Nitrous oxide accumulation in soils from riparian buffers of a coastal plain watershed carbon/nitrogen ratio control

Riparian buffers are used throughout the world for the protection of water bodies from nonpoint-source nitrogen pollution. Few studies of riparian or treatment wetland denitrification consider the production of nitrous oxide (N2O). The objectives of this research were to ascertain the level of potential N2O production in riparian buffers and identify controlling factors for N2O accumulations within riparian soils of an agricultural watershed in the southeastern Coastal Plain of the USA. Soil samples were obtained from ten sites (site types) with different agronomic management and landscape position. Denitrification enzyme activity (DEA) was measured by the acetylene inhibition method. Nitrous oxide accumulations were measured after incubation with and without acetylene (baseline N2O production). The mean DEA (with acetylene) was 59 microg N2O-N kg(-1) soil h(-1) for all soil samples from the watershed. If no acetylene was added to block conversion of N2O to N2, only 15 microg N2O-N kg(-1) soil h(-1) were accumulated. Half of the samples accumulated no N2O. The highest level of denitrification was found in the soil surface layers and in buffers impacted by either livestock waste or nitrogen from legume production. Nitrous oxide accumulations (with acetylene inhibition) were correlated to soil nitrogen (r2=0.59). Without acetylene inhibition, correlations with soil and site characteristics were lower. Nitrous oxide accumulations were found to be essentially zero, if the soil C/N ratios>25. Soil C/N ratios may be an easily measured and widely applicable parameter for identification of potential hot spots of N2O productions from riparian buffers.     

Scale and sustainability of marine bioprospecting for pharmaceuticals

Collecting marine organisms for the discovery and development of pharmaceuticals has been perceived variously as sustaining and threatening conservation. Our initial expectations that marine bioprospecting might pose conservation challenges were largely not confirmed. Thousands of marine species have been collected for initial assessment, but usually only in very small amounts. Very few compounds are sufficiently promising to provoke re-collections, where volumes can be much larger. This is where conservation concerns may arise, particularly if the organism is rare, has a restricted distribution, or is targeted in one narrow area. However, industry generally seeks to avoid dependency on small populations, for economic as well as ecological reasons. Alternative supply strategies to wild capture include synthesis and culture. Mandatory collection protocols and environmental impact (stock) assessments are useful routes for management to achieve sustainable use where extraction is desirable. In general, the scanty information available suggests that marine bioprospecting for pharmaceuticals may have minimal impacts on the environment, particularly compared with those created by other pressures.     

2,4-Dichlorophenoxy acetic acid mineralization in amended soil

The application of municipal biosolid or liquid hog manure to agricultural soils under laboratory conditions at 20 degrees C influenced the fate of the herbicide 2,4-D [2,4-(dichlorophenoxy)acetic acid] in soil. When 2,4-D was added to soil at agronomic rates immediately after the addition of manure or biosolids to a coarse-textured soil, the percentage of 2,4-D mineralized at 100 days was about 47% for both treatments, compared to only 31% for control soils without amendments. The enhanced 2,4-D mineralization as a result of amendment addition was due to an increased heterotrophic microbial activity, with the greatest increases in soil respiration occurring for soils amended with biosolids. When additions of 2,4-D were delayed for one, two, or four weeks after the amendments were applied, the additions of amendments generally reduced 2,4-D mineralization in soil, particularly for manure, indicating that the effect of amendments on enhancing soil microbial activities diminished over time. In contrast, the mineralization of 2,4-D in control soils was less dependent on when 2,4-D was applied in relation to pre-incubations of soil for zero, one, two, or four weeks. The effect of manure on decreasing 2,4-D mineralization in specific soils was as large as the effect of soil texture on differences in 2,4-D mineralization across soils. Because manure was not found to impact 2,4-D sorption by soil, it is possible that 2,4-D mineralization decreased because 2,4-D transformation products were strongly sorbed onto organic carbon constituents in manure-amended soils and were therefore less accessible to microorganisms. Alternatively, microorganisms were less likely to metabolize the herbicide because they preferentially consumed the type of organic carbon in manure that is a weak sorbent for 2,4-D.     

Evaluating peats for their capacities to remove odorous compounds from liquid swine manure using headspace “solid‐phase microextraction”

Abstract

This paper reports on research designed to investigate the capacities of different highly characterized peats to remove odorous compounds from liquid swine manure (LSM). Peat types representing a wide range of properties were tested in order to establish which chemical and physical properties might be most indicative of their capacities to remediate odors produced by LSM. Eight percent slurries (of peat/LSM) were measured for odor changes after 24 hours using odor panel and GC/MS‐Solid‐phase microextraction (GC/MS‐SPME) analysis.

The GC/MS‐SPME and odor panel results indicated that, although all peats tested in this study were found to be effective at removing odor‐causing compounds found in LSM, some peats tended to work better than others. Overall, the peats that were the most effective at removing odor‐causing compounds tended to have lower bulk densities, ash contents, fulvic acids contents, and guaiacyl lignins contents,and higher water holding capacities, hydraulic conductivities, “total other lignins”; contents, hydrogen contents, carbon contents, and total cellulose contents.

GC/MS‐SPME analysis was found to be a reasonably inexpensive and efficient way of conducting this type of research. It allows one to identify a large number of the odor‐causing compounds found in LSM, and more importantly, to detect with some precision specific differences in the amounts of these compounds between peat types.     

WATER RESOURCE POLITICS AND INTEREST GROUP TACTICS1

ABSTRACT: The traditional strong role of interest groups in water resources policy making has been modified recently by the introduction of many environmental groups. The new groups differ from traditional groups in their relatively modest resources and their relative lack of access to traditional decision points. This paper examines the extent to which the new groups differ in their perceptions of the effectiveness of tactics and in their use of tactics, taking into account group resources and group access to decision makers.     

APPLICATION OF THE SNOWMELT RUNOFF MODEL USING MULTIPLE-PARAMETER LANDSCAPE ZONES ON THE TOWANDA CREEK BASIN,PENNSYLVANIA1

ABSTRACT: The Snowmelt Runoff Model (SRM) is designed to compute daily stream discharge using satellite snow cover data for a basin divided into elevation zones. For the Towanda Creek basin, a Pennsylvania watershed with relatively little relief, analysis of snow cover images revealed that both elevation and land use affected snow accumulation and melt on the landscape. The distribution of slope and aspect on the watershed was also considered; however, these landscape features were not well correlated with the available snow cover data. SRM streamflow predictions for 1990, 1993 and 1994 snowmelt seasons for the Towanda Creek basin using a combination of elevation and land use zones yielded more precise streamflow estimates than the use of standard elevation zones alone. The use of multiple-parameter zones worked best in non-rain-on-snow conditions such as in 1990 and 1994 seasons where melt was primarily driven by differences in solar radiation. For seasons with major rain-on-snow events such as 1993, only modest improvements were shown since melt was dominated by rainfall energy inputs, condensation and sensible heat convection. Availability of GIS coverages containing satellite snow cover data and other landscape attributes should permit similar reformulation of multiple-parameter watershed zones and improved SRM streamflow predictions on other basins.