Impact of calcium and magnesium on growth and morphological acclimations of Nitella: implications for calcification and nutrient dynamics

The impact of calcium (Ca) and magnesium (Mg) on the growth and morphology of a Charophyte, Nitella pseudoflabellata, and the influence of Mg on calcification and phosphorous (P) speciation were studied in laboratory experiments for variable concentrations (≤q120 mg · L^?1) of Ca and Mg. It was clearly identified that Mg aided shoot elongation. An increase in Ca concentrations produced intensified shoot elongation also, but at a lesser rate than the equivalent levels of Mg. Depending on the availability of Ca and Mg, the morphological appearance differed significantly, suggesting significant levels of ecoplasticity. Furthermore, Mg was observed to produce less calcite encrustation. Plant P-speciation suggested a higher Mg concentration corresponding to a more water-soluble and less carbonate-bound P fraction. This indicates that upon senescence and decomposition, a large fraction of P is supplied to the water column; ultimately behaving similar to a typical vascular plant.     

Arsenic speciation in polychaetes (Annelida) and sediments from the intertidal mudflat of Sundarban mangrove wetland, India

This paper documents the concentration of total arsenic and individual arsenic species in four soft-bottom benthic polychaetes (Perenereis cultifera, Ganganereis sootai, Lumbrinereis notocirrata and Dendronereis arborifera) along with host sediments from Sundarban mangrove wetland, India. An additional six sites were considered exclusively for surface sediments for this purpose. Polychaetes were collected along with the host sediments and measured for their total arsenic content using inductively coupled plasma mass spectrometry. Arsenic concentrations in polychaete body tissues varied greatly, suggesting species-specific characteristics and inherent peculiarities in arsenic metabolism. Arsenic was generally present in polychaetes as arsenate (As^V ranges from 0.16 to 0.50 mg kg^?1) or arsenite (As^III ranges from 0.10 to 0.41 mg kg^?1) (30–53 % as inorganic As) and dimethylarsinic acid (DMA^V <1–25 %). Arsenobetaine (AB < 16 %), and PO₄-arsenoriboside (8–48 %) were also detected as minor constituents, whilst monomethylarsonic acid (MA^V) was not detected in any of the polychaetes. The highest total As (14.7 mg kg^?1 dry wt) was observed in the polychaete D. arborifera collected from the vicinity of a sewage outfall in which the majority of As was present as an uncharacterised compound (10.3 mg kg^?1 dry wt) eluted prior to AB. Host sediments ranged from 2.5 to 10.4 mg kg^?1 of total As. This work supports the importance of speciation analysis of As, because of the ubiquitous occurrence of this metalloid in the environment, and its variable toxicity depending on chemical form. It is also the first work to report the composition of As species in polychaetes from the Indian Sundarban wetlands.     

Fume emissions during gas metal arc welding

The control of exposure to welding fumes is of increasing importance in promoting a healthy, safe and productive work environment. This article describes the effects of shielding gas composition on the amount and composition of welding fumes produced during gas metal arc welding (GMAW). The amount of fumes generated during welding was measured for steady current over a range of wire-feed speeds and arc voltages using the standard procedures contained in ANSI/AWS F1.2 [American Welding Society. ANSI/AWS F1.2. Laboratory method for measuring fume generation rates and total fume emission of welding and allied processes. Miami, Florida; 1992]. Results of these measurements show that the fume formation rates (FFRs) increase with CO₂ and O₂ in the shielding gas mixture. The lowest FFRs were obtained with the mixtures of Ar?+?2%CO₂ and Ar?+?3%CO₂?+?1%O₂. The highest FFRs were obtained with the mixtures of Ar?+?18%CO₂ and Ar?+?5%CO₂?+?4%O₂. The welding fumes contains mainly iron, manganese, silicon, titanium and sodium under oxide forms. The fume cluster particles have dimensions between 0.5 and 2?µm. The FFR was found to be governed by the transfer modes of molten metal, i.e. the current intensity and arc voltage, as well as by the shielding gas mixtures composition. Thus these parameters have to be taken into consideration before designing a welding process. Whenever possible, users of GMAW should use the lowest current intensity. However, when this is not possible, due to the constraints of process productivity, welders should use higher currents, but with Ar?+?2%CO₂ and Ar?+?3%CO₂?+?1%O₂ shielding mixtures, which will lead to smaller fume emissions.     

Accurate DTM generation in sand beaches using mobile mapping

A Mobile Mapping System (MMS) is composed by a set of sensors placed on a mobile platform whose main objective is to obtain attitude and position over time of a referential in the platform together with the image of the objects surrounding the platform. The acquired data allows to obtain georeferenced positions of object points captured by the object sensors. This paper describes a methodology to automatically extract accurate Digital Terrain Models (DTM) of sand beach areas using a Terrestrial Mobile Mapping System (TMMS). The main goal of the presented TMMS is to obtain accurate 3D models of sand beaches. A very important consequence of this will be the abbility to track spatial and temporal changes in coastal geomorphology. The presented methodology has several advantages over more classical approaches: the overall cost, flexibility for regular surveys or at the most convenient epoch, such as after storms. Besides one of the major constraints in Mobile Mapping, that is poor GNSS (Global Navigation Satellite Systems) observation conditions, is usually not present in these areas. The TMMS uses two progressive colour video cameras and can work with any type of direct georeferencing system, which obvoiusly has impact in the final accuracy of the derived DTM. For the results herein reported, a dual frequency GNSS receiver and a low grade type of IMU (Inertial Measurement System) were used. The moving platform where the system was installed is a moto quad. The developed methodology for the DTM generation relies on an automatic choice of terrain points whose three-dimensional coordinates are calculated using a presented image matching technique. A cloud of points obtained in a nearly regular grid pattern is the base for the DTM. The proposed methodology was applied on a sector of the Vila Nova de Gaia Coast, in northern Portugal, and the results presented here show that it is possible with this methodology to produce DTMs with a precision of a few centimetres.     

Sustainability measurement of product-service systems: Brazilian case studies about electric car-sharing

Modifying the traditional production system and the culture of consumption is necessary to achieve a sustainable society. The product-service system (PSS) business model allows companies to progressively add services to physical products, thus promoting more pro-sustainable business outcomes. The purpose of this work is to verify how a PSS model can contribute to sustainability by analyzing two electric car-sharing projects using a set of five factors. As a methodological strategy, a Systematic Literature Review and a case study of the two projects (VAMO and EMOTIVE) were performed. Findings show benefits generated by both projects as to environmental aspects, mainly related to gases emission. It was also possible to observe social benefits due to income development and environmental awareness. This paper thus contributes to the discussion of the potential of the PSS models and how they can leverage business models toward a more sustainable society. Although the results are applicable only in this case, this article can motivate new projects and contribute to enriching the debate about sustainable solutions, as the literature in this field still provides few case studies showing these types of applications.     

Red blood cell osmotic fragility in the Spanish mackerel Scomberomorus maculatus

Red cell osmotic fragility was studied in 50 blood samples of the fish Scomberomorus maculatus (Mitchill). High levels of mean corpuscular fragility were found and hypotheses are presented to explain this phenomenon.     

A quantitative review of the effects of biochar application to soils on crop productivity using meta-analysis

Increased crop yield is a commonly reported benefit of adding biochar to soils. However, experimental results are variable and dependent on the experimental set-up, soil properties and conditions, while causative mechanisms are yet to be fully elucidated. A statistical meta-analysis was undertaken with the aim of evaluating the relationship between biochar and crop productivity (either yield or above-ground biomass). Results showed an overall small, but statistically significant, benefit of biochar application to soils on crop productivity, with a grand mean increase of 10%. However, the mean results for each analysis performed within the meta-analysis covered a wide range (from −28% to 39%). The greatest (positive) effects with regard to soil analyses were seen in acidic (14%) and neutral pH soils (13%), and in soils with a coarse (10%) or medium texture (13%). This suggests that two of the main mechanisms for yield increase may be a liming effect and an improved water holding capacity of the soil, along with improved crop nutrient availability. The greatest positive result was seen in biochar applications at a rate of 100 t ha⁻¹ (39%). Of the biochar feedstocks considered and in relation to crop productivity, poultry litter showed the strongest (significant) positive effect (28%), in contrast to biosolids, which were the only feedstock showing a statistically significant negative effect (−28%). However, many auxiliary data sets (i.e. information concerning co-variables) are incomplete and the full range of relevant soil types, as well as environmental and management conditions are yet to be investigated. Furthermore, only short-term studies limited to periods of 1 to 2 years are currently available. This paper highlights the need for a strategic research effort, to allow elucidation of mechanisms, differentiated by environmental and management factors and to include studies over longer time frames.     

Physiological responses and phytoremediation capacity of floating and submerged aquatic macrophytes exposed to ciprofloxacin

Environmental Science and Pollution Research - Ciprofloxacin (Cipro) water contamination is a global concern, having reached disturbing concentrations and threatening the aquatic ecosystems. We...     

Geochronology of anthropogenic radionuclides in Ribeira Bay sediments, Rio de Janeiro, Brazil

Ribeira Bay is located approximately 130 km south of the city of Rio de Janeiro and receives discharges of liquid effluent from the Angra dos Reis nuclear power plant (NPP) site, where two pressurized water reactors are located. To test whether the presence of anthropogenic radionuclides in sediments in Ribeira Bay could be correlated to the NPP operations, we sampled seven sediment cores and determined accumulation rates and chronologies. Only one sediment core did not exhibit a superficial mixing layer; this sample was used for dating purposes. Cesium-137 and ²⁰⁷Bi were observed in this sediment profile, but their presence was associated with atmospheric fall-out rather than the nearby NPP. The exponential decay of ²¹⁰Pb concentration with sediment layer depth was verified below a superficial mixing layer for all other sediment cores. Calculated accumulation rates ranged from 1.2 mm y⁻¹ in the inner bay to 6.2 mm y⁻¹ close to its entrance.     

CO2 dispersion around two PWR nuclear power plants in Brazil

Atmospheric air samples were taken within 3 km from power plants encompassing five different distances and wind directions. Samples were taken between 2002 and 2005 aiming to evaluate the environmental ¹⁴C enrichment due to the operation of Brazilian nuclear power plants. The sampling system consisted of a pump connected to a trapping column filled with a 3 M NaOH solution. The trapped CO₂ was analyzed for ¹⁴C by using a single stage accelerator mass spectrometry (SSAMS).