Plastic pollution is a major environmental issue worldwide, calling for advanced methods to recycle waste plastics in the context of the circular economy. Here we review methods and strategies to convert waste plastics into value-added carbon materials, with focus on sources, properties, pretreatment of waste plastics, and on preparation of carbon materials. Pretreatment techniques include mechanical crushing, plastic stabilization and electrospinning. Carbon materials such as carbon nanotubes, graphene, carbon nanosheets, carbon spheres and porous carbon are prepared by oxygen-limited carbonization, catalytic carbonization, the template-based method, and pressure carbonization. We emphasize the conversion of polyethene terephthalate, polyethylene, polypropylene, polystyrene, halogenated plastics, polyurethane and mixed plastics.
● pz-UiO-66 was synthesized facilely by a solvothermal method.● Efficient capture of copper from highly acidic solution was achieved by pz-UiO-66.● pz-UiO-66 exhibited excellent selectivity and capacity for copper capture.● Pyrazine-N in pz-UiO-66 was shown to be the dominant adsorption site. The selective capture of copper from strongly acidic solutions is of vital importance from the perspective of sustainable development and environmental protection. Metal organic frameworks (MOFs) have attracted the interest of many scholars for adsorption due to their fascinating physicochemical characteristics, including adjustable structure, strong stability and porosity. Herein, pz-UiO-66 containing a pyrazine structure is successfully synthesized for the efficient separation of copper from strongly acidic conditions. Selective copper removal at low pH values is accomplished by using this material that is not available in previously reported metal–organic frameworks. Furthermore, the material exhibits excellent adsorption capacity, with a theoretical maximum copper uptake of 247 mg/g. As proven by XPS and FT-IR analysis, the coordination of pyrazine nitrogen atoms with copper ions is the dominant adsorption mechanism of copper by pz-UiO-66. This work provides an opportunity for efficient and selective copper removal under strongly acidic conditions, and promises extensive application prospects for the removal of copper in the treatment for acid metallurgical wastewater. 相似文献
The purpose of this study is to evaluate the methods of reducing elevated-road traffic-noise levels in rural residential areas by controlling the relative locations and morphological parameters and to investigate the effect of noise barriers on noise attenuation along elevated roads and building facades in villages. This study selected six morphological parameters and used noise-mapping techniques to estimate the noise attenuation in 60 village sites. The results indicate that ‘quiet areas’ increase by approximately 10% for each additional 100 m increase in the distance between the elevated road and the village. The best strategy for noise reduction is keeping the elevated road 1,000 m away from the village and raising the road height to 20 m. The building façade conditions only affect the traffic noise level attenuation when the buildings are within 100 m of the elevated road. It was found that the cost-effective length of the road noise barrier is 600 m on both sides of the village parallel to the road. The results highlight the importance of using morphology to improve the traffic noise resistance of villages. The landscape shape indices of buildings and roads are the most important parameters that affect the traffic noise attenuation of elevated roads. 相似文献
Environmental Science and Pollution Research - Bromate (BrO3?) and ammonia nitrogen (NH4+) are both typical environmental pollutants: BrO3? has been categorized as one of the Group 2B... 相似文献