor) that was performed in order to investigate various aspects of fish resource utilization (management, policy of protection and exploitation of freshwater fishery resources, present fisheries legislation, catch statistics), was realized during 2004 and 2005. Data were collected via survey with a structured interview. Socio-economic circumstances, together with ecological factors, have had an influence on the fish stock and number of commercial fishermen. Awareness of the occurring problems, both economic and ecological ones, is apparent, regardless of whether it is assessed in the field of commercial or recreational fishing. Fishery sector in Serbia is in a prolonged process of transition, with the enforcement of fishing regulations, but also the lack of control that leaves space for illegal commercial fishing. The statements, consciousness, experience and behavior of commercial fishermen represent a good basis for planning the sustainable development of fishing in this section of the Danube River. 相似文献
448.
Characterizing hydrochemical properties of springs in Taiwan based on their geological origins 总被引:1,自引:0,他引:1
This study was performed to characterize hydrochemical properties of springs based on their geological origins in Taiwan.
Stepwise discriminant analysis (DA) was used to establish a linear classification model of springs using hydrochemical parameters.
Two hydrochemical datasets—ion concentrations and relative proportions of equivalents per liter of major ions—were included
to perform prediction of the geological origins of springs. Analyzed results reveal that DA using relative proportions of
equivalents per liter of major ions yields a 95.6% right assignation, which is superior to DA using ion concentrations. This
result indicates that relative proportions of equivalents of major hydrochemical parameters in spring water are more highly
associated with the geological origins than ion concentrations do. Low percentages of Na + equivalents are common properties of springs emerging from acid-sulfate and neutral-sulfate igneous rock. Springs emerging
from metamorphic rock show low percentages of Cl − equivalents and high percentages of HCO3-_{3}^{-} equivalents, and springs emerging from sedimentary rock exhibit high Cl − /SO42-_{4}^{2-} ratios. 相似文献
449.
Rai PK 《Environmental monitoring and assessment》2012,184(1):113-131
The present article provides a multifaceted critical research review on environmental issues intimately related with the socio-economy
of North East India (NE), a part of Indo-Burma hotspot. Further, the article addresses the issue of sustainable development
of NE India through diverse ecological practices inextricably linked with traditional ecological knowledge (TEK). The biodiversity
of NE India comprises endemic floral diversity, particularly medicinal plants of importance to pharmaceutical industry, and
unique faunal diversity. Nevertheless, it is very unfortunate that this great land of biodiversity is least explored taxonomically
as well as biotechnologically, probably due to geographical and political constraints. Different anthropogenic and socio-economic
factors have perturbed the pristine ecology of this region, leading to environmental degradation. Also, the practice of unregulated
shifting cultivation (jhooming), bamboo flowering, biological invasions and anthropogenic perturbations to biodiversity exacerbate the gloomy situation.
Instead of a plethora of policies, the TEK of NE people may be integrated with modern scientific knowledge in order to conserve
the environment which is the strong pillar for socio-economic sector here. The aforesaid approach can be practiced in NE India
through the broad implementation and extension of agroforestry practices. Further, case studies on Apatanis, ethnomedicinal plants use by indigenous tribal groups and sacred forests are particularly relevant in the context of conservation
of environmental health in totality while addressing the socioeconomic impact as well. In context with the prevailing scenarios
in this region, we developed an eco-sustainable model for natural resource management through agroforestry practices in order
to uplift the social as well as environmental framework. 相似文献
450.
Characteristics of aerosol types during large-scale transport of air pollution over the Yellow Sea region and at Cheongwon,Korea, in 2008 总被引:1,自引:0,他引:1
Episodes of large-scale transport of airborne dust and anthropogenic pollutant particles from different sources in the East
Asian continent in 2008 were identified by National Oceanic and Atmospheric Administration satellite RGB (red, green, and
blue)-composite images and the mass concentrations of ground level particulate matter. These particles were divided into dust,
sea salt, smoke plume, and sulfate by an aerosol classification algorithm. To analyze the aerosol size distribution during
large-scale transport of atmospheric aerosols, aerosol optical depth (AOD) and fine aerosol weighting (FW) of moderate imaging
spectroradiometer aerosol products were used over the East Asian region. Six episodes of massive airborne dust particles,
originating from sandstorms in northern China, Mongolia, and the Loess Plateau of China, were observed at Cheongwon. Classified
dust aerosol types were distributed on a large-scale over the Yellow Sea region. The average PM10 and PM2.5 ratio to the total
mass concentration TSP were 70% and 15%, respectively. However, the mass concentration of PM2.5 among TSP increased to as
high as 23% in an episode where dust traveled in by way of an industrial area in eastern China. In the other five episodes
of anthropogenic pollutant particles that flowed into the Korean Peninsula from eastern China, the anthropogenic pollutant
particles were largely detected in the form of smoke over the Yellow Sea region. The average PM10 and PM2.5 ratios to TSP
were 82% and 65%, respectively. The ratio of PM2.5 mass concentrations among TSP varied significantly depending on the origin
and pathway of the airborne dust particles. The average AOD for the large-scale transport of anthropogenic pollutant particles
in the East Asian region was measured to be 0.42 ± 0.17, which is higher in terms of the rate against atmospheric aerosols
as compared with the AOD (0.36 ± 0.13) for airborne dust particles with sandstorms. In particular, the region ranging from
eastern China, the Yellow Sea, and the Korean Peninsula to the Korea East Sea was characterized by high AOD distributions.
In the episode of anthropogenic polluted aerosols, FW averaged 0.63 ± 0.16, a value higher than that in the episode of airborne
dust particles (0.52 ± 0.13) with sandstorms, showing that fine anthropogenic pollutant particles contribute greatly to atmospheric
aerosols in East Asia. 相似文献