Adsorption and transport of arsenic(V) in experimental subsurface systems

The adsorption and transport of As(V) in a heterogeneous, iron oxide-containing soil was investigated in batch and column laboratory experiments. The As(V) adsorbed rapidly to the soil over the first 48 h, but continued to adsorb slowly over the next several weeks, clearly indicating the potential for rate-limited transport. The equilibrium As(V) adsorption isotherm was markedly nonlinear, further indicating the potential for nonideal transport. A model developed for the adsorption of As(V) to hydrous ferric oxide (HFO) was able to predict the pH-dependent adsorption of As(V) to the soil in batch experiments within 0.116 to 0.726 root mean square error (RMSE). Arsenic(V) was significantly retarded in column transport experiments. The column transport experiments were modeled using the one-dimensional advection-dispersion equation, considering both linear and nonlinear adsorption equilibrium. Although the nonlinear local equilibrium model (NLLE, RMSE = 0.273) predicted the data better than the linear local equilibrium model (LLE, RMSE = 0.317), As(V) breakthrough occurred more rapidly than predicted by either model due to adsorption nonequilibrium. However, due to the presence of an irreversible or slowly desorbing fraction, the peak aqueous As(V) concentration (0.624 mg L(-1)) and the total amount of As(V) recovered (44%) was lower than predicted based on the two equilibrium models (NLLE and LLE). For the conditions used in this study [1 mg L(-1) As(V), pH 4.5 and 9,0-0.25 mM PO4, 0.53-1.6 cm min(-1) pore water velocity], the effect on As(V) mobility and recovery increased in the order pH < pore water velocity < PO4.     

Risk assessment of chromium and arsenic in date palm leaves used as livestock feed

Appreciable levels of total chromium (Cr) and arsenic (As) were found (by emission spectroscopy) in date palm leaves, which form a significant ingredient in livestock feed. The levels in the fruit were considered safe for human consumption. Our work involved evaluation of the distribution of these elements in the leaves during the developmental stages of the fruiting season. Thirty-six leaf specimens of the Fard cultivar were collected 9, 15 and 20 weeks, respectively, after pollination and subjected to a standard digestion procedure. Sample masses of typically 1 g (dry weight) were prepared in 25 ml dilute acid solution and investigated for trace levels of Cr and As by ICP-AES. Eleven soil samples collected at random during the growth stages were subjected to a similar digestion procedure and analysis. According to the literature, the permissible mean levels of Cr and As in plants are 200 and 80 ng/g (dry weight), respectively. We used these values as our guideline to assess the "risk" levels in our samples of interest. In the case of Cr, about 45% of the specimens possessed levels between 250 and 700 ng/g, while a significant number produced levels between 1000 and 5000 ng/g. With regard to As, about 70% of the samples were above the documented permissible mean value. As a result of the unusually high Cr concentrations in some cases, the feasibility of Cr "accumulation" in the leaves was examined. Insects and other organisms subsist on the leaves and an added concern was the accumulation of these elements in the food chain. The study formed an interesting contribution to environmental research, and the impact of our assessment on the environment is discussed.     

Responsibility of drivers, by age and gender, for motor-vehicle crash deaths

Problem: Motor-vehicle crash rate comparisons by age and gender usually are based on the extent to which drivers in a particular age/gender category are themselves injured or involved in crashes (e.g., the number of 20-year-old females in crashes). Basing comparisons instead on the extent to which drivers in various age/gender groups are responsible for deaths (including themselves) in their crashes is more revealing of their overall contribution to the problem. Methods: Data from the Fatality Analysis Reporting System (FARS, 1996–2000) were used in the analysis, which was based on crashes that involved one or two vehicles only. Drivers in fatal single-vehicle crashes were assumed to have responsibility for the crash. In fatal two-vehicle crashes, driver operator errors reported by police were used to assign crash responsibility. Results: When all crashes were considered, both the youngest and oldest drivers were most likely to be responsible for deaths in their crashes. In two-vehicle crashes, the oldest drivers were more likely than young drivers to be responsible. Young males were more likely than young females to be responsible for crash deaths, whereas females in their 50s and older were more likely than same-age males to be responsible. In terms of responsibility for deaths per licensed driver, young drivers, especially males, had the highest rates because of their high involvement rates and high responsibility rates. The majority of deaths for which young drivers were responsible occurred to people other than themselves, especially passengers in their vehicles, whereas the bulk of the deaths for which older drivers were responsible were their own. Discussion: The results highlight the contribution of young drivers to the motor-vehicle crash problem, the need for measures such as passenger restrictions in graduated licensing systems, and the need for vehicle modifications to better protect older occupants.     

NITROGEN AND PHOSPHORUS CONCENTRATIONS IN FOREST STREAMS OF THE UNITED STATES1

ABSTRACT: Seventy to eighty percent of the water flowing in rivers in the United States originates as precipitation in forests. This project developed a synoptic picture of the patterns in water chemistry for over 300 streams in small, forested watersheds across the United States. Nitrate (NO₃^?) concentrations averaged 0.31 mg N/L, with some streams averaging ten times this level. Nitrate concentrations tended to be higher in the northeastern United States in watersheds dominated by hardwood forests (especially hardwoods other than oaks) and in recently harvested watersheds. Concentrations of dissolved organic N (mean 0.32 mg N/L) were similar to those of NO₃～, whereas ammonium (NH₄⁺) concentrations were much lower (mean 0.05 mg N/L). Nitrate dominated the N loads of streams draining hardwood forests, whereas dissolved organic N dominated the streams in coniferous forests. Concentrations of inorganic phosphate were typically much lower (mean 12 mg P/L) than dissolved organic phosphate (mean 84 mg P/L). The frequencies of chemical concentrations in streams in small, forested watersheds showed more streams with higher NO₃^? concentrations than the streams used in national monitoring programs of larger, mostly forested watersheds. At a local scale, no trend in nitrate concentration with stream order or basin size was consistent across studies.     

Defining acceptable conditions in wilderness

The limits of acceptable change (LAC) planning framework recognizes that forest managers must decide what indicators of wilderness conditions best represent resource naturalness and high-quality visitor experiences and how much change from the pristine is acceptable for each indicator. Visitor opinions on the aspects of the wilderness that have great impact on their experience can provide valuable input to selection of indicators. Cohutta, Georgia; Caney Creek, Arkansas; Upland Island, Texas; and Rattlesnake, Montana, wilderness visitors have high shared agreement that littering and damage to trees in campsites, noise, and seeing wildlife are very important influences on wilderness experiences. Camping within sight or sound of other people influences experience quality more than do encounters on the trails. Visitors’ standards of acceptable conditions within wilderness vary considerably, suggesting a potential need to manage different zones within wilderness for different clientele groups and experiences. Standards across wildernesses, however, are remarkably similar.     

Lake management techniques in Florida,USA: Costs and water quality effects

Economic evaluations of restored or enhanced lakes in Florida indicated gravity drawdown was the least expensive action, whereas effluent diversion was 10,000 times more costly on a per hectare basis, with the other lake treatment costs occurring in the following order: gravity drawdown < grass carp introduction < mechanical drawdown < aeration < stormwater control = drawdown-dredging < effluent diversion. Within a particular treatment category, the costs spanned approximately one and one half orders of magnitude. Contrary to the abundant cost data, which permitted an economic analysis, inappropriate statistical design and lack of commitment toward sampling Florida's restored lakes undermines attempts to understand long-term water quality responses to various enhancement techniques. Using Lake Tohopekaliga as a case study, ordinary statistical tests produced contradictory and unreliable interpretations on the effectiveness of drawdown and phosphorus removal at sewage treatment plants in improving the trophic state index. This emphasizes the need for more robust statistical approaches and more detailed data collection in evaluating lake restoration activities It is unfortunate for Florida's lake restoration program that quantitative conclusions based on inferential statistics, replete with tests of assumptions, is limited to very few lakes     

GROUND WATER FLOW AND RUNOFF IN A COASTAL PLAIN STREAM1

ABSTRACT: The quantity, seasonality, and sources of flow were analyzed for two segments of Four Mile Branch, a small stream on the Coastal Plain of South Carolina using data obtained from USGS gauging stations. Flows in the “upstream segment,” a 12.6-km² watershed comprising the head waters of Four Mile Branch, averaged 0.129 m³ s^?1 and showed a distinctly seasonal pattern, with maximum flows in February and March and minimum flows in September and October. Inflow to the “downstream segment,” a 2.2-km² watershed associated with the main channel, averaged 0.059 m³ s^?1 and showed no seasonal patterns. Discharges per unit area of watershed were greater for the downstream segment, 0.83 m³ per year per m² of land surface, than for the upstream segment, 0.32 m³ per year per m². The differences in discharge rates and seasonalities between the two segments reflect differences in aquifers supplying the different segments. Analyses of Streamflow by hydrograph separation and Streamflow partitioning methods indicated that greater than 90 percent of the flows in the upstream and downstream segments were due to ground water-driven base flows.     

Energy planning and wood balances

Woodfuel balances are commonly used by energy planners in developing countries to determine the adequacy of woodfuel resources. Recently, critics have argued that wood balances are misleading in their simplicity, exaggerating both the severity of the woodfuel shortage and the need for planned interventions to solve that problem. This paper examines four different wood balances developed for Tanzania. While the four studies all indicate that areas with miombo woodlands are in the greatest wood surplus, the specific estimates for any given region may differ widely. Despite their shortcomings, energy planners need woodfuel balances to give an impression of the adequacy of woodfuel resources. However, if energy planning is to have any effect, these balances must represent the beginning, and not the end result, of the planning process. Planners must follow the wood-energy balance analysis with work utilizing local people to solve local problems.     

Belief-bias and labor unions: The effect of strong attitudes on reasoning

This study compared three types of reasoning bias associated with strong belief: Judgement of plausibility, contrast effects, and social attribution. Respectively, these relate to bias in the perceived validity and extremity of statements and bias in causal interpretations of actions. Technical college students (N = 153) in two highly unionized communities completed one scale for each form of bias and a section of the IRC Union Attitude Scale which measured their attitude toward unions. Belief–bias was indicated across all three measures although there were differences in their salience. Social attribution was the strongest type of bias manifested (r = 0.58, p ? 0.001) and contrast effects (r = 0.33, p ? 0.001) were a second and third. The implications of these results are explored and future research directions in this new line of study are suggested.     

Some psychological consequences of striking: A six month,longitudinal study

The literature available on organizational psychology has largely neglected the issue of industrial conflict, and little is known about individual psychological effects of industrial conflict such as labour disputes and strikes. Psychological consequences of involvement in a strike were assessed in this research. Data were collected from 117 full-time, white collar union members immediately following a 22 day strike, and again two and six months later. Negatively perceived industrial relations events (e.g. 'strike or lockout', 'being involved in negotiations') were associated with marital adjustment, psychosomatic symptoms and a lack of psychological well-being on completion of the strike, and predicted unfavourable changes in psychological well-being over the next two and six months. A framework for understanding the negative effects of labour disputes and strikes is proposed, and the role of the organizational psychologist when such conflicts occur is considered.