Trapping and decomposing of color compounds from recycled water by TiO2 coated activated carbon

Five types of commercially available activated carbons (ACs) were coated with TiO₂ nanoparticles prepared using a sol–gel method. Color and trace organics remaining in the actual treated effluent were adsorbed by TiO₂ coated ACs. The absorbed organic compounds were then decomposed using a photocatalytic process, and the ACs were regenerated for reuse. The efficiency of the process was assessed by the characterization of true color and A₂₅₄ (the organics absorption at the wavelength of 254 nm) at the beginning and the end of the experiment. The effects of UV light source, UV irradiation time, hydrogen peroxide and ultrasound on the efficiency of photocatalytic regeneration were also investigated. Significant differences in the efficiency were observed between uncoated ACs and TiO₂ coated samples. Among the 5 types of ACs tested, AC-3, AC-4 and their coated ones achieved better efficiency in color and A₂₅₄ removal, with around 90% or more color and A₂₅₄ being removed within 1 h of treatment. The data obtained in this study also demonstrated that the photocatalytic process was effective for decomposing the adsorbed compounds and regenerating the spent TiO₂/AC-3. Finally, it was found that this regeneration process could be greatly enhanced with the assistance of H₂O₂ and ultrasound by reducing the required regeneration time.     

Water Quality in the Near Coastal Waters of the Gulf of Mexico Affected by Hurricane Katrina: Before and After the Storm

Water quality was assessed following Hurricane Katrina in the affected waters of Alabama, Mississippi, and Louisiana. Post-landfall water quality was compared to pre-hurricane conditions using indicators assessed by EPA’s National Coastal Assessment program and additional indicators of contaminants in water and pathogens. Water quality data collected after Hurricane Katrina suggest that the coastal waters affected by the storm exhibited higher salinity and concentrations of chlorophyll a, dissolved inorganic phosphorus, and total suspended solids following the storm compared to the previous 5-year averages. Higher bottom dissolved oxygen concentrations and light attenuation were also observed. Contaminant concentrations measured in the water column were very low or undetectable, as were the presence of pathogens. Overall water quality did not significantly differ from water quality assessed in the five years preceding the storm. Statistical analyses indicate that use of a probabilistic survey design is appropriate for making pre-storm and post storm comparisons for water quality condition on an areal basis. The information in this article has been funded wholly (or in part) by the U.S. Environmental Protection Agency. It has been subjected to review by the National Health and Environmental Effects Research Laboratory and approved for publication. Approval does not signify that the contents reflect the views of the Agency, nor does mention of trade names or commercial products constitute endorsement or recommendation for use. This is contribution number 1280 from the Gulf Ecology Division.     

Role of Patch Size, Disease, and Movement in Rapid Extinction of Bighorn Sheep

Abstract: The controversy (  Berger 1990, 1999 ; Wehausen 1999 ) over rapid extinction in bighorn sheep ( Ovis canadensis ) has focused on population size alone as a correlate to persistence time. We report on the persistence and population performance of 24 translocated populations of bighorn sheep. Persistence in these sheep was strongly correlated with larger patch sizes, greater distance to domestic sheep, higher population growth rates, and migratory movements, as well as to larger population sizes. Persistence was also positively correlated with larger average home-range size ( p = 0.058, n = 10 translocated populations) and home-range size of rams ( p = 0.087, n = 8 translocated populations). Greater home-range size and dispersal rates of bighorn sheep were positively correlated to larger patches. We conclude that patch size and thus habitat carrying capacity, not population size per se, is the primary correlate to both population performance and persistence. Because habitat carrying capacity defines the upper limit to population size, clearly the amount of suitable habitat in a patch is ultimately linked to population size. Larger populations (250+ animals) were more likely to recover rapidly to their pre-epizootic survey number following an epizootic ( p = 0.019), although the proportion of the population dying in the epizootic also influenced the probability of recovery ( p = 0.001). Expensive management efforts to restore or increase bighorn sheep populations should focus on large habitat patches located ≥23 km from domestic sheep, and less effort should be expended on populations in isolated, small patches of habitat.     

Regional patterns in foliar (15)N across a gradient of nitrogen deposition in the northeastern US

Recent studies have demonstrated that natural abundance (15)N can be a useful tool for assessing nitrogen saturation, because as nitrification and nitrate loss increase, delta(15)N of foliage and soil also increases. We measured foliar delta(15)N at 11 high-elevation spruce-fir stands along an N deposition gradient in 1987-1988 and at seven paired northern hardwood and spruce-fir stands in 1999. In 1999, foliar delta(15)N increased from -5.2 to -0.7 per thousand with increasing N deposition from Maine to NY. Foliar delta(15)N decreased between 1987-1988 and 1999, while foliar %N increased and foliar C:N decreased at most sites. Foliar delta(15)N was strongly correlated with N deposition, and was also positively correlated with net nitrification potential and negatively correlated with soil C:N ratio. Although the increase in foliar %N is consistent with a progression towards N saturation, other results of this study suggest that, in 1999, these stands were further from N saturation than in 1987-1988.     

The Ecological Condition of Gulf of Mexico Resources from Perdido Key to Port St. Joe, Florida, USA: Part I. Coastal Beach Resources

Using the approach established by EPA's Environmental Monitoring and Assessment Program (EMAP), a shoreline monitoring survey was conducted in August and September 1999, encompassing the Florida Panhandle from Perdido Key, Florida to Port St. Joe, Florida. The objective of this survey was to demonstrate the use of a probabilistic survey for monitoring and estimating the condition of swimmable beach areas. Thirty stations were sampled using a probabilistic sampling design. Hydrographic data were collected in addition to samples for water chemistry. Bacterial indicators, enterococci and fecal coliforms, were enumerated from the water according to the EPA Beaches Environmental Assessment Closure and Health (BEACH) Program and Florida state guidelines. Additional criteria for site condition included the presence or absence of primary and secondary dunes, anthropogenic debris and vegetation. Based on EMAP evaluation guidelines and Florida state criteria, a baseline assessment of the condition of the Gulf of Mexico beach resources surveyed is presented.     

Statistical Issues for Monitoring Ecological and Natural Resources in the United States

The United States funds a number of national monitoring programs to measure the status and trends of ecological and natural resources. Each of these programs has a unique focus; the scientific objectives are different as are the sample designs. However, individuals and committees, all well aware of the cost of ecological monitoring, have called for more effective monitoring programs. The objective of this paper is to summarize existing programs' statistical designs and discuss potential alternatives for improvement in national monitoring. Can we improve the current situation by providing an overall framework for the design or analysis of data from these disparate surveys? First, the paper summarizes the objectives of these surveys, compares and contrasts their survey designs as currently implemented, and determines what variables they collect. Through this process we identify commonalities and issues that impact our ability to combine information across one or more of the surveys. Three potential alternatives are presented, leading to comprehensive monitoring in the United States.