Effect of metallic cations on the sorption of pesticides on soil

We studied the adsorption and desorption of two pesticides, namely isoproturon and dimetomorph, onto a model soil sample. We first show that the adsorption of isoproturon depends on pH, from 1 mg g⁻¹ at pH 4 to 2 mg g⁻¹ at pH 10, contrary to the adsorption of dimetomorph (5.8 mg g⁻¹). We also studied the influence of metallic cations, copper(II), iron(III), manganese(II), and chromium(III), on the sorption of isoproturon and dimetomorph. We found that in the case of isoproturon, the presence of metallic cations does influence the retention capacity of the soil sample. The sorption becomes very weak in the presence of copper and chromium, whereas in the case of iron and manganese the sorption properties are slightly modified.     

The effect of cadmium upon the structure of the olfactory nerve in the young pike †

Some recent experiments have shown with autoradiographic methods the axonal transport of cadmium along the olfactory nerve of the salmon trout.² We should determine in our experiments the effect of cadmium upon the olfactory nerve at histological level using optical microscopy technics.     

Life cycle assessment of mine tailings management in Canada

The effective management of mine tailings involves the control of several environmental impacts and legal requirements. Six tailings site management and closure scenarios were developed for a copper zinc underground mine located in Quebec (Canada) and compared using life cycle assessment (LCA). Two options are considered for the mine operation: tailings can be sent to the tailings disposal area where they are submerged or they can be partly used for backfilling. For each of these two operation options, three alternatives are presented for mine closure: (a) submerged tailings, (b) partial desulphurization with a cover of desulphurized material and (c) a cover with capillary barrier effects (CCBE) made of natural soils followed by revegetation. The goals of the study were to draw the inventory of these management scenarios from the development to the post-closure phase, to assess and compare their environmental impacts and to determine the importance of the land-use impact category. The potential impacts for each scenario were evaluated using the IMPACT 2002+ LCIA method. The results of the performed LCA indicate that for mine development and operation, scenarios where tailings are partly used as backfill for underground stopes appear to lead to larger impacts in 11 of the 14 midpoint categories since the backfill plant operation consumes a greater amount of material and energy. For a site closure period of 2 years, the CCBE option creates the greatest impacts, since it requires much more effort than the other techniques. The results for the post-closure phase have been analysed separately since they have a larger uncertainty. They appear to modify the comparative assessment results. The various results presented in the paper show the importance of taking land-use impacts into account.     

Photolysis of estrone generates estrogenic photoproducts with higher activity than the parent compound

In the present study, we aimed to evaluate the effect of UV-visible irradiation on the estrogenicity of an estrone aqueous solution by using chemical analysis associated with an in vitro bioassay and in silico analysis. An estrone aqueous solution was irradiated with an UV-visible high-pressure mercury lamp. By using the MELN in vitro cellular bioassay, based on the induction of a luciferase reporter gene upon the activation of the estrogen receptor by chemicals, we showed that the estrogenic potency of the solution increased after irradiation. High-performance liquid chromatography fractionation of the photolyzed solution followed by in vitro testing of fractions allowed the quantitation of the estrogenic potency of each fraction. Nine photoproducts were detected and characterized by liquid chromatography-mass spectrometry coupling. The observed estrogenic activity is mediated by mono- and multi-hydroxylated photoproducts; it is influenced by the position of hydroxyl groups on the steroidal skeleton. In addition, a structure-activity analysis of the hydroxylated photoproducts confirmed their ability to act as estrogen receptor ligands.     

Pesticide residues intake of French adults under increased consumption of fresh fruits and vegetables – A theoretical study

The increase of fresh vegetable and fruit (FVF) intake could contribute to the prevention of obesity and several major pathologies and thus represents a major public health goal in industrial countries. Nutritional recommendations for increased consumption of FVF could lead to ingestion of unwanted amounts of pesticides. This study was undertaken to evaluate theoretical exposure of French adults to pesticide residues under increasing amounts of FVF intake. Balanced menus with 200 – 400 – 600 – 800 and 1200 g FVF/day were established. Amounts of active substances brought by every FVF vector, at the maximum residue level (MRL) were summed up to determine the intake for each active substance. Values were compared to the Acceptable Daily Intake (ADI) to point out any potential over exposure. A maximalistic approach was adopted and no reducing factor due to processing was taken into account. It was found that under minimal recommended consumption of fruit and vegetables (400 g/d), no active substance reached the ADI, but 18 vs 144 were over 10% of the ADI. Raising FVF to 600 g/d increased the number of active substances over 10 % of the ADI to 24, but again in no case was the ADI exceeded. Doubling the intake to 800 g/d gives values over the ADI for 2 active substances only (cyhexatin and thirame). It was concluded that the increase in fruit and vegetables up to 800 g per day should not expose adults over the ADIs for a majority of authorized pesticides. In this regard, residues levels of ten active substances in fruit and vegetables should deserve particular attention.     

Photodegradation of chlorinated pesticides dispersed on sand

The photochemical behaviour of several chlorinated pesticides, namely 4-chloro-2-methylphenoxyacetic acid (MCPA), dichlorophen (DCPH), flamprop-methyl (FPM) and vinclozolin (VCZ) is studied on various kinds of sand: Fontainebleau sand (almost pure silica), Touggourt sand (coloured sand from Sahara) and Jijel sand (dark marine sand). The photodegradation of MCPA is more rapid on Fontainebleau sand than on the two others, because the former is almost colourless pure silica and the others adsorb on the internal surface of the reactor. The degradation rate decreases in the order MCPA, DCPH, FPM, VCZ. The main products identified are 4-chloro-2-methylphenol with MCPA and reduction product with DCPH.     

Leaching and degradation of S-Metolachlor in undisturbed soil cores amended with organic wastes

Environmental Science and Pollution Research - Organic waste (OW) reuse in agriculture is a common practice fostered by benefits in terms of waste recycling and crop production. However, OW...