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排序方式: 共有111条查询结果,搜索用时 15 毫秒
21.
Visser A Kroes J T H van Vliet M Blenkinsop S Fowler HJ Broers HP 《Journal of contaminant hydrology》2012,127(1-4):47-64
The Keersop catchment (43km(2)) in the south of The Netherlands has been contaminated by the emissions of four zinc ore smelters. The objective of this study was to assess the effects of future projected climate change on the hydrology and the leaching of heavy metals (i.e. Cd and Zn) in the catchment. The numerical, quasi-2D, unsaturated zone Soil Water Atmosphere Plant model was used with 100-year simulated daily time series of precipitation and potential evapotranspiration. The time series are representative of stationary climates for the periods 1961-1990 ("baseline") and 2071-2100 ("future"). The time series of future climate were obtained by downscaling the results of eight regional climate model (RCM) experiments, driven by the SRES A2 emissions scenario, using change factors for a series of climate statistics and applying them to stochastic weather generator models. The time series are characterized by increased precipitation in winter, less precipitation in summer, and higher air temperatures (between 2°C and 5°C) throughout the year. Future climate scenarios project higher evapotranspiration rates, more irrigation, less drainage, lower discharge rates and lower groundwater levels, due to increased evapotranspiration and a slowing down of the groundwater system. As a result, lower concentrations of Cd and Zn in surface water are projected. The reduced leaching of heavy metals, due to drying of the catchment, showed a positive impact on a limited aspect of surface water quality. 相似文献
22.
Degradation of ethinyl estradiol by nitrifying activated sludge 总被引:26,自引:0,他引:26
Vader JS van Ginkel CG Sperling FM de Jong J de Boer W de Graaf JS van der Most M Stokman PG 《Chemosphere》2000,41(8):1239-1243
Degradation of ethinyl estradiol (EE2) by nitrifying activated sludge was studied with micro-organisms grown in a reactor with feedback of sludge fed with only a mineral salts medium containing ammonium as the sole energy source. Ammonium was oxidised by this sludge at a rate of 50 mg NH4+ g(-1) DW h(-1). This activated sludge was also capable of degrading EE2 at a maximum rate of 1 microg g(-1) DW h(-1). Using sludge with an insignificant nitrifying capacity of 1 mg NH4+ g(-1) DW h(-1), no degradation of EE2 was detected. Oxidation of EE2 by nitrifying sludge resulted in the formation of hydrophilic compounds, which were not further identified. Most probably degradation by nitrifying sludge results in a loss of estrogenic activity, as hydroxylated derivatives of EE2 are known to have a substantially lower pharmacological activity than EE2. 相似文献
23.
Th. A. de Boer 《Environmental monitoring and assessment》1983,3(3-4):375-380
Composition of the vegetation and the properties of its environment are related, as was shown by research. In these, mostly statistical-correlative studies, both the vegetation and some growth factors, such as plant nutrients and moisture supply were analyzed and studied on interdependence. At present the environmental conditions can be estimated in the field from the floristic composition with regard to differences both in the combination of plant species and in their relative biomass production. With a vegetation survey the spatial pattern of the different environmental conditions can be indicated. For instance, the places where moisture supply gradients occur can be detected, also a better understanding is obtained of the environmental equalization and the decreasing number of plant species and spatial diversity. Conclusions can be drawn about changes in the vegetation to be expected, from the combined occurrence of, a terrestrial vegetation indicating an eutrofied environment and a water vegetation indicating a relatively oligotrophic environment. By comparing vegetation recordings of the past and present, environmental changes that have occurred in the same place can be indicated. By vegetations situated in different places in relation with soil profile properties the consequences of environmental changes can be predicted. For instance, lowering of the ground water table and intensifying the agricultural use. On the other hand, measures can be suggested to increase the biological value of land and water, for instance, indication of seepage areas and floristically rich areas in the field. 相似文献
24.
Rachèl V. van Schendel G. C. Page-Christiaens Lean Beulen Catia M. Bilardo Marjon A. de Boer Audrey B. C. Coumans Brigitte H. Faas Irene M. van Langen Klaske D. Lichtenbelt Merel C. van Maarle Merryn V. E. Macville Dick Oepkes Eva Pajkrt Lidewij Henneman for the Dutch NIPT Consortium 《黑龙江环境通报》2016,36(12):1091-1098
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Angélique C. Belfroid Willem Scinen Kees C. A. M. van Gestel Joop L. M. Hermens Kees J. van Leeuwen 《Environmental science and pollution research international》1995,2(1):5-15
In this paper a method is developed which can be used to estimate the body burden of organic hydrophobic chemicals in earthworms. In contrast to the equilibrium partitioning theory, two routes of uptake are incorporated: uptake from interstitial water and dietary uptake. Although many uncertainties still remain, calculations show that for earthworms steady state body burdens are mainly determined by uptake from interstitial water. Under most circumstances, the contribution of dietary uptake is small, except for hydrophobic chemicals (log Kow > 5) in soils with a high organic matter (OM) content of ≈ 20 %. Under those conditions, estimates of the steady state body burden calculated with the equilibrium partitioning model, in which only uptake from interstitial water is taken into account, might result in a small underestimation of the real body burden of chemicals in earthworms. 相似文献
28.
Eric M. J. Verbruggen Willem M. G. M. van Loon Joop L. M. Hermens 《Environmental science and pollution research international》1996,3(3):163-168
Hydrophobicity is an important property in risk assessment of chemicals. A group parameter that reflects the hydrophobicity of technical mixtures is not yet available. However, many substances are complex organic mixtures, for which it is practically impossible to determine each component separately. An experimental procedure to measure the hydrophobicity of organic mixtures without knowledge of the individual components was developed and tested for a mixture of benzene and twelve chlorobenzenes. This procedure is based on separation of the mixture into fractions of increasing hydrophobicity by reversed-phase HPLC, after which the total molar concentration in each fraction is determined by vapour pressure osmometry. The obtained information on hydrophobicity can be used for assessing bioaccumulation and sediment sorption after emission of the mixture to water has occurred. 相似文献
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Steven T.J. Droge Joop L.M. Hermens 《Environmental pollution (Barking, Essex : 1987)》2010,158(10):3116-3122
Mineral surfaces form the main sorption phase for alcohol ethoxylates (AEs) in marine sediment. Competition for adsorption sites is investigated for marine sediment and kaolinite clay using simple mixtures of AE homologues. For both sorbents, adsorption sites on mineral surfaces can be effectively blocked by an AE homologue with the strongest adsorption affinity. The strongly adsorbed AE, however, forms a second sorption phase to which weakly adsorbing AE will sorb, forming bilayers. An extended dual-mode model accounts for competition effects, while still based on sorption properties of individual compounds. Competition effects become apparent when total adsorbed concentrations reach ∼10% of the adsorption capacity. Deviations from individual sorption isotherms depend on affinity constants and dissolved homologue composition. Competition will not often occur in contaminated field sediments, with AEs concentrations usually far below the adsorption capacity, but will affect sorption studies, sediment toxicity tests or applications with nonionic surfactant mixtures. 相似文献