Distraction in older drivers - A face-to-face interview study

The prevalence of older drivers’ engagement in distracting activities while driving is largely unexplored. Face-to-face interviews were conducted in the city of Braunschweig, Germany, comparing a sample of older drivers (n = 205) to a group of middle-aged drivers (n = 209). The drivers were interviewed on their engagement in distracting activities during the last half an hour of their driving trip, including the frequency and duration of these activities, their perception of the risk associated with these distracting activities and the role of these activities in at-fault crashes. Middle-aged drivers were significantly more likely to engage in certain distracting activities than older drivers. With regard to the duration of interactions with the passengers older drivers were significantly more talkative than middle-aged drivers. Middle-aged drivers rated most of the distracting activities as significantly less dangerous than older drivers. Distraction-related crashes are not a special problem of older drivers but seem to be very comparable to the middle-aged drivers. It is concluded that older drivers’ reluctance to engage in distracting tasks while driving is either a process of self-regulation or their age-related prudence. The study is the first to gather knowledge about distraction in German older drivers. Although older drivers are not currently overrepresented in distraction-related crashes, it is important to note that future cohorts of older drivers might differ in the way they engage with vehicles and technologies, which in turn may influence their driving patterns and willingness to engage in potentially distracting activities.     

新疆孔雀河表层沉积物中有机氯农药的分布及风险评价

分析了新疆孔雀河9个表层沉积物样品中22种有机氯农药(OCPs)含量,其主要OCPs含量的顺序为:六六六>异狄氏剂醛>滴滴涕>艾氏剂>硫丹Ⅱ>异狄氏剂>氯丹.研究表明,近期有γ-HCH输入到孔雀河,其最可能的来源是博斯腾湖的补给或孔雀河附近的农业回流水.滴滴涕的组成特征分析表明,DDTs主要源于施用的农药在好氧环境土壤中的分解,产生DDE等主要产物.风险评价表明,污染物的风险较低,所有被评估的OCPs的风险值均小于风险评价高限(ERM).     

A review of the health impacts of barium from natural and anthropogenic exposure

There is an increasing public awareness of the relatively new and expanded industrial barium uses which are potential sources of human exposure (e.g., a shale gas development that causes an increased awareness of environmental exposures to barium). However, absorption of barium in exposed humans and a full spectrum of its health effects, especially among chronically exposed to moderate and low doses of barium populations, remain unclear. We suggest a systematic literature review (from 1875 to 2014) on environmental distribution of barium, its bioaccumulation, and potential and proven health impacts (in animal models and humans) to provide the information that can be used for optimization of future experimental and epidemiological studies and developing of mitigative and preventive strategies to minimize negative health effects in exposed populations. The potential health effects of barium exposure are largely based on animal studies, while epidemiological data for humans, specifically for chronic low-level exposures, are sparse. The reported health effects include cardiovascular and kidney diseases, metabolic, neurological, and mental disorders. Age, race, dietary patterns, behavioral risks (e.g., smoking), use of medications (those that interfere with absorbed barium in human organism), and specific physiological status (e.g., pregnancy) can modify barium effects on human health. Identifying, evaluating, and predicting the health effects of chronic low-level and moderate-level barium exposures in humans is challenging: Future research is needed to develop an understanding of barium bioaccumulation in order to mitigate its potential health impacts in various exposured populations. Further, while occupationally exposed at-risk populations exist, it is also important to identify potentially vulnerable subgroups among non-occupationally exposed populations (e.g., elderly, pregnant women, children) who are at higher risk of barium exposure from drinking water and food.     

E‐waste in the world today: An overview of problems and a proposal for improvement in Brazil

Environmental issues have been at the center of society's concerns for a long time. Recently, this kind of concern is growing even more due to the damage caused to the environment by electrical and electronic product waste. Based on this same concern, this work aimed to analyze, through a literature review, the production and treatment of electronic waste in today's world, with an emphasis on Brazil and China. The articles reviewed point to an increase in the production of this type of waste, in both Brazil and China, and reveal that the current processes of treatment of electronic waste mostly aim to obtain profit through the recovery of precious metals such as copper. This paper concluded that although Brazil is one of the major producers of e‐waste, more than 90% of its e‐waste has not had a proper final destination. This deficiency in e‐waste treatment in Brazil is mainly due to financial factors and the lack of a robust educational policy focused on the environment. Thus, this work suggests the implementation of an effective educational policy aimed at environmental conservation, as well as investments in research on recycling methods in Brazil, especially on the use of e‐waste as an aggregate in the manufacture of concrete.     

High-resolution mass spectrometry analysis of secondary organic aerosol generated by ozonolysis of isoprene

The chemical composition of secondary organic aerosol (SOA) generated from the ozonolysis of isoprene (C₅H₈) in the presence of an OH scavenger was examined using high-resolution electrospray ionization mass spectrometry (ESI-MS) in the mass range m/z = 50–1000. The chemical composition of SOA is complex, with more than 1000 assigned peaks observed in the positive and negative ion mode spectra. Only a small fraction of peaks correspond to known products of isoprene oxidation, such as pyruvic acid, glycolic acid, methylglyoxal, etc. The absolute majority of the detected peaks correspond to highly oxidized oligomeric constituents of SOA, with an average O:C molar ratio of 0.6. The corresponding organic mass (OM) to organic oxygen (OO) ratio is 2.4. Approximately 8% of oxygen atoms in SOA are in the form of peroxides, as quantified with an iodide test. Double bond equivalency (DBE) factors, representing the sum of all double bonds and rings, increase by 1 for every 1–2 additional carbon atoms in the molecule. The number of unoxidized CC double bonds is estimated to be less than 10%; the remaining DBE is due to CO carbonyl groups. Kendrick analysis suggests that the prevalent oligomer building blocks are small carbonyls with a C₁–C₂ skeleton. Formaldehyde (CH₂O) is identified as the most common repetitive building block in the observed oligomeric compounds.     

Disaggregated contributions of ecosystem services to human well-being: a case study from Eastern Europe

Aggregated analyses of the benefits from ecosystem services (ES) to well-being neglect important differences among beneficiaries and fail to capture the complexity of factors that mediate the ES–well-being relationship. Based on 25 group interviews, we disaggregated the ES–well-being relationships across six groups of potential beneficiaries in a farming landscape in central Romania, Eastern Europe. We explored what mediates distributional patterns of needs and benefits among beneficiaries and identified six contextual factors: (1) characteristics of the appropriated ES; (2) policies, formal institutions, and markets; (3) social and power relations, and informal institutions; (4) household decisions and individual contexts; (5) different perceptions and understandings of equity; and (6) individually held values. Based on these empirically derived factors, we developed a conceptual model of mediating factors that holistically takes into account the contextual space between ES and human beneficiaries. This model provides a framework for unpacking ES–well-being relationships that may guide ES research across varying socioeconomic cases. Notably, this model of mediating factors incorporates an equity perspective that is more refined than the dominant discourse on the relation between poverty and ES (which typically emphasizes that poor people are most dependent on ES, but neglects factors such as power relations and held values). Recognizing multiple contextual factors that shape the contribution of ES to well-being opens doors for harnessing new interdisciplinary collaborations and can help to inform more holistic policy interventions.     

Thermal decomposition of electronic wastes: mobile phone case and other parts

Pyrolysis and combustion runs at 850°C in a horizontal laboratory furnace were carried out on different parts of a mobile phone (printed circuit board, mobile case and a mixture of both materials). The analyses of the carbon oxides, light hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), polychlorodibenzo-p-dioxin, polychlorodibenzofurans (PCDD/Fs), and dioxin-like PCBs are shown. Regarding semivolatile compounds, phenol, styrene, and its derivatives had the highest yields. In nearly all the runs the same PAHs were identified, naphthalene being the most common component obtained. Combustion of the printed circuit board produced the highest emission factor of PCDD/Fs, possibly due to the high copper content.     

Elemental analysis of printed circuit boards considering the ROHS regulations

The EU RoHS Directive (2002/95/EC of the European Parliament and of the Council) bans the placing of new electrical and electronic equipment containing more than agreed levels of lead, cadmium, mercury, hexavalent chromium, polybrominated biphenyl (PBB) and polybrominated diphenyl ether (PBDE) flame retardants on the EU market. It necessitates methods for the evaluation of RoHS compliance of assembled electronic equipment. In this study mounted printed circuit boards from personal computers were analyzed on their content of the three elements Cd, Pb and Hg which were limited by the EU RoHS directive. Main focus of the investigations was the influence of sample pre-treatment on the precision and reproducibility of the results. The sample preparation steps used were based on the guidelines given in EN 62321. Five different types of dissolution procedures were tested on different subsequent steps of sample treatment like cutting and milling. Elemental analysis was carried out using ICP-OES, XRF and CV-AFS (Hg). The results obtained showed that for decision-making with respect to RoHS compliance a size reduction of the material to be analyzed to particles ?1.5 mm can already be sufficient. However, to ensure analytical results with relative standard deviations of less than 20%, as recommended by the EN 62321, a much larger effort for sample processing towards smaller particle sizes might be required which strongly depends on the mass fraction of the element under investigation.     

Temporal Analysis of Airborne Particulate Matter Reveals a Dose-Rate Effect on Mortality in El Paso: Indications of Differential Toxicity for Different Particle Mixtures

Abstract

One of two topics explored is the limitations of the daily average in summarizing pollutant hourly profiles. The daily average of hourly measurements of air pollutant constituents provides continuity with previous studies using monitoring technology that only provided the daily average. However, other summary statistics are needed that make better use of all available information in 24-hr profiles. The daily average reflects the total daily dose, obscuring hourly resolution of the dose rate. Air pollutant exposures with comparable total daily doses may have very different effects when occurring at high levels over a few hours as opposed to low levels over a longer time. Alternative data-based choices for summary statistics are provided using principal component analysis to capture the exposure dose rate, while preserving ease of interpretation. This is demonstrated using the earliest hourly particle concentration data available for El Paso from archived records of particulate matter (PM)₁₀. In this way, a significant association between evening PM₁₀ exposures and nonaccidental daily mortality is found in El Paso from 1992 to 1995, otherwise missed using the daily average. Secondly, the nature and, hence, effects of particles in the ambient aerosol during El Paso sandstorms is believed different from that of particles present during stillair conditions resulting from atmospheric temperature inversions. To investigate this, wind speed (ws) is used as a surrogate variable to label PM₁₀ exposures as Low-ws (primarily fine particles), High-ws (primarily coarse particles), or Mid-ws (a mixture of fine and coarse particles). A High-ws evening is significantly associated with a 10% lower risk of mortality on the succeeding third day, as compared with comparable exposures at Low- or Mid-ws. Although this analysis cannot be used to form firm conclusions because it uses a very small data set, it demonstrates the limitations of the daily average and suggests differential toxicity for different particle compositions.