全文获取类型
收费全文 | 205篇 |
免费 | 2篇 |
专业分类
安全科学 | 12篇 |
废物处理 | 9篇 |
环保管理 | 61篇 |
综合类 | 18篇 |
基础理论 | 51篇 |
环境理论 | 1篇 |
污染及防治 | 30篇 |
评价与监测 | 17篇 |
社会与环境 | 8篇 |
出版年
2023年 | 2篇 |
2021年 | 4篇 |
2018年 | 7篇 |
2017年 | 3篇 |
2016年 | 1篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 10篇 |
2012年 | 8篇 |
2011年 | 13篇 |
2010年 | 9篇 |
2009年 | 7篇 |
2008年 | 14篇 |
2007年 | 16篇 |
2006年 | 15篇 |
2005年 | 4篇 |
2004年 | 3篇 |
2003年 | 7篇 |
2002年 | 9篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 5篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1968年 | 1篇 |
1965年 | 1篇 |
1914年 | 1篇 |
排序方式: 共有207条查询结果,搜索用时 15 毫秒
201.
We conducted a laboratory study to assess the feasibility of a washing process with nonionic and anionic surfactants in combination with ethylenediaminetetraacetate (EDTA) for the simultaneous mobilization of heavy metals and polychlorinated biphenyls (PCBs) from a field-contaminated soil. Unit processes consisting of complexometric extraction and surfactant-assisted mobilization were combined with reagent regeneration and detoxification steps to generate innocuous products. Ten minutes of ultrasonic mixing of the soil with a combination of 30 mL L(-1) surfactant suspension and a sparing quantity (2 mmol) of EDTA mobilized appreciable quantities of PCBs, virtually all of the available Cd, Cu, Mn, and Pb, and lesser amounts of the Zn, Ni, and Cr but only small quantities of Al and Fe. Relative to individual reagents, combinations of surfactant (Brij 98, Triton X-301, or Triton XQS-20) with EDTA did not influence PCB extraction efficiencies perceptibly. Of the three surfactants, the Brij 98 proved to be the most efficient for three successive extractions with a single charge, mobilizing 83% of the PCBs, whereas companion extractions that used fresh reagent each time mobilized 87% of the soil PCB content. The decreased PCB mobilization with the same quantity of anionic surfactant (71 or 68%) resulted from losses during the EDTA regeneration process with zero-valent Mg. In toto, these studies demonstrate that PCB compounds and selected heavy metals can be coextracted efficiently from soil with three successive washes with the same washing suspension containing EDTA and a nonionic surfactant. 相似文献
202.
We conducted a laboratory study to assess the efficiency of nonionic and anionic surfactants in combination with a sparing quantity of ethylenediaminetetraacetate (EDTA) to simultaneously extract heavy metals (HMs) and polychlorinated biphenyl (PCB) compounds from a field-contaminated soil. A soil wash that mobilized both HMs and PCBs was combined with back-extraction with hexane to remove PCBs from the aqueous wash. The aqueous washing suspension was then regenerated by precipitation of the HMs induced by corrosion and hydrolysis of zero-valent Mg to provide a cleaned soil and innocuous extract. Finally, the washing suspension was recycled twice to mobilize more contaminants from the soil particulate fraction. After ultrasonic equilibration, EDTA in admixture with a nonionic surfactant did not appreciably change the efficiency of mobilization of most heavy metals (Al, Cd, Cr, Fe Mn, Ni, and Zn), but did increase the recovery of Cu and Pb. The release of EDTA from HM complexes was efficient for most metals (99%) but was influenced by the chemical characteristics of the surfactant. The EDTA recovery (62-65%) after three cycles of soil washing, hexane back-extraction, and Mg(0) treatment was similar for all reagent combinations. In toto, these studies demonstrate that after treatment with ultrasound, selected heavy metals can be coextracted efficiently from soil with a single washing suspension containing EDTA and a nonionic surfactant. 相似文献
203.
Introduced plants that have both production values and negative impacts can be contentious. Generally they are either treated
as weeds and their use prohibited; or unfettered exploitation is permitted and land managers must individually contend with
any negative effects. Buffel grass (Cenchrus ciliaris) is contentious in Australia and there has been no attempt to broadly and systematically address the issues surrounding it.
However, recent research indicates that there is some mutual acceptance by proponents and opponents of each others’ perspectives
and we contend that this provides the basis for a national approach. It would require thorough and on-going consultation with
stakeholders and development of realistic goals that are applicable across a range of scales and responsive to regional differences
in costs, benefits and socio-economic and biophysical circumstances. It would be necessary to clearly allocate responsibilities
and ascertain the most appropriate balance between legislative and non-legislative mechanisms. A national approach could involve
avoiding the introduction of additional genetic material, countering proliferation in regions where the species is sparse,
preventing incursion into conservation reserves where it is absent, containing strategically located populations and managing
communities to prevent or reduce dominance by buffel grass. This approach could be applied to other contentious plant species. 相似文献
204.
205.
206.
Heavy metal (Cu, Zn, Cd and Pb) contamination of vegetables in urban India: a case study in Varanasi 总被引:8,自引:0,他引:8
Sharma RK Agrawal M Marshall FM 《Environmental pollution (Barking, Essex : 1987)》2008,154(2):254-263
The contributions of heavy metals in selected vegetables through atmospheric deposition were quantified in an urban area of India. Deposition rate of Zn was recorded maximum followed by Cu, Cd and Pb. The concentrations of Zn and Cu were highest in Brassica oleracea, Cd in Abelmoschus esculentus and B. oleracea, while Pb was highest in Beta vulgaris. Heavy metal pollution index showed that B. oleracea was maximally contaminated with heavy metals followed by A. esculentus and then B. vulgaris. The results of washing showed that atmospheric deposition has contributed to the increased levels of heavy metals in vegetables. Both Cu and Cd posed health risk to local population via test vegetables consumption, whereas Pb posed the same only through B. oleracea. The study concludes that atmospheric depositions can elevate the levels of heavy metals in vegetables during marketing having potential health hazards to consumers. 相似文献
207.
Imogen R. Marshall Chris J. Brauer Scotte D. Wedderburn Nick S. Whiterod Michael P. Hammer Thomas C. Barnes Catherine R. M. Attard Luciana M. Möller Luciano B. Beheregaray 《Conservation biology》2022,36(4):e13889
Restoration programs in the form of ex-situ breeding combined with reintroductions are becoming critical to counteract demographic declines and species losses. Such programs are increasingly using genetic management to improve conservation outcomes. However, the lack of long-term monitoring of genetic indicators following reintroduction prevents assessments of the trajectory and persistence of reintroduced populations. We carried out an extensive monitoring program in the wild for a threatened small-bodied fish (southern pygmy perch, Nannoperca australis) to assess the long-term genomic effects of its captive breeding and reintroduction. The species was rescued prior to its extirpation from the terminal lakes of Australia's Murray-Darling Basin, and then used for genetically informed captive breeding and reintroductions. Subsequent annual or biannual monitoring of abundance, fitness, and occupancy over a period of 11 years, combined with postreintroduction genetic sampling, revealed survival and recruitment of reintroduced fish. Genomic analyses based on data from the original wild rescued, captive born, and reintroduced cohorts revealed low inbreeding and strong maintenance of neutral and candidate adaptive genomic diversity across multiple generations. An increasing trend in the effective population size of the reintroduced population was consistent with field monitoring data in demonstrating successful re-establishment of the species. This provides a rare empirical example that the adaptive potential of a locally extinct population can be maintained during genetically informed ex-situ conservation breeding and reintroduction into the wild. Strategies to improve biodiversity restoration via ex-situ conservation should include genetic-based captive breeding and longitudinal monitoring of standing genomic variation in reintroduced populations. 相似文献