全文获取类型
收费全文 | 23650篇 |
免费 | 1152篇 |
国内免费 | 8033篇 |
专业分类
安全科学 | 1898篇 |
废物处理 | 1466篇 |
环保管理 | 2020篇 |
综合类 | 13343篇 |
基础理论 | 3636篇 |
环境理论 | 2篇 |
污染及防治 | 7538篇 |
评价与监测 | 1049篇 |
社会与环境 | 867篇 |
灾害及防治 | 1016篇 |
出版年
2024年 | 33篇 |
2023年 | 347篇 |
2022年 | 1086篇 |
2021年 | 972篇 |
2020年 | 775篇 |
2019年 | 661篇 |
2018年 | 871篇 |
2017年 | 1034篇 |
2016年 | 967篇 |
2015年 | 1288篇 |
2014年 | 1870篇 |
2013年 | 2401篇 |
2012年 | 2046篇 |
2011年 | 2080篇 |
2010年 | 1712篇 |
2009年 | 1657篇 |
2008年 | 1822篇 |
2007年 | 1470篇 |
2006年 | 1416篇 |
2005年 | 963篇 |
2004年 | 723篇 |
2003年 | 840篇 |
2002年 | 754篇 |
2001年 | 588篇 |
2000年 | 682篇 |
1999年 | 589篇 |
1998年 | 532篇 |
1997年 | 545篇 |
1996年 | 480篇 |
1995年 | 368篇 |
1994年 | 268篇 |
1993年 | 249篇 |
1992年 | 225篇 |
1991年 | 146篇 |
1990年 | 117篇 |
1989年 | 48篇 |
1988年 | 53篇 |
1987年 | 30篇 |
1986年 | 31篇 |
1985年 | 19篇 |
1984年 | 16篇 |
1983年 | 15篇 |
1982年 | 22篇 |
1981年 | 12篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1968年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
42.
Zheng Lei Li Dewen Song Shuzheng Wang Hongtu Sui Jinjun 《Environment, Development and Sustainability》2022,24(3):3110-3125
Environment, Development and Sustainability - In order to reveal the distribution and migration law of downwind and upwind coal cutting, total dust (TD) and respirable dust (RD) concentration... 相似文献
43.
Jiao Youzhou Xue Huizan He Chao Wang Zigang Ma Xiaoran Liu Xinxin Liu Liang Chang Chun Petracchini Francesco Li Panpan 《Environment, Development and Sustainability》2022,24(4):4709-4726
Environment, Development and Sustainability - Anaerobic digestion (AD) is an attractive straw resource treatment technology as it can improve the utilization efficiency of straw resource. Raw straw... 相似文献
44.
为揭示地下水波动带中细菌群落结构特征及其与地下水环境相互作用关系,选取哈尔滨市第一水源地作为研究区,采集地下水样品以及波动带不同深度(0~5m非饱和带和6~50m饱和带)含水介质样品,分别用于水化学分析和16S rRNA细菌高通量测序,依托冗余分析定量表述地下水质参数与细菌群落相关性.水化学分析结果显示,研究区地下水主要污染物为Fe、Mn、NH4+和有机质,Fe、Mn超标与研究区特定地质背景有关,NH4+和有机质主要来源于人类活动.微生物分析结果显示,非饱和带和饱和带的细菌群落结构差异性显著,非饱和带细菌群落丰度和多样性显著高于饱和带,Proteobacteria、Bacteroidetes、Actinobacteria、Firmicutes和Acidobacteria为研究区优势门,在非饱和带和饱和带的累积相对丰度分别为82.89%和98.64%.冗余分析(RDA)结果显示,门水平上非饱和带中与水质演化强相关的细菌类群是Bacteroidetes、Proteobacteria、Actinobacteria、Verrucomicrobia,贡献率分别为15%、14.8%、8.9%和5.2%;饱和带中对地下水质演化起主要作用的类群为Bacteroidetes、Acidobacteria、Actinobacteria和Firmicutes,贡献率分别为38.4%、19.0%、10.8%和9.1%.属水平上非饱和带中的Pseudomonas和饱和带中的Flavobacterium对Fe、Mn、NH4+生物转化起主导作用.本研究为揭示地下水波动带中生物地球化学作用对地下水环境的影响提供了科学依据,对地下水污染修复具有重要的意义. 相似文献
45.
以沸石为载体制备了锰铈复合氧化物催化剂(记为:MnCeOx/沸石催化剂),探究了催化剂对工业典型VOCs的二元催化性能,并对催化剂进行BET、XRD及SEM表征。结果表明:Ce的加入,促进了Mn的分散,提高了MnCeOx/沸石催化剂的活性;当n(Mn)∶n(Ce)为1∶1,负载率为20%,焙烧温度为500℃时,催化剂的活性最高,其对甲苯的起燃温度(T50)和完全燃烧温度(T90)分别为155,255℃;单组分实验中,催化剂对3种有机物均表现出较高活性,转化率达到90%时的反应温度均在275℃以下,其活性顺序为乙酸乙酯>甲苯>丙酮,主要受反应活化能大小及分子极性的影响;二元催化实验中,由于竞争吸附的影响,3种物质的T50和T90较单组分均分别提高了8~13,14~38℃。 相似文献
46.
Xiaoai Lu Junqian He Jing Xie Ying Zhou Shuo Liu Qiulian Zhu Hanfeng Lu 《环境科学学报(英文版)》2020,32(1):39-48
Carbon–silica materials with hierarchical pores consisting of micropores and mesopores were prepared by introducing nanocarbon microspheres derived from biomass sugar into silica gel channels in a hydrothermal environment.The physicochemical properties of the materials were characterized by nitrogen physical adsorption(BET),scanning electron microscopy(SEM),and thermogravimetric(TG),and the adsorption properties of various organic waste gases were investigated.The results showed that microporous carbon materials were introduced successfully into the silica gel channels,thus showing the high adsorption capacity of activated carbon in high humidity organic waste gas,and the high stability and mechanical strength of the silica gel.The dynamic adsorption behavior confirmed that the carbon–silica material had excellent adsorption capacity for different volatile organic compounds(VOCs).Furthermore,the carbon–silica material exhibited excellent desorption characteristics:adsorbed toluene was completely desorbed at 150℃,thereby showing superior regeneration characteristics.Both features were attributed to the formation of hierarchical pores. 相似文献
47.
Liuwei Kong Min Hu Qinwen Tan Miao Feng Yu Qu Junling An Yuanhang Zhang Xingang Liu Nianliang Cheng 《环境科学学报(英文版)》2020,32(1):49-59
To clarify the aerosol hygroscopic growth and optical properties of the Pearl River Delta(PRD)region,integrated observations were conducted in Heshan City of Guangdong Province from October 19 to November 17,2014.The concentrations and chemical compositions of PM_(2.5),aerosol optical properties and meteorological parameters were measured.The mean value of PM_(2.5) increased from less than 35(excellent) to 35-75 μg/m~3(good) and then to greater than 75 μg/m~3(pollution),corresponding to mean PM_(2.5) values of 24.9,51.2,and 93.3 μg/m~3,respectively.The aerosol scattering hygroscopic growth factor(f(RH = 80%)) values were 2.0,2.12,and 2.18 for the excellent,good,and pollution levels,respectively.The atmospheric extinction coefficient(σext)and the absorption coefficient of aerosols(σ_(ap)) increased,and the single scattering albedo(SSA)decreased from the excellent to the pollution levels.For different air mass sources,under excellent and good levels,the land air mass from northern Heshan had lower f(RH) and σ_(sp) values.In addition,the mixed aerosol from the sea and coastal cities had lower f(RH) and showed that the local sources of coastal cities have higher scattering characteristics in pollution periods. 相似文献
48.
The performance of Ce-OMS-2 catalysts was improved by tuning the fill percentage in the hydrothermal synthesis process to increase the oxygen vacancy density. The Ce-OMS-2 samples were prepared with different fill percentages by means of a hydrothermal approach (i.e. 80%, 70%, 50% and 30%). Ce-OMS-2 with 80% fill percentage (Ce-OMS-2-80%) showed ozone conversion of 97%, and a lifetime experiment carried out for more than 20?days showed that the activity of the catalyst still remained satisfactorily high (91%). For Ce-OMS-2-80%, Mn ions in the framework as well as K ions in the tunnel sites were replaced by Ce4+, while for the others only Mn ions were replaced. O2-TPD and H2-TPR measurements proved that the Ce-OMS-2-80% catalyst possessed the greatest number of mobile surface oxygen species. XPS and XAFS showed that increasing the fill percentage can reduce the AOS of Mn and augment the amount of oxygen vacancies. The active sites, which accelerate the elimination of O3, can be enriched by increasing the oxygen vacancies. These findings indicate that increasing ozone removal can be achieved by tuning the fill percentage in the hydrothermal synthesis process. 相似文献
49.
Yongjiao Xiong Xiangfeng Huang Bin Lu Baoqiang Wu Lijun Lu Jia Liu Kaiming Peng 《环境科学学报(英文版)》2020,32(3):80-89
Waste cutting emulsions are difficult to treat efficiently owing to their complex composition and stable emulsified structure. As an important treatment method for emulsions, chemical demulsification is faced with challenges such as low flocs–water separation rates and high sludge production. Hence, in this study, Fe3O4 magnetic nanoparticles (MNPs) were used to enhance chemical demulsification performance for treating waste cutting emulsions under a magnetic field. The addition of MNPs significantly decreased the time required to attain sludge–water separation and sludge compression equilibrium, from 210 to 20 min. In addition, the volume percentage of sludge produced at the equilibrium state was reduced from 45% to 10%. This excellent flocculation–separation performance was stable over a pH range of 3–11. The magnetization of the flocculants and oil droplets to form a flocculant–MNP–oil droplet composite, and the magnetic transfer of the composite were two key processes that enhanced the separation of cutting emulsions. Specifically, the interactions among MNPs, flocculants, and oil droplets were important in the magnetization process, which was controlled by the structures and properties of the three components. Under the magnetic field, the magnetized flocculant–MNP–oil droplet composites were considerably accelerated and separated from water, and the sludge was simultaneously compressed. Thus, this study expands the applicability of magnetic separation techniques in the treatment of complex waste cutting emulsions. 相似文献
50.
Glycine(Gly) is ubiquitous in the atmosphere and plays a vital role in new particle formation(NPF).However,the potential mechanism of its on sulfuric acid(SA)-ammonia(A)clusters formation under various atmospheric conditions is still ambiguous.Herein,a(Gly)_x·(SA)_y·(A)_z(z≤x+y≤3) multicomponent system was investigated by using density functional theory(DFT) combined with Atmospheric Cluster Dynamics Code(ACDC) at different temperatures and precursor concentrations.The results show that Gly,with one carboxyl(-COOH) and one amine(-NH_2) group,can interact strongly with SA and A in two directions through hydrogen bonds or proton transfer.Within the relevant range of atmospheric concentrations,Gly can enhance the formation rate of SA-A-based clusters,especially at low temperature,low [SA],and median [A].The enhancement(R) of Gly on NPF can be up to 340 at T=218.15 K,[SA]=10~4,[A]=10~9,and [Gly]=10~7 molecules/cm~3.In addition,the main growth paths of clusters show that Gly molecules participate into cluster formation in the initial stage and eventually leave the cluster by evaporation in subsequent cluster growth at low [Gly],it acts as an important "transporter" to connect the smaller and larger cluster.With the increase of [Gly],it acts as a "participator" directly participating in NPF. 相似文献