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491.
Pooja?PalEmail author Himangana?Gupta Deepak?Kapur 《Mitigation and Adaptation Strategies for Global Change》2016,21(3):391-402
Steel dominates the global metal production accounting for 5 % of increase in Earth’s atmospheric carbon dioxide (CO2). Today, India is the 4th largest producer of crude steel in the world. The sector contributes around 3 % to the country’s gross domestic product (GDP) but adds 6.2 % to the national greenhouse gas (GHG) load. It accounts for 28.4% of the entire industry sector emissions, which are 23.9% of the country’s total emissions. Being a developing country, India is not obliged to cut its emissions under the Kyoto Protocol to the United Nations Framework Convention on Climate Change (FCCC), but gave voluntary commitment to reduce the emission intensity of its GDP by 20–25 % from the 2005 level by 2020. This paper attempts to find out if the Indian steel sector can help the country in fulfilling this commitment. The sector reduced its CO2 emissions per ton of steel produced by 58% from 1994 to 2007. The study generates six scenarios for future projections which show that the sector can reduce its emission intensity by 12.5 % to 63 %. But going by the conservative estimates, the sector can reduce emission intensity by 30 % to 53 %. However, actual emissions will go up significantly in every case. 相似文献
492.
Joseph?M.?Kimetu Josephine?M.?Hill Maen?Husein Joule?Bergerson David?B.?LayzellEmail author 《Mitigation and Adaptation Strategies for Global Change》2016,21(5):761-777
This study explored the feasibility of using residual biomass to both mitigate greenhouse gas (GHG) emissions and remediate water contaminated by hydrocarbons. Using produced (process-affected) water from Canada’s oil sands operations as a case study, activated biochar (ACB) was found to have a higher affinity to organics than activated coal and removed 75 % of total organic carbon (TOC) from produced water in steam-assisted gravity drainage (SAGD) operations or 90 % of the TOC from synthetic tailings (ST) water sample. Up to 6 Tg dry biomass year?1 would be required to treat the waters associated with the 93?×?106-m3 of bitumen recovered per year. Landfilling the spent ACB and flaring any biogas produced were estimated to provide a greater GHG benefit than the combustion of the biochar + organics for heat to offset natural gas demand. Net costs for the ACB were about 13.84?$?m?3 bitumen for SAGD operations and 1.76?$?m?3 bitumen for mining operations. The values for mining operations justify further work to create a value chain that will integrate bioprocesses into the fossil fuel industry. 相似文献
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Govindasamy?BalaEmail author Ranjith?Gopalakrishnan Mathangi?Jayaraman Ramakrishna?Nemani N.?H.?Ravindranath 《Mitigation and Adaptation Strategies for Global Change》2011,16(2):143-160
There is huge knowledge gap in our understanding of many terrestrial carbon cycle processes. In this paper, we investigate
the bounds on terrestrial carbon uptake over India that arises solely due to CO
2
-fertilization. For this purpose, we use a terrestrial carbon cycle model and consider two extreme scenarios: unlimited CO2-fertilization is allowed for the terrestrial vegetation with CO2 concentration level at 735 ppm in one case, and CO2-fertilization is capped at year 1975 levels for another simulation. Our simulations show that, under equilibrium conditions,
modeled carbon stocks in natural potential vegetation increase by 17 Gt-C with unlimited fertilization for CO2 levels and climate change corresponding to the end of 21st century but they decline by 5.5 Gt-C if fertilization is limited
at 1975 levels of CO2 concentration. The carbon stock changes are dominated by forests. The area covered by natural potential forests increases
by about 36% in the unlimited fertilization case but decreases by 15% in the fertilization-capped case. Thus, the assumption
regarding CO2-fertilization has the potential to alter the sign of terrestrial carbon uptake over India. Our model simulations also imply
that the maximum potential terrestrial sequestration over India, under equilibrium conditions and best case scenario of unlimited
CO2-fertilization, is only 18% of the 21st century SRES A2 scenarios emissions from India. The limited uptake potential of the
natural potential vegetation suggests that reduction of CO2 emissions and afforestation programs should be top priorities. 相似文献
495.
Tsung-Chen?LeeEmail author 《Mitigation and Adaptation Strategies for Global Change》2011,16(6):663-675
The literature on cost-effective international emissions trading (IET) assumes exogenous market structures. This paper develops
a game-theoretical model along with numerical simulations for the world economy in order to analyze the equilibrium market
structures of an IET scheme. Countries’ decisions regarding the exercise of market power and their initial permit endowments
are made non-cooperatively, being guided by their national self-interest. The theoretical results show that both price-influencing
and price-taking countries choose an optimal permit endowment in light of their damage costs. Low-damage (high-damage) countries
choose more emission permits and act as permit sellers (buyers). The numerical results further suggest that an imperfectly
competitive IET market with all price-influencing countries being permit buyers (sellers) has lower (higher) emissions than
a perfectly competitive IET market. Finally, the IET scheme has an equilibrium market structure of imperfect competition where
the high-damage European Union acts as a unique price maker. This equilibrium imperfectly competitive IET has the lowest global
emissions. 相似文献
496.
Māris K?avi?š Agrita Briede Elga Parele Valery Rodinov Inta K?avi?a 《Chemosphere》1998,36(15):3043-3053
The concentrations of cadmium, lead, nickel and copper in waters, sediments (total metal concentrations and their speciation forms) and benthic macroinvertebrates in 11 lakes of Latvia were determined using atomic absorption spectroscopy. Metal concentrations in lake waters, sediments and biota were compared with water chemistry. Compared to total concentrations, metal speciation forms in sediments were better correlated with respective metal concentrations in invertebrates. Therefore, the evaluation of potential metal bioaccumulation should consider metal speciation. The mean concentrations of trace metals in benthic invertebrates in Latvia were much lower than in other countries, which can be explained by comparatively lower anthropogenic loads. However, local areas of anthropogenic impacts were evident. 相似文献
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499.
Bojidarka?IvanovaEmail author Michael?Spiteller 《Environmental geochemistry and health》2016,38(5):1051-1066
Study of uranium interstitial compositions of non-stoichiometric oxides UO2+x (x ∈ 0.1–0.02) in gas and condense phases has been presented, using various soft-ionization mass spectrometric methods such as ESI-, APCI-, and MALDI-MS at a wide dynamic temperature gradient (∈ 25–300 °C). Linearly polarized vibrational spectroscopy has been utilized in order to assign unambiguously, the vibrational frequencies of uranium non-stoichiometric oxides. Experimental design has involved xUO2.66·yUO2.33, xUO2.66·yUO2.33/SiO2, xUO2.66·yUO2.33/SiO2 (NaOH) and SiO2/x′NaOH·y′UO2(NO3)2·6H2O, multicomponent systems (x = 1, y ∈ 0.1–1.0 and x′ = 1, y′ ∈ 0.1–0.6) as well as phase transitions UO2(NO3)2·6H2O → {U4O9(UO2.25)} → U3O7(UO2.33) → U3O8(UO2.66) → {UO3}, thus ensuring a maximal representativeness to real environmental conditions, where diverse chemical, geochemical and biochemical reactions, including complexation and sorption onto minerals have occurred. Experimental factors such as UV-irradiation, pH, temperature, concentration levels, solvent types and ion strength have been taken into consideration, too. As far as uranium speciation represents a challenging analytical task in terms of chemical identification diverse coordination species, mechanistic aspects relating incorporation of oxygen into UO 2+x form the shown full methods validation significantly impacts the field of environmental radioanalytical chemistry. UO2 is the most commonly used fuel in nuclear reactors around the globe; however, a large non-stoichiometric range ∈ UO1.65–UO2.25 has occurred due to radiolysis of water on UO2 surface yielding to H2O2, OH·, and more. Each of those compositions has different oxygen diffusion. And in this respect enormous effort has been concentrated to study the potential impact of hazardous radionuclide on the environment, encompassing from the reprocessing to the disposal stages of the fuel waste, including the waste itself, the processes in the waste containers, the clay around the containers, and geological processes. In a broader sense, thereby, this study contributes to field of environmental analysis highlighting the great ability of various soft-ionization MS methods, particularly, MALDI-MS one, for direct assay of complex multicomponent heterogeneous mixtures at fmol–attomol concentration ranges, along with it the great instrumental features allowing, not only meaningful quantitative, but also structural information of the analytes, thus making the method indispensable for environmental speciation of radionuclides, generally. 相似文献
500.
Meriem?AmeurEmail author Fadoua?Hamzaoui-Azaza Moncef?Gueddari 《Environmental geochemistry and health》2016,38(5):1147-1167
In Tunisia, the water resources are limited, partially renewable and unequally distributed between the wet north and the dry south of the country. The Sminja aquifer in Zaghouan city is located in north-east of Tunisia, between latitudes 36°38′ and 36°47′ and longitudes 9°95′ and 10°12′. This aquifer is used to satisfy the population needs for their domestic purposes and agricultural activities. Water analyses results are expressed by many methods, among which are geochemical methods combined with the geographic information system (GIS) (all schematic presentations of the diagram software (Piper, Riverside, Wilcox…), which can be used to assess the suitability of the Sminja aquifer groundwater for human consumption and irrigation purposes. A total of 23 wells were sampled in January 2013, and the concentrations of major cations (Na+, Ca2+, Mg2+ and K+), major anions (Cl?, SO4 2? and HCO3 ?), electrical conductivity and total dissolved solids were analysed. In the Sminja groundwater, the order of the cations dominance was Na > Ca > Mg > K and that of the anions was Cl > HCO3 > SO4. All of the analysed samples of the study area exceed chemical values recommended by the World Health Organisation guidelines and Tunisian Standards (NT.09.14) for potability but with different percentages. The aquifer spatial distribution of saturation indices reveals that all groundwater samples are under-saturated with gypsum, halite and anhydrite and are over-saturated with respect to calcite and dolomite based on water quality evaluation parameters for irrigation purposes; here, 87 % of samples in Sminja aquifer groundwater are suitable, whereas 13 % are unsuitable for irrigation uses. 相似文献