Understanding the chemical and mineralogical properties of the inorganic portion of MSWI bottom ash

This paper investigates the changes of mineralogical composition of bottom ash in the environment. The chemical and mineralogical bulk composition was determined by X-ray fluorescence (XRF) and X-ray powder diffraction (XRPD) Rietveld method. Single bottom ash particles were investigated by optical microscopy, scanning electron microscopy with quantitative energy-dispersive X-ray microanalysis (SEM/EDX) and electron probe micro analysis (EPMA). SEM/EDX and EPMA are valuable complement to bulk analysis and provide means for rapid and sensitive multi-elemental analysis of ash particles. The fresh bottom ash consists of amorphous (>30 wt.%) and major crystalline phases (>1 wt.%) such as silicates, oxides and carbonates. The mineral assemblage of the fresh bottom ash is clearly unstable and an aging process occurs by reaction towards an equilibrium mineral phase composition in the environmental conditions. The significant decrease of anhydrite and amorphous contents was observed in the aged bottom ash, leading to the formation of ettringite, hydrocalumite and rosenhahnite under atmospheric conditions. In the water-treated sample, the calcite contents increased significantly, but ettringite was altered by the dissolution and precipitation processes in part, to produce gypsum, while the remaining part reacted with chloride to form hydrocalumite. Gypsum and other Ca based minerals may take up substantial amounts of heavy metals and subsequently control leaching behaviour of bottom ash.     

Habitat type-based bioaccumulation and risk assessment of metal and As contamination in earthworms, beetles and woodlice

The present study investigated the contribution of environmental factors to the accumulation of As, Cd, Cu, Pb and Zn in earthworms, beetles and woodlice, and framed within an exposure assessment of the European hedgehog. Soil and invertebrate samples were collected in three distinct habitat types. Results showed habitat-specific differences in soil and invertebrate metal concentrations and bioaccumulation factors when normalized to soil metal concentration. Further multiple regression analysis showed residual variability (habitat differences) in bioaccumulation that could not be fully explained by differences in soil metal contamination, pH or organic carbon (OC). Therefore, the study demonstrated that in bioaccumulation studies involving terrestrial invertebrates or in risk assessment of metals, it is not sufficient to differentiate habitat types on general soil characteristics such as pH and/or OC alone. Furthermore, simple generic soil risk assessments for Cd and Cu showed that risk characterization was more accurate when performed in a habitat-specific way.     

APPLICATION OF ENHANCED ANNEALING TO GROUND WATER REMEDIATION DESIGN1

ABSTRACT: A methodology for ground water remediation design has been developed that interfaces ground water simulation models with an enhanced annealing optimizer. The ground water flow and transport simulators provide the ability to consider site‐specific contamination and geohydrologic conditions directly in the assessment of alternative remediation system designs. The optimizer facilitates analysis of tradeoffs between technical, environmental, regulatory, and financial risks for alternative design and operation scenarios. A ground water management model using an optimization method referred to as “enhanced annealing” (simulated annealing enhanced to include “directional search” and “memory” mechanisms) has been developed and successfully applied to an actual restoration problem. The demonstration site is the contaminated unconfined aquifer referred to as N‐Springs located at Han‐ford, Washington. Results of the demonstration show the potential for improving groundwater restoration system performance while reducing overall system cost.     

Fluoride Emissions and Forest Growth

Abstract

The October 1995 court decision allowing Ethyl Corporation to offer methylcyclopentadienyl manganese tricarbonyl (MMT) for sale to refiners for introduction into unleaded gasoline as an octane enhancer is likely to result in increased fine (PM_2.5) manganese (Mn) concentrations in ambient air. Concern exists regarding possible health effects. In this paper, recent fine Mn concentrations in three monitoring networks and one U.S. Environmental Protection Agency (EPA) study of personal exposure are analyzed. One network consists mainly of rural sites in national parks in the United States, a second consists mainly of urban sites in California, and the third consists mainly of urban sites in Canada where MMT has been used for a number of years. During the late 1980s and early 1990s, mean ambient concentrations ranged from 1 ng/m³ in the mostly rural network to 3 ng/m³ in the mostly urban California network to 12 ng/m³ in the MMT-impacted Canadian network. Several lines of evidence suggested that some of the fine Mn observed in the United States during the 1986-1992 period was contributed by automobiles using leaded gasoline, for which MMT was a registered fuel additive. However, the near-disappearance of leaded gasoline has resulted in a very small portion of fine Mn being attributed to automobiles in the years since 1992.A source apportionment analysis suggested that crustal contributions to ambient fine Mn are on the order of 1-2 ng/m³ in both the United States and Canada.     

Variations in some environmental characteristics including C and N stable isotopic composition of suspended organic matter in the Mandovi estuary

Chemical and isotopic (??¹³C and ??¹⁵N) investigation of the Mandovi estuary along the Indian west coast affected strongly by the seasonal monsoon cycle was carried out. The Mandovi estuary is a major waterway for Goa and extensively used for transportation of iron and manganese ore. In addition, with large population centers as well as agricultural fields located on its shores, the estuary is assumed to have been influenced by human activities. Measurements of chemical and isotopic parameters made in the lower part of the estuary during the southwest (SW) monsoon and post-monsoon seasons reveal distinct changes, and it is observed that despite considerable enrichment of macronutrients during the SW monsoon, productivity of the estuary (phytoplankton biomass), as inferred from the chlorophyll-a content, is not as high as expected. This is due to occurrences of high turbidity and cloud cover that limits photosynthetic productivity. The isotopic characterization (C and N isotopes) of suspended organic matter produced/transported during the monsoon and post-monsoon seasons of year 2007 provides a baseline dataset for future isotopic studies in such type of tropical estuaries.     

Effect of interior door position on room-to-room differences in residential pollutant concentrations after short-term releases

Residential interior door positions influence the pollutant concentrations that result from short-term indoor sources, such as cigarettes, candles, and incense. To elucidate this influence, we reviewed past studies and conducted new experiments in three residences: a single-story 714 m³ ranch-style house, a 510 m³ two-story split-level house, and a 200 m³ two-story house. During the experiments, we released sulfur hexafluoride or carbon monoxide tracer gas over short periods (≤30 min) and measured concentrations in the source room and at least one other (receptor) room for various interior door opening positions. We found that closing a door between rooms effectively prevented transport of air pollutants, reducing the average concentration in the receptor room relative to the source room by 57–100% over exposure periods of 1–8 h. When intervening doors were partially or fully open, the reduction in average concentrations ranged from 3% to 99%, varying as a function of door opening width and the distance between source and receptor rooms.     

Fire Regime Changes in La Michilía Biosphere Reserve, Durango, Mexico

Abstract: The ability of reserves to maintain natural ecosystem processes such as fire disturbance regimes is central to long-term conservation. Fire-scarred tree samples were used to reconstruct fire regimes at five study sites totaling approximately 230 ha in pine (   Pinus spp.) and oak ( Quercus spp.) forests of La Michilía Biosphere Reserve on the dry east slope of the Sierra Madre Occidental, Durango, Mexico. Study sites covered a 20-km environmental gradient of elevation, topography, and human land uses. Plant communities ranged from oak-pine to mixed conifer forests. Fires were frequent at all sites prior to 1930, when large-scale grazing of domestic livestock was initiated. Widespread fires have been excluded from four of the five sites since 1945, with an essentially uninterrupted regime of frequent fires continuing only in the reserve core. Xeric sites had many, smaller fires, whereas mesic sites had fewer but larger fires. On a reserve-wide scale, a fire burned on at least one site nearly every year, usually in the dry spring or early summer season, but fire years were rarely synchronous among the sites. Fire occurrence was weakly related to the Southern Oscillation climate pattern; major reserve-wide fire years almost never coincided with wet Southern Oscillation extremes but only occasionally matched dry extremes. Maintenance of the long-term frequent-fire regime in the reserve core is one indicator that the biosphere reserve model has been successful in conserving natural processes, but the protected area is small ( 7000 ha). Because of the key role of frequent-fire regimes in regulating ecosystem structure and function, restoration of the ecological role of fire disturbance is a desirable conservation strategy.     

Assessing ecological risk on a regional scale

Society needs a quantitative and systematic way to estimate and compare the impacts of environmental problems that affect large geographic areas. This paper presents an approach for regional risk assessment that combines regional assessment methods and landscape ecology theory with an existing framework for ecological risk assessment. Risk assessment evaluates the effects of an environmental change on a valued natural resource and interprets the significance of those effects in light of the uncertainties identified in each component of the assessment process. Unique and important issues for regional risk assessment are emphasized; these include the definition of the disturbance scenario, the assessment boundary definition, and the spatial heterogeneity of the landscape. Although the research described in this article has been funded wholly or in part by the United States Environmental Protection Agency (EPA) through Interagency Agreement Number DW89932112-01-2 to the U.S. Department of Energy, it has not been subjected to EPA review and therefore does not necessarily reflect the views of EPA and no official endorsement should be inferred.