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681.
Climate change is expected to cause an increased frequency of extreme events such as heavy floods and major storms. Such stochastic events have an immediate impact on surface water quality, but the long-term effects are largely unknown. In this study, we assess long-term monitoring data from two Swedish headwater catchments affected by extreme weather events. At one site, where nitrogen effects in soil water, groundwater, and stream water were studied after storm-felling and subsequent forest dieback from bark beetle attack, long-term (>5 years) but relatively modest (generally <1 mg L?1) increases in ammonium (NH4-N) and nitrate (NO3-N) concentrations were observed in the various aqueous media. At the other site, where effects on benthic fauna were studied in a stream impacted by extreme geophysical disturbances caused by rainstorm-induced flashflood, only short-term (1 year) effects were revealed both regarding diversity and composition of species. 相似文献
682.
David G. Angeler Craig R. Allen Hannah E. Birgé Stina Drakare Brendan G. McKie Richard K. Johnson 《Ambio》2014,43(1):113-125
Freshwater ecosystems are important for global biodiversity and provide essential ecosystem services. There is consensus in the scientific literature that freshwater ecosystems are vulnerable to the impacts of environmental change, which may trigger irreversible regime shifts upon which biodiversity and ecosystem services may be lost. There are profound uncertainties regarding the management and assessment of the vulnerability of freshwater ecosystems to environmental change. Quantitative approaches are needed to reduce this uncertainty. We describe available statistical and modeling approaches along with case studies that demonstrate how resilience theory can be applied to aid decision-making in natural resources management. We highlight especially how long-term monitoring efforts combined with ecological theory can provide a novel nexus between ecological impact assessment and management, and the quantification of systemic vulnerability and thus the resilience of ecosystems to environmental change. 相似文献
683.
Restoration of acidified lakes by liming does not, in many cases, improve productivity to a pre-acidified state. We hypothesize that the poor recovery detected in many of these lakes is due to constrained in-lake phosphorous (P) cycling caused by enhanced precipitation of metals in higher pH, limed waters. Long-term (1990–2012) data for 65 limed, circum-neutral (pH 6–8), and acidified lakes in Sweden were analyzed to determine trends for P and potential drivers of these trends. Limed lakes not only had lower mean values and stronger decreasing trends for total P than non-limed lakes, but they also had the highest percentage of decreasing trends (85 %). A P release factor (Hypolimnetic P/Epilimnetic P) was developed to elucidate differences in internal P cycling between lake groups. Consistently, lower P release factors in limed lakes show limitation of internal P cycling during summer months that may be a factor limiting P bioavailability and thus productivity of these systems. 相似文献
684.
Kai Zhao Huaming Guo 《Environmental science and pollution research international》2014,21(3):1944-1953
Activated natural siderite (ANS) was used to investigate its characteristics and mechanisms of As(V) adsorption from aqueous solution. Batch tests were carried out to determine effects of contact time, initial As(V) concentration, temperature, pH, background electrolyte, and coexisting anions on As(V) adsorption. Arsenic(V) adsorption on ANS well-fitted pseudo-second-order kinetics. ANS showed a high-adsorption capacity of 2.19 mg/g estimated from Langmuir isotherm at 25 °C. Thermodynamic studies indicated that As(V) adsorption on ANS was spontaneous, favorable, and endothermic. ANS adsorbed As(V) efficiently in a relatively wide pH range between 2.0 and 10.0, although the removal efficiency was slightly higher in acidic conditions than that in basic conditions. Effects of background electrolyte and coexisting anions were not significant within the concentration ranges observed in high As groundwater. Results of XRD and Fe K-edge XANES analysis suggested ANS acted as an Fe(II)/(III) hybrid system, which was quite effective in adsorbing As from aqueous solution. There was no As redox transformation during adsorption, although Fe(II) oxidation occurred in the system. Two infrared bands at 787 and 872 cm?1 after As(V) adsorption suggested that As(V) should be predominantly adsorbed on ANS via inner-sphere bidendate binuclear surface complexes. 相似文献
685.
Vincent Bartolomei Matthias Sörgel Sasho Gligorovski Elena Gómez Alvarez Adrien Gandolfo Rafal Strekowski Etienne Quivet Andreas Held Cornelius Zetzsch Henri Wortham 《Environmental science and pollution research international》2014,21(15):9259-9269
Gaseous nitrogen dioxide (NO2) represents an oxidant that is present in relatively high concentrations in various indoor settings. Remarkably increased NO2 levels up to 1.5 ppm are associated with homes using gas stoves. The heterogeneous reactions of NO2 with adsorbed water on surfaces lead to the generation of nitrous acid (HONO). Here, we present a HONO source induced by heterogeneous reactions of NO2 with selected indoor paint surfaces in the presence of light (300 nm?<?λ?<?400 nm). We demonstrate that the formation of HONO is much more pronounced at elevated relative humidity. In the presence of light (5.5 W m?2), an increase of HONO production rate of up to 8.6?·?109 molecules cm?2 s?1 was observed at [NO2]?=?60 ppb and 50 % relative humidity (RH). At higher light intensity of 10.6 (W m?2), the HONO production rate increased to 2.1?·?1010 molecules cm?2 s?1. A high NO2 to HONO conversion yield of up to 84 % was observed. This result strongly suggests that a light-driven process of indoor HONO production is operational. This work highlights the potential of paint surfaces to generate HONO within indoor environments by light-induced NO2 heterogeneous reactions. 相似文献
686.
Anuluxshy Balasubramaniyam Patricia J. Harvey 《Environmental science and pollution research international》2014,21(22):12651-12661
The choice of plant for phytoremediation success requires knowledge of how plants respond to contaminant exposure, especially their roots which are instrumental in supporting rhizosphere activity. In this study, we investigated the responses of plants with different architectures represented by beetroot (Beta vulgaris), a eudicot with a central taproot and many narrower lateral roots, and tall fescue (Festuca arundinacea), a monocot possessing a mass of threadlike fibrous roots to grow in crude oil-treated sand. In this paper, scanning electron microscopy was used to investigate modifications to plant root structure caused by growth in crude oil-contaminated sand. Root structural disorders were evident and included enhanced thickening in the endodermis, increased width of the root cortical zone and smaller diameter of xylem vessels. Inhibition in the rate of root elongation correlated with the increase in cell wall thickening and was dramatically pronounced in beetroot compared to the roots of treated fescue. The latter possessed significantly fewer (p?<?0.001) and significantly shorter (p?<?0.001) root hairs compared to control plants. Possibly, root hairs that absorb the hydrophobic contaminants may prevent contaminant absorption into the main root and concomitant axile root thickening by being sloughed off from roots. Tall fescue exhibited greater root morphological adaptability to growth in crude oil-treated sand than beetroot and, thus, a potential for long-term phytoremediation. 相似文献
687.
Dharmendra Kumar Singh Lakshay Tarun Gupta 《Environmental science and pollution research international》2014,21(6):4551-4564
This study presents the performance evaluation of a novel denuder-equipped PM1 (particles having aerodynamic diameter less than 1 μm) sampler, tested during fog-dominated wintertime, in the city of Kanpur, India. One PM1 sampler and one denuder-equipped PM1 sampler were co-located to collect ambient PM1 for 25 days. The mean PM1 mass concentration measured on foggy days with the PM1 sampler and the denuder-equipped PM1 sampler was found to be 165.95 and 135.48 μg/m3, respectively. The mean PM1 mass concentration measured on clear days with the PM1 sampler and the denuder-equipped PM1 sampler was observed to be 159.66 and 125.14 μg/m3, respectively. The mass concentration with denuder-fitted PM1 sampler for both foggy and clear days was always found less than the PM1 sampler. The same drift was observed in the concentrations of water-soluble ions and water-soluble organic carbon (WSOC). Moreover, it was observed that the use of denuder leads to a significant reduction in the PM positive artifact. The difference in the concentration of chemical species obtained by two samplers indicates that the PM1 sampler without denuder had overestimated the concentrations of chemical species in a worst-case scenario by almost 40 %. Denuder-fitted PM1 sampler can serve as a useful sampling tool in estimating the true values for nitrate, ammonium, potassium, sodium and WSOC present in the ambient PM. 相似文献
688.
M. Veera Lakshmi J. Merrylin S. Kavitha S. Adish Kumar J. Rajesh Banu Ick-Tae Yeom 《Environmental science and pollution research international》2014,21(4):2733-2743
Extracellular polymeric substances (EPS) are an extracellular matrix found in sludge which plays a crucial role in flocculation by interacting with the organic solids. Therefore, to enhance pretreatment of sludge, EPS have to be removed. In this study, EPS were removed with a chemical extractant, NaOH, to enhance the bacterial pretreatment. A lysozyme secreting bacterial consortium was isolated from the waste activated sludge (WAS). The result of density gradient gel electrophoresis (DGGE) analysis revealed that the isolated consortium consists of two strains. The two novel strains isolated were named as Jerish03 (NCBI accession number KC597266) and Jerish 04 (NCBI accession number KC597267) and they belong to the genus Bacillus. Pretreatment with these novel strains enhances the efficiency of the aerobic digestion of sludge. Sludge treated with the lysozyme secreting bacterial consortium produced 29 % and 28.5 % increase in suspended solids (SS) reduction and chemical oxygen demand (COD) removal compared to the raw activated sludge (without pretreatment) during aerobic digestion. It is specified that these two novel strains had a high potential to enhance WAS degradation efficiency in aerobic digestion. 相似文献
689.
Potential use of Caulerpa fastigiata biomass for removal of lead: kinetics, isotherms, thermodynamic, and characterization studies 总被引:1,自引:0,他引:1
B. Sarada M. Krishna Prasad K. Kishore Kumar Ch. V. R. Murthy 《Environmental science and pollution research international》2014,21(2):1314-1325
The present study attempts to analyze the biosorption trend of biosorbent Caulerpa fastigiata (macroalgae) biomass for removal of toxic heavy metal ion Pb (II) from solution as a function of initial metal ion concentration, pH, temperature, sorbent dosage, and biomass particle size. The sorption data fitted with various isotherm models and Freundlich model was the best one with correlation coefficient of 0.999. Kinetic study results revealed that the sorption data on Pb (II) with correlation coefficient of 0.999 can best be represented by pseudo-second-order. The biosorption capacity (q e ) of Pb (II) is 16.11?±?0.32 mg g?1 on C. fastigiata biomass. Thermodynamic studies showed that the process is exothermic (ΔH° negative). Free energy change (ΔG°) with negative sign reflected the feasibility and spontaneous nature of the process. The SEM studies showed Pb (II) biosorption on selective grains of the biosorbent. The FTIR spectra indicated bands corresponding to –OH, COO?, –CH, C?=?C, C?=?S, and –C–C– groups were involved in the biosorption process. The XRD pattern of the C. fastigiata was found to be mostly amorphous in nature. 相似文献
690.
Kishor Atreya Fred H?kon Johnsen Bishal Kumar Sitaula 《Environment, Development and Sustainability》2012,14(4):477-493
There is a growing concern of pesticide risks to human health, natural environment and ecosystems. Many previous economic valuations have accounted health aspects or environmental components, but rarely combined; thus, overall risk assessment is partially distorted. The study, conducted close to the capital of Nepal, addressed the health effects of pesticides on small-scale farmers and evaluated the monetary risks of pesticide use on human health and environmental resources. We also aim to establish the relationships among valuation methods. The paper adopts cost of illness, defensive expenditure and contingent valuation willingness to pay approach. The study concluded that the methods used for valuing pesticide risks to human and environmental health are theoretically consistent. The exposed individuals are likely to bear significant economic costs of exposures depending on geographical location, pesticide use magnitudes and frequency. Individuals are willing to pay between 53 and 79% more than the existing pesticide price to protect their health and environment. The integrated pest management training is less likely to reduce health costs of pesticide exposure, although it leads to higher investment in safety measures. 相似文献