Incubation time effects on imazaquin desorption as determined by nonequilibrium thin-soil disc flow

Because organic sorption in soil may never reach equilibrium, a thin-disc flow nonequilibrium method may be helpful in understanding herbicide-soil interactions. This research was conducted to (i) determine the influence of incubation time on imazaquin [2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-3-quinolinecarboxylic acid] desorption from soil, (ii) examine the influence of solution flow velocities on desorption, and (iii) elucidate the most appropriate kinetic model to describe imazaquin leaching. Soil at 7.5% moisture w/w was treated with imazaquin and incubated for 24, 72, and 168 h. Treated soil was sealed in an in-line filter apparatus and rinsed with 5.0 mM CaCl2 at 0.33, 0.67, or 1.0 mL min(-1). Effluent was collected as 1.0-mL fractions for a total of 50 mL. Flow was stopped for 24 h. When flow resumed, fractions were collected for an additional 15 mL. After the initial desorption, 79% of the imazaquin incubated for 24 h was leached. Increasing incubation time beyond 24 h reduced imazaquin leaching. After both desorption events, 13% of the initially applied imazaquin remained in the soil incubated for 168 h, compared with 7% with soil incubated for 24 h. Elovich and Freundlich kinetics accounted for 98% of the variance observed in the imazaquin desorption curves. First-order and diffusion kinetics accounted for 91% of the variance. Incubating soil for 72 h before desorption reduced the rate of imazaquin desorption by approximately 12%, compared with the 24-h incubation treatment. Imazaquin desorption was not affected by wash solution flow rate. These data suggest that the kinetics of desorption in prolonged desorption events are limited by transport phenomena (i.e., particle and film diffusion).     

A spatial model approach for assessing windbreak growth and carbon stocks

Agroforestry, the deliberate integration of trees into agricultural operations, sequesters carbon (C) while providing valuable services on agricultural lands. However, methods to quantify present and projected C stocks in these open-grown woody systems are limited. As an initial step to address C accounting in agroforestry systems, a spatial Markov random field model for predicting the natural logarithm (log) of the mean aboveground volume of green ash ( Marsh.) within a shelterbelt, referred to as the log of aboveground volume, was developed using data from an earlier study and web-available soil and climate information. Windbreak characteristics, site, and climate variables were used to model the large-scale trend of the log of aboveground volume. The residuals from this initial model were correlated among sites up to 24 km from a point of interest. Therefore, a spatial dependence parameter was used to incorporate information from sites within 24 km into the prediction of the log of the aboveground volume. Age is an important windbreak characteristic in the model. Thus, the log of aboveground volume can be predicted for a given windbreak age and for values of other explanatory variables associated with a site of interest. Such predictions can be exponentiated to obtain predictions of aboveground volume for windbreaks without repeated inventory. With the capability of quantifying uncertainty, the model has the potential for large regional planning efforts and C stock assessments for many deciduous tree species used in windbreaks and riparian buffers once it is calibrated.     

Case Study: Chemical Screening at Eastman Kodak Company

This case study is the final installment in a four‐part series profiling environmental decision making at leading companies. © 2001 John Wiley & Sons, Inc.     

Challenges of Urban and Regional Carbon Management and the Scientific Response

Abstract

How urbanization unfolds in the text few decades and which urban development path we choose are potentially critical to the efforts aimed at stabilizing greenhouse gas emissions. However, our understanding of urban, as a unit or system, and its cross-scale linkages in the context of carbon management is at infancy state. In this context, this article outlines, the key challenges and introduces a new scientific initiative - Urban and Regional Carbon Management Initiative of the Global Carbon Project, which has raised key scientific questions with the aim to find reasonable answers. This article mainly showcases key science questions, past activities and future outlook with the aim to reach out to the related scientific and policy communities.     

Environmental quality and hog production

This paper has been presented at a meeting of the National Research Council in February 1995, in Perugia, Italy. This is a preview of that which is to be the final product of the study: a manual for evaluating the environmental impact of pig-breeding farms. The most important issues in the environment-hog production relationship are discussed. After that, some elements for a sustainable swine production are focused. To solve the pig-breeding/environment conflict is not an easy task. The challenge is to find the right compromises, adopting all possible technologies for minimizing the impact on the environment. Since the first problem is the risk of water pollution due to manure, it is important to study the best solutions from the viewpoint of the watershed, taking into account the interactions and synergies occurring in the drainage system, and especially for the communities at the lower part of the basin. Therefore it becomes more and more of an absolute necessity to plan and manage resources using the watershed as a reference.Prof. Paolo Abbozzo is the Scientific Head of the CNR-RAISA Monodisciplinary Group of the Institute of Estimo Rurale e Contabilità at the University of Perugia; Dr. Antonio Boggia is a teaching/research assistant and Dr. Mauro Brunetti is CNR scholarship holder at the same Institute.     

High-energy milling to decontaminate soils polluted by polychlorobiphenyls and atrazine

Mechanical energy has been used so far for running chemical reactions and for preparing new materials in absence of solvents. Very recently, the technology has been applied to solve environmental problems. In this paper, we describe the application of high-energy milling (HEM) for the remediation of soils contaminated by chlorinated organic compounds such as polychlorobiphenyls (PCBs) and agrochemicals like atrazine. NaBH₄ and LiAlH₄ have been successfully used for the total dehydrohalogenation of both classes of compounds, leaving a residue lower than 2 ppmw of the starting compound in the treated soil. LiAlH₄ was found to be more active than NaBH₄.     

Partitioning gas tracer tests for measurement of water in municipal solid waste

A key component in the operation of almost all bioreactor landfills is the addition of water to maintain optimal moisture conditions. To determine how much water is needed and where to add it, in situ methods are required to measure water within solid waste. Existing technologies often result in measurements of unknown accuracy, because of the variability of solid waste materials and time-dependent changes in packing density, both of which influence most measurement methods. To overcome these problems, a new technology recently developed by hydrologists for measuring water in the vadose zone--the partitioning gas tracer test--was tested. In this technology, the transport behavior of two gas tracers within solid waste is used to measure the fraction of the void space filled with water. One tracer is conservative and does not react with solids or liquids, while a second tracer partitions into the water and is separated from the conservative tracer during transport. This technology was tested in four different solid waste packings and was capable of determining the volumetric water content to within 48% of actual values, with most measurement errors less than 15%. This technology and the factors that affect its applicability to landfills are discussed in this paper.