FATE OF NITROGEN AND PHOSPHORUS ENTERING A GULF COAST FRESHWATER LAKE: A CASE STUDY1

ABSTRACT: Nitrogen and P fluxes, transformations and water quality functions of Lake Verret (a coastal Louisiana freshwater lake), were quantified. Ortho-P, total-P, NH₄⁺-N NO₃ -N and TKN in surface water collected from streams feeding Lake Verret averaged 104, 340, 59, 185, and 1,060 mg 1^?1, respectively. Lake Verret surface water concentrations of ortho-P, total-P, NH⁺-N, NO₃^?_-N and TKN averaged 66, 191, 36, 66, and 1,292 μg 1^?1. The higher N and P concentrations were located in areas of the lake receiving drainage. Nitrification and denitrification processes were significant in removing appreciable inorganic N from the system. In situ denitrification rates determined from acetylene inhibition techniques show the lake removes 560 mg N m^?2 yr^?1. Laboratory investigations using sediment receiving 450 μg NH⁺₄-N (N-15 labeled) showed that the lake has the potential to remove up to 12.8 g N m^?2 yr^?1. Equilibrium studies of P exchanges between the sediment and water column established the potential or adsorption capacity of bottom sediment in removing P from the overlying water. Lake Verret sediment was found to adsorb P from the water column at concentrations above 50 μg P 1^?1 and the adsorption rates were as great as 300 μg P cm^?2 day^?1 Using the ¹³⁷C s dating techniques, approximately 18 g N m^?2 yr^?1 and 1.2 g P m^?2 yr^?1 were removed from the system via sedimentation. Presently elevated nutrient levels are found only in the upper reaches of the lake receiving nutrient input from runoff from streams draining adjacent agricultural areas. Nitrification, denitrification, and adsorption processes at the sediment water interface over a relatively short distance reduces the N and P levels in the water column. However, if the lake receives additional nutrient loading, elevated levels will likely cover a larger portion of the lake, further reducing water quality in the lake.     

Apatite and phillipsite as sequestering agents for metals and radionuclides

Laboratory and greenhouse studies were conducted to quantify apatite and phillipsite (zeolite) sequestration of selected metal contaminants. The laboratory batch study measured the sorption of aqueous Co2+, Ba2+, Pb2+, Eu3+, and UO2(2+). Apatite sorbed more Co2+, Pb2+, Eu3+, and UO2(2+) from the spike solution than phillipsite, resulting in distribution coefficients (Kd values) of >200,000 L kg(-1). Phillipsite was more effective than apatite at sorbing aqueous Ba2+. Results from the laboratory study were used to design the greenhouse study that used a soil affected by a Zn-Pb smelter from Pribram, Czech Republic. Two application rates (25 and 50 g kg(-1)) of phillipsite and apatite and two plant species, maize (Zea mays L.) and oat (Avena sativa L.), were evaluated in this study. There was little (maize) to no (oat) plant growth in the unamended contaminated soil. Apatite and, to a slightly lesser extent, phillipsite additions significantly enhanced plant growth and reduced Cd, Pb, and Zn concentrations in all analyzed tissues (grain, leaves, and roots). The sequestering agents also affected some essential elements (Ca, Fe, and Mg). Phillipsite reduced Fe and apatite reduced P and Fe concentrations in oat tissues; however, the level of these elements in oat leaves and grains remained sufficient. Sequential extractions of the soil indicated that the Cd, Pb, and Zn were much more strongly sorbed onto the amended soil, making the contaminants less phytoavailable.     

Design of aquifer remediation systems: (2) estimating site-specific performance and benefits of partial source removal

A Lagrangian stochastic model is proposed as a tool that can be utilized in forecasting remedial performance and estimating the benefits (in terms of flux and mass reduction) derived from a source zone remedial effort. The stochastic functional relationships that describe the hydraulic "structure" and non-aqueous phase liquid (NAPL) "architecture" have been described in a companion paper (Enfield, C.G., Wood, A.L., Espinoza, F.P., Brooks, M.C., Annable, M., Rao, P.S.C., this issue. Design of aquifer remediation systems: (1) describing hydraulic structure and NAPL architecture using tracers. J. Contam. Hydrol.). The previously defined functions were used along with the properties of the remedial fluids to describe remedial performance. There are two objectives for this paper. First, is to show that a simple analytic element model can be used to give a reasonable estimate of system performance. This is accomplished by comparing forecast performance to observed performance. The second objective is to display the model output in terms of change in mass flux and mass removal as a function of pore volumes of remedial fluid injected. The modelling results suggest that short term benefits are obtained and related to mass reduction at the sites where the model was tested.     

Hurricanes and hegemony: A qualitative analysis of micro-level climate change denial discourses

The climate change countermovement and its program of climate change denial have been well documented and studied. However, individual rationales for rejecting climate science remain under-studied. Twitter data related to Hurricane Sandy in 2012 are used to understand why individuals reject the orthodox climate consensus, using a summative content analysis of climate change denial discourses. Three major discourses are discovered: rejecting climate science because climate science is a conspiracy favoring growth of government; opposing renewable energy and energy taxation; and expressing fear of governmental abuse of power. Importantly, each discourse expressed certainty that climate science itself was a wholesale fraud; the denial discourses themselves focused far more on climate politics than on science.     

Cooling Pond Steam Fog

This paper is responsive to needs to describe and predict the environmental effects from power plant cooling ponds. A study was made to determine atmospheric and pond surface conditions required for steam fog to occur from power plant cooling ponds, to define the dimensions of the fog, and to collect data on deposition of ice. Data, collected principally at the 4-Corners Plant over a three-year period, included water surface temperature, ambient meteorological conditions and occurrence and magnitude of steam fog and ice deposition. With strong winds, the fog extended onshore without lifting. With light winds, the fog extended some distance onshore but then lifted to form stratus. With almost calm winds, the steam fog lifted over the pond and drifted downwind as stratus. Steam fog was observed in winds to 28 mph, air-water temperature differences from 21.5° to 68°F and in atmospheric stability categories C, D, E, and F. A fog index number, Ar/(e_s — e_a)°F/mbs, was defined and used for data interpretation, where Ar is temperature of water less temperature of ambient air, e_s is the saturation vapor pressure of the ambient air and e_a is the actual vapor pressure of the ambient air. The probability of occurrence of steam fog as a function of the fog index number varied from 0.04 for an index number less than 10 to 1.00 for an index number greater than 90. From the data, if fog occurred, its extent along the ground was ≥100 feet 88% of the time, ≥500 feet 35% of the time, ≥1000 feet 18% of the time, and ≥5000 feet 12% of the time. If stratus occurred its extent above ground was ≥1 mile 91% of the time, ≥5 miles 55% of the time and ≥10 miles 36% of the time. Measurements showed that steam fog droplet sizes predominate in the 10 micron diameter size. Values of liquid water content up to 0.20 g/m³ were reported. Ice accretion data show build-up rates from 0.23 to 13 mm/hr of rime.     

Active capping technology—New approaches for in situ remediation of contaminated sediments

This study evaluated pilot‐scale active caps composed of apatite, organoclay, biopolymers, and sand for the remediation of metal‐contaminated sediments. The active caps were constructed in Steel Creek, at the Savannah River Site near Aiken, South Carolina. Monitoring was conducted for 12 months. Effectiveness of the caps was based on an evaluation of contaminant bioavailability, resistance to erosion, and impacts on benthic organisms. Active caps lowered metal bioavailability in the sediment during the one‐year test period. Biopolymers reduced sediment suspension during cap construction, increased the pool of carbon, and lowered the release of metals. This field validation showed that active caps can effectively treat contaminants by changing their speciation, and that caps can be constructed to include more than one type of amendment to achieve multiple goals. © 2012 Wiley Periodicals, Inc.     

HISTORICAL CHANGES IN UPPER MISSISSIPPI RIVER WATER AREAS AND ISLANDS1

ABSTRACT: Periodic surveys of the upper Mississippi River since 1866 and a discharge record of nearly equal length provided an opportunity to learn more about the magnitudes and rates of geomorphic processes at work in large stream systems. Furthermore, geomorphic and hydrologic adjustments could be evaluated in relation to watershed land use changes, small‐scale climate fluctuations, and considerable modifications to the channel and floodplain during the period of record. The present study uses GIS mapping to quantitatively compare historical changes in mapped land and water phenomena in the upper Mississippi River Pool 10, located along southwest Wisconsin's border. Modest channel widening and decreases in island area throughout the study reach during the last century are detectable. Flood magnitudes and frequencies also have varied during this time, and stages and low flow discharges have increased since the 1940s. The latter hydrologic change appears to be closely associated with the reach's geomorphic adjustments. Results are representative of a valley reach where a major tributary contributes a large sand bedload, forming an alluvial fan of considerable size in the floodplain.     

Leachate recirculation in a landfill: some insights obtained from the development of a simple 1-D model

The re-introduction of leachate back into the waste can play an important part in landfill management. It can encourage biodegradation by raising the water content and transporting bacteria, nutrients and waste products. It also enables leachate to be stored within the body of the landfill, for example to help minimise temporal variations in the load on a leachate treatment plant. It is helpful for a landfill operator to be able to estimate the rate at which the landfill can accept leachate (the maximum infiltration or injection rate), the storage capacity of the landfill and the leachate retention time. This paper discusses some of the insights obtained from the development and application of a simple conceptual model of leachate recirculation that can be used to estimate key parameter values on the basis of the hydraulic properties of the waste. The model is described, partly validated against a more rigorous numerical analysis, and then used to interpret data obtained from field tests on a real site. The shortcomings of the model in its current form are discussed, and suggestions are made as to how these might be addressed in the context of developing the model as a design tool.     

The First Detection of Human Bocavirus Species 2 and 3 in Raw Sewage and Mussels in South Africa

Human bocavirus (HBoV) has a global distribution and is associated with respiratory and enteric infections, particularly in the paediatric population. In this study, raw sewage and mussel samples were analysed for the presence of HBoV using nested PCR with primers targeting the VP1/VP2 junction. Amplification and sequencing of the 382 bp region followed by phylogenetic analysis indicated the presence of HBoV 2 in mussel samples and HBoV 3 in sewage samples. This is the first report describing the presence of enteric-associated HBoV in environmental samples from South Africa and in mussel samples from the African continent. The results signify the need for further studies examining the potential risk of foodborne transmission of HBoV and highlight the importance of continued screening to determine the prevalence and epidemiology of HBoV in South Africa.