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141.
Mubarak A. Khan S. Shehrzade M. Sarwar U. Chowdhury M. M. Rahman 《Journal of Polymers and the Environment》2001,9(3):115-124
Jute yarns were grafted with a single impregnating monomer 1,6-hexanediol diacrylate (HDDA) in order to improve the physicomechanical properties. Jute yarns soaked for different soaking times (3, 5, 10, and 30 minutes) in HDDA+MeOH solutions at different proportions (1–10% HDDA in MeOH [v/v] along with photoinitiator Darocur-1664 [3%]) were cured under UV lamp at different UV radiation intensities (two, four, six, and eight passes). Concentration of monomer, soaking time, and intensity of UV radiation were optimized with extent of mechanical properties such as tensile strength, elongation at break, and modulus. Enhanced tensile strength (67%), modulus (108%), and polymer loading (11%) were achieved with 5% HDDA concentration, 5-minute soaking time, fourth pass of UV radiation. To further improve the mechanical properties, the jute yarns were pretreated with UV radiation (5, 10, 15, 30, and 50 passes) and treated with optimized monomer concentration (5%). UV-pretreated samples showed the enhanced properties. The tensile strength and modulus increase up to 84% and 132%, respectively, than that of virgin jute yarn. An experiment involving water absorption capacity shows that water uptake by treated samples was much lower than that of the untreated samples. During the weathering test, treated yarns exhibited less loss of mechanical properties than untreated yarns. 相似文献
142.
Ozonation catalyzed by homogeneous and heterogeneous catalysts for degradation of DEHP in aqueous phase 总被引:5,自引:0,他引:5
Di-(2-ethyl hexyl) phthalate (DEHP), a recalcitrant and an endocrine disrupting chemical, was studied for its removal from wastewater by advanced oxidation process. The effects of pH, transition metal ions, and granular activated carbon (GAC) were investigated. Removal of DEHP increased with increase in pH and among metal ions Cr(III) was found to be the most active catalyst to remove DEHP. In the case of GAC, original carbon (G0) and GAC pre-ozonated in gas phase for 10 min (G10) were tested as catalysts in catalytic ozonation and found G0 to be more active than G10. This is because, during pre-ozonation, basic groups like chromene, pyrones and also graphene layers were oxidized to acidic surface oxygen groups. These basic surface groups are reported to be active catalytic centres for ozone decomposition into .OH which is a strong oxidant. According to kinetic manipulations, DEHP degradation rate constant due to .OH was affected by the catalyst while that due to direct ozonation is same in all cases with or without catalyst. G0 was doped with chromia gels (G0/CrA) to combine the benefits of homogeneous and heterogeneous catalysis. G0/CrA showed lower catalytic efficiency than that of only G0. This might be because of changes in surface structure of GAC caused by doping of chromia gel and changes in chemical nature of Cr(III) during formation of gel. A good correlation was found between the rate constants of ozone decay and DEHP degradation (R2=0.96). This correlation confirms that ozone decomposition into .OH is a critical factor for the activity of a catalyst during ozonation. 相似文献
143.
Health risks of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China 总被引:24,自引:0,他引:24
Khan S Cao Q Zheng YM Huang YZ Zhu YG 《Environmental pollution (Barking, Essex : 1987)》2008,152(3):686-692
Consumption of food crops contaminated with heavy metals is a major food chain route for human exposure. We studied the health risks of heavy metals in contaminated food crops irrigated with wastewater. Results indicate that there is a substantial buildup of heavy metals in wastewater-irrigated soils, collected from Beijing, China. Heavy metal concentrations in plants grown in wastewater-irrigated soils were significantly higher (P相似文献
144.
M. Tufail Sikander M. Mirza Arif Mahmood A. A. Qureshi Yasir Arfat H. A. Khan 《Journal of environmental radioactivity》2000,50(3):283
Using the closed-can technique, radon exhalation rate measurements have been carried out for shale and coal samples collected from various mines located in the Chakwal and Makarwal areas of Pakistan. For the two areas, the measured average values of the exhalation rates from shale are 1.45±0.13 and 0.67±0.25 Bq m−2 h−1 and for coal are 1.0±0.03 and 0.65±0.32 Bq m−2 h−1, respectively. These values are much lower than the measured exhalation rates from alum-shale-based Nordic concrete which has values in the 50–200 Bq m−2 h−1 range. The lower values of the measured exhalation rates from the shale and coal deposits in the Chakwal and Makarwal areas are indicative of their lower uranium contents and mine workers in these areas do not face any abnormal health hazard due to radon since the exhalation rates have been found to be on the low side. 相似文献
145.
Nutrient-impregnated charcoal: an environmentally friendly
slow-release fertilizer 总被引:20,自引:0,他引:20
Modabber Ahmed Khan Ki-Wook Kim Wang Mingzhi Bu-Kug Lim Weon-Hee Lee Jong-Yoon Lee 《The Environmentalist》2008,28(3):231-235
The widespread contamination of surface and ground water quality from the heavy use of fertilizer in modern agriculture is
the current concern. Therefore, this study was carried out to develop a slow-release fertilizer using charcoal. The morphology
of the charcoal impregnated fertilizer was investigated by scanning electron microscopy (SEM). This study also evaluated the
release patterns of N, P, and K from impregnated charcoal using a simulated soil solution and distilled water as leaching
solutions. The patterns of N, P, and K releases were examined in both static and continuous-flow conditions for 360 h. Releases
of N, P, and K from impregnated charcoal were found to be slow and steady. However, the release trends of N, P, and K were
higher in soil solution than distilled water under both the above conditions. Dissolution occurred when N, P, and K were released
in the above leached solutions. As a result, the fertilizer impregnated charcoal could be developed as slow-release type fertilizer
to minimize the contamination. 相似文献
146.
陕北黄土丘陵区不同土地利用方式下土壤碳剖面分布特征 总被引:9,自引:7,他引:9
黄土高原土层深厚,土壤剖面碳存储受土地利用方式影响明显.为探讨不同土地利用方式对深层土壤碳分布的影响,研究了人工经济林地(陕北米脂)、退耕还林地(神木)和防风固沙林地(榆林榆阳区)0~20.0 m土壤有机碳(SOC)和无机碳(SIC)的分布特征和差异.结果表明,在不同土地利用方式下SOC含量:矮化枣树(2.00 g·kg~(-1))未矮化枣树(1.54 g·kg~(-1))柠条林(0.97 g·kg~(-1))退化人工草地(0.81 g·kg~(-1))樟子松林(0.70 g·kg~(-1))荒草地(0.45 g·kg~(-1)),且各剖面之间SOC含量存在显著性差异(P0.05).在不同土地利用方式下SIC含量:矮化枣树(11.66 g·kg~(-1))≥未矮化枣树(11.59g·kg~(-1))柠条林(9.62 g·kg~(-1))退化人工草地(8.07 g·kg~(-1))樟子松林(4.32 g·kg~(-1))荒草地(0.47 g·kg~(-1));人工经济林和退耕还林(草)样地内所有土壤剖面之间SIC含量无显著性差异;人工经济林、退耕还林(草)剖面和防风固沙林地剖面SIC含量存在显著性差异(P0.05).矮化枣树、未矮化枣树、柠条林、退化人工草地、樟子松林和荒草地土壤剖面无机碳密度分别是有机碳密度的6.19、7.71、10.80、10.78、5.91和1.03倍.综上可见,不同土地利用方式之间土壤碳储量存在明显差异,无机碳的含量远高于有机碳. 相似文献
147.
Role of plant growth promoting rhizobacteria in the remediation of metal contaminated soils 总被引:2,自引:0,他引:2
Mohammad Saghir Khan Almas Zaidi Parvaze Ahmad Wani Mohammad Oves 《Environmental Chemistry Letters》2009,7(1):1-19
Pollution of the biosphere by the toxic metals is a global threat that has accelerated dramatically since the beginning of
industrial revolution. The primary source of this pollution includes the industrial operations such as mining, smelting, metal
forging, combustion of fossil fuels and sewage sludge application in agronomic practices. The metals released from these sources
accumulate in soil and in turn, adversely affect the microbial population density and physico-chemical properties of soils,
leading to the loss of soil fertility and yield of crops. The heavy metals in general cannot be biologically degraded to more
or less toxic products and hence, persist in the environment. Conventional methods used for metal detoxification produce large
quantities of toxic products and are cost-effective. The advent of bioremediation technology has provided an alternative to
conventional methods for remediating the metal-poisoned soils. In metal-contaminated soils, the natural role of metal-tolerant
plant growth promoting rhizobacteria in maintaining soil fertility is more important than in conventional agriculture, where
greater use of agrochemicals minimize their significance. Besides their role in metal detoxification/removal, rhizobacteria
also promote the growth of plants by other mechanisms such as production of growth promoting substances and siderophores.
Phytoremediation is another emerging low-cost in situ technology employed to remove pollutants from the contaminated soils.
The efficiency of phytoremediation can be enhanced by the judicious and careful application of appropriate heavy-metal tolerant,
plant growth promoting rhizobacteria including symbiotic nitrogen-fixing organisms. This review presents the results of studies
on the recent developments in the utilization of plant growth promoting rhizobacteria for direct application in soils contaminated
with heavy metals under a wide range of agro-ecological conditions with a view to restore contaminated soils and consequently,
promote crop productivity in metal-polluted soils across the globe and their significance in phytoremediation. 相似文献
148.
Sajjad Haider Rab Nawaz Muzammil Anjum Tahir Haneef Vipin Kumar Oad Salah Uddinkhan Rawaiz Khan Muhammad Aqif 《Frontiers of Environmental Science & Engineering》2023,17(9):111
149.
Syed Harris Laeeque Atif Bilal Abdullah Hafeez Zoia Khan 《International journal of occupational safety and ergonomics》2019,25(4):604-613
The present study examines whether patient-perpetrated violence triggers anger, hatred and other negative emotions that, under certain circumstances, might motivate nurses to behave violently with patients. In doing so, this study considers burnout as a mediator in the patient violence–nurse violence relationship. To test the causal paths, data were collected from 182 nurses working in two government-sector teaching hospitals of Pakistan's Punjab province. Results confirm that patient violence toward nurses leads to nurse violence toward patients through the mediating effect of burnout. The study advises hospitals to provide wellness and stress management programs to nurses who regularly experience events involving patient violence. Hospitals may consider allowing nurses to take short breaks after an encounter with violently behaving patients. In addition, hospitals should conduct empathy-promoting training, emotional intelligence training and ‘lens of the patient’ training programs to sensitize their nursing staff. 相似文献
150.
Raza Ali Khan Muhammad Tariq Iqbal Ali Qamar Hussain Tanveer Narjis Saadia 《Environmental science and pollution research international》2021,28(30):40378-40393
Environmental Science and Pollution Research - This study was designed to investigate the impact of meteorological indicators (temperature, rainfall, and humidity) on total COVID-19 cases in... 相似文献