Absorption characteristics of potassium carbonate-based solutions with rate promoters and corrosion inhibitors

In this research, absorbents for CO₂ capture were prepared by blending 30 wt% potassium carbonate, 3 wt% of a rate promoter, and 1 wt% of a corrosion inhibitor. Pipecolic acid, sarcosine, and diethanolamine were chosen as rate promoter candidates. Based on a rate promoter screening test for CO₂ loading capacity and absorption rate, pipecolic acid and sarcosine were selected to be used as rate promoters. 1,2,3-benzotriazole and ammonium thiocyanate were chosen as corrosion inhibitors, and they were mixed with a 30 wt% potassium carbonate-based absorbent mixture containing one of the rate promoters. The absorption rates for four absorbent solutions (30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% 1,2,3-benzotriazole, 30 wt% potassium carbonate?+?3 wt% pipecolic acid?+?1 wt% ammonium thiocyanate, 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% 1,2,3-benzotriazole, and 30 wt% potassium carbonate?+?3 wt% sarcosine?+?1 wt% ammonium thiocyanate) were measured, tabulated, and graphically displayed. These types of absorbents can be used for capturing CO₂ under high temperature and pressure conditions, such as those found in coal-fired power plants.     

Fully Bio-Sourced Nylon 11/Raw Lignin Composites: Thermal and Mechanical Performances

Ecofriendly fully bio-composites based on polyamide 11 (PA11) and lignin have been prepared on the entire concentration range using a twin-screw extruder. In this work, PA11 was blended with lignin by direct extrusion technology without any chemical pre- or in-situ- modifications or physical pretreatments. The presence of various organic and inorganic impurities in the selected technical lignin have been maintained. The incorporation of this cheap renewable material from biomass in bio-based PA11 was inspected by an array of characterization tools. Also, the effect of the presence of lignin on the morphology and on the mechanical properties of the resulting materials was examined. Finally, in-situ investigation of structural evolution in PA11 induced by the presence of lignin was analyzed by Fast Scanning Chip Calorimetry.     

Man-Made and Natural Fibres as a Reinforcement in Fully Biodegradable Polymer Composites: A Concise Study

Biodegradable and ecologically friendly polymer materials attract great attention of many scientific groups in the world as they fit well in the sustainable development policy and are considered to be “a right thing to do” by the general public. Such polymers can be modified by the addition of different fillers, favorably of natural origin. In the paper we provide a comparison between composites based on two biodegradable polymers: poly(lactic acid)—biodegradable, natural stock polymer and poly(butylene succinate)—biodegradable polymer produced from fossil based materials. For each polymer we have prepared a series of composites with different fibres (natural: hemp and flax, and manmade: Cordenka) and different filler loadings. To fully characterize obtained materials thermal, mechanical and surface free energy measurements were performed, completed with morphology observations and an attempt to compare the experimental data for tensile measurements with values obtained using the modified rule of mixtures. The tensile results calculated using the modified rule of mixture for below 30% fibre loading are found to be fitting the experimental data. Composites mechanical properties and morphology were strongly affected by the type of fibre used and its loading, however thermal properties remained almost unchanged. In specific, Cordenka fibres tend to form bunches which presence greatly influences the mechanical properties but still our studies have shown clear advantage of manmade Cordenka fibres over the hemp and flax fibres when considering distribution and fibre–polymer interaction.     

A Solvent-Free Approach for Production of Films from Pectin and Fungal Biomass

Self-binding ability of the pectin molecules was used to produce pectin films using the compression molding technique, as an alternative method to the high energy-demanding and solvent-using casting technique. Moreover, incorporation of fungal biomass and its effects on the properties of the films was studied. Pectin powder plasticized with 30% glycerol was subjected to heat compression molding (120 °C, 1.33 MPa, 10 min) yielding pectin films with tensile strength and elongation at break of 15.7 MPa and 5.5%, respectively. The filamentous fungus Rhizopus oryzae was cultivated using the water-soluble nutrients obtained from citrus waste and yielded a biomass containing 31% proteins and 20% lipids. Comparatively, the same strain was cultivated in a semi-synthetic medium resulting in a biomass with higher protein (60%) and lower lipid content (10%). SEM images showed addition of biomass yielded films with less debris compared to the pectin films. Incorporation of the low protein content biomass up to 15% did not significantly reduce the mechanical strength of the pectin films. In contrast, addition of protein-rich biomass (up to 20%) enhanced the tensile strength of the films (16.1–19.3 MPa). Lastly, the fungal biomass reduced the water vapor permeability of the pectin films.     

Photo-Stabilisation and UV Blocking Efficacy of Coated Macro and Nano-Rutile Titanium Dioxide Particles in Paints and Coatings

Surface treated macro and nanoparticle TiO₂ samples have been prepared, characterised and their efficiency as UV blockers evaluated in clear coatings and paints. The particle size of the ‘base’ TiO₂ has been optimised to block UV radiation and the surface treatment developed to deactivate the photocatalytic activity of the surface of the TiO₂ particles. The resultant UV blockers have been evaluated in both solvent and water-based clear coatings. Nanoparticle TiO₂ has been prepared from ‘seed’ and the particle size was controlled by calcination. It was found that the choice of particle size is a compromise between UVA absorption, UVB absorption, visible transmission and photoactivity. It has been demonstrated that TiO₂ with a crystallite size of 25 nm yields a product with the optimum properties. A range of dispersants was successfully used to disperse and mill the TiO₂. Both organic and inorganic dispersants were used; 2-amino-2-methyl-1-propanol and 1-amino-2-propanol (MIPA) and P₂O₅ and Na₂SiO₃ respectively. The surface of the nano-TiO₂ was coated with mixed oxides of silicon, aluminium, zirconium and phosphorous. Addition of the resultant coated nano-rutiles to an Isocyanate Acrylic clear coating prolonged the lifetime of that coating compared to the blank. Generally, a surface treatment based on SiO₂, Al₂O₃ and P₂O₅ was more successful than one based on ZrO₂, Al₂O₃ and P₂O₅. Higher addition levels of the surface treatment were beneficial for protecting the polymeric coating. The UV blocker products were also evaluated in a water-based acrylic, first a water-based dispersion of the UV blocker was prepared before addition to the acrylic. The dispersions and resultant acrylic thin films were evaluated using UV/Vis spectroscopy and durability assessed. The ratio of absorbance at 300:500 nm for the water-based dispersion was shown to be a good predictor of both the transparency of the resultant acrylic thin film and the durability of that film, in terms of weight loss. Macro grade titanium dioxide pigments were also prepared and coated with treatments of silica, alumina and siloxane and their photo-stabilising activity in alkyd paint film assessed and found to be directly related to the electron–hole pair mobility and trapping as determined by micro-wave spectroscopy.     

Biosynthesis of Poly(3-hydroxybutyrate) from Cheese Whey by <Emphasis Type="Italic">Bacillus megaterium</Emphasis> NCIM 5472

Microbial polyhydroxyalkonate such as homopolyester of poly(3-hydroxybutyrate) (PHB) was produced from cheese whey by Bacillus megaterium NCIM 5472. Due to their numerous potential industrial applications, the focus was given to competently enhance the amount of PHB produced. The amount of PHB produced from whole cheese whey, and ultrafiltered cheese whey was first compared, and after observing a rise in PHB production by using ultrafiltered cheese whey, cheese whey permeate was chosen for further analysis. The presence of PHB was then confirmed by GCMS. Since the main aim of the study was to increase the amount of PHB produced through batch fermentation, various process parameters like time, pH, C/N ratio, etc. were optimized. After optimization, it was found that B. megaterium NCIM 5472 was capable of accumulating 75.5% of PHB of its dry weight and a PHB yield of 8.29 g/L. The chemical structure of the polymer was further analyzed by using FTIR and NMR spectroscopy methods. Also, the physical and thermal properties were studied by using Differential scanning calorimetry and Thermogravimetric analysis. It was found that the polymer produced had excellent thermal stability, thus allowing the possibility to exploit its properties for industrial purposes such as adhesives, packaging materials, etc.     

Preparation and Characterization of Xylan Derivatives and Their Blends

Although hemicellulose is found widely in nature, it is currently under-utilized as a raw material for commercial applications. It would be desirable to find new uses for hemicellulose in order to add value to this agro-based material. A common type of hemicellulose is xylan, which is found in a number of wood species and in cotton. In this work we prepared cationic and anionic xylan derivatives and characterized them by ¹³C NMR, FT-IR, size exclusion chromatography (SEC), thermal analysis, and rheology. In particular, the ¹³C NMR spectra of carboxymethyl xylan (CMX) and quaternary ammonium-adducted xylan (QAX) were fully assigned with the help of samples with different degrees of substitution. SEC indicated that the beechwood xylan showed a bimodal molecular weight distribution, but with derivatization the distribution tended to become unimodal. Thermal analysis and rheology studies did not uncover any surprises; the solution of xylan and its derivatives exhibited mostly Newtonian behavior. The blends of CMX and QAX produced a precipitate at almost all ratios, indicating the formation of a polyelectrolyte complex. When cationic and anionic xylan samples were added together to paper, the paper dry strength increased. Thus, the combination of cationic/anionic xylan may be of interest in selected applications.     

The Effect of Silane Treated Fibre Loading on Mechanical Properties of Pineapple Leaf/Kenaf Fibre Filler Phenolic Composites

The aim of the present study is to investigate mechanical and morphological properties of pineapple leaf fibres (PALF) reinforced phenolic composites and its comparison with kenaf fibre (KF)/phenolic composites. Mechanical properties (tensile, flexural and impact) of untreated and treated PALF phenolic composites at different fibre loading were investigated. Tensile, flexural and impact properties of PALF and kenaf/phenolic composites were analyzed as per ASTM standard. Morphological analysis of tensile fracture samples of composites was carried out by scanning electron microscopy. Obtained results indicated that treated PALF/phenolic composites at 50% PALF loading exhibited better tensile, flexural and impact properties as compared to other untreated PALF/phenolic composites. Treated kenaf/phenolic composites at 50% fibre loading showed better tensile, flexural and impact properties than untreated kenaf/phenolic composite. It is concluded that treated 50% fibre loading kenaf and PALF/phenolic composites showed better mechanical properties than untreated kenaf and PALF/phenolic composites due to good fibre/matrix interfacial bonding. Results obtained in this study will be used for the further study on hybridization of PALF and KF based phenolic composites.     

Utilization of Industrial Wastes from Mining and Packaging Industries in Wood-Plastic Composites

The manufacturing industry produces a lot of different by-products and waste. In this research, the utilization of different industrial wastes as a part of wood-plastic composites was tested. Limestone waste and carton cutting waste were tested by replacing part of the reinforcing fibers of the composite with these materials. The materials were made with the extrusion process, and they were tested for their mechanical properties, water absorption and thickness swelling. The materials were also viewed with a scanning electron microscope. The results showed that both industrial wastes affected the properties of the composite. Mining waste in the composite improved the moisture properties, impact strength and hardness of the material. Carton cutting waste improved the impact strength remarkably.