企业安全文化评估与企业安全行为的质化研究

通过总结国内外各种不同的安全文化概念,归纳分析了国内外较为流行的近10种安全文化建立模式。在研讨文献的基础上,通过深入访谈、焦点小组与参与观察,归纳构造了一套共11个维度,总题项为152题的安全文化评估量表。通过对选定企业的实证问卷调查,进行统计分析,采用多元逐步回归分析等方法对安全文化各评核因素及整体安全文化进行预测,并以百分数呈现其整体的安全文化现状水平。通过基于扎根理论的各种质化研究方法,对案例企业的安全文化建设和企业安全行为进行研究,得到了7点关于企业安全行为的研究发现,并提出了相应的改进建议。     

电源变压器温升试验中（绕组法）的影响因素及不确定度的评估

本文中探讨的是根据绕组法计算电源变压器绕组温升的试验方法,以及对整个试验过程中环境、仪器设备、仪表、人为因素所引起的误差等对最终试验结果的影响,并对其测量不确定度进行评估。     

基层环境执法中环境行政强制问题的探讨

环境行政强制包括环境行政强制措施和环境行政强制执行.在基层环境执法实践中,环境行政强制措施尤其是环境行政强制执行存在许多困惑和问题,拓展环境行政强制措施,给予环保部门一定的行政强制执行权是提高基层环境执法效率和遏制环境污染的有效途径.     

洪灾对柳州可持续发展的影响及减灾对策

通过对柳州市洪灾特点的分析,探讨了洪灾对柳州市经济、社会可持续发展的制约作用,提出洪灾的治理必须走可发展的道路,采用工程措施和非工程措施相结合的对策。     

七种染料对鲤鱼肝微粒体芳烃羟化酶的诱导

以鲤鱼肝微粒体为实验体系,研究了七种染料化合物对其芳烃羟化酶（AHH）的诱导,发现七种染料都可诱导AHH的活性,随染料浓度增大AHH的活性升高。七种染料对AHH活性诱导能力大小为：酸性红B＞派拉丁蓝RRN＞普拉红B＞活性艳红K－2BP＞活性艳红K－2G,媒介大红S－80＞分散红E－4B,与其毒性大小相关。     

杭州城区环境空气中二口恶英浓度状况研究

依据2009年7月至2012年2月连续3年对杭州城区环境空气中二英（PCDD/Fs）采样分析结果得知,杭州城区环境空气中二英毒性当量质量浓度变化范围为0.13～0.55 pg TEQ/m³,均值为0.34 pg TEQ/m³。城区环境空气中二英浓度季节变化不显著,夏季略低于冬季;城区范围内不同功能区之间二英浓度差别不显著;连续3年监测结果未显现二英年度变化趋势。沙尘暴天气环境空气中二英浓度显著增高,日常天气和烟花爆竹集中燃放天气环境空气中二英形态分布存在明显区别,烟花爆竹集中燃放期间八氯代二苯并-对-二英（OCDD）占总质量浓度比例显著提高。利用IBM SPSS Statistics 19.0统计软件对24个监测结果聚类分析发现,杭州城区环境空气中二英的同类物分布具有明显的“源”分布特征。     

气相分子吸收光谱法测定印染废水中氨氮的影响因素

采用气相分子吸收法光谱测定印染废水中的氨氮,并对相关影响因素进行探讨。结果证实,硫化物和尿素会对氨氮的测定产生负干扰,硫化物干扰可用乙酸锌-乙酸钠固定液沉淀法去除,尿素干扰可以用稀释法去除,但仅适用于氨氮质量浓度0.10 mg/L且稀释后尿素质量浓度≤100 mg/L的水样;苯胺、浊度和色度对测定无干扰,可直接检测。     

氨基化有机-无机杂化整体柱分离富集环境水中五价砷

将四乙氧基硅烷(TEOS)和N-(β-氨乙基)-γ-氨丙基三乙氧基硅烷(AEAPTES)作为共聚前体,采用在毛细管内原位聚合的方式制备得到氨基功能化的有机-无机杂化整体柱,将其作为针式固相微萃取(SPME)介质,建立了现场分离富集环境水中As(V)的SPME方法,优化了有机-无机杂化整体柱富集As(V)的实验条件,并研究了整体柱对As(V)的吸附/洗脱性能和富集能力,实现了环境水样中As(V)的高效、快速、高选择性检测。     

Assessment of trace element contamination in sediment cores from the Pearl River and estuary,South China: geochemical and multivariate analysis approaches

Twenty-four major and trace elements and the mineralogical composition of four sediment cores along the Pearl River and estuary were analyzed using ICP-AES, ICP-MS, and X-ray diffraction (XRD) to evaluate contamination levels. The dominant minerals were quartz, kaolinite, and illite, followed by montmorillonite and feldspars, while small amounts of halite and calcite were also observed in a few samples. Cluster analysis (CA) and principal component analysis (PCA) were performed to identify the element sources. The highest metal concentrations were found at Huangpu, primarily due to wastewater treatment plant discharge and/or the surreptitious dumping of sludge, and these data differed from those of other sources. Excluding the data from Huangpu, the PCA showed that most elements could be considered as lithogenic; few elements are the combination of lithogenic and anthropogenic sources. An antagonistic relationship between the anthropogenic source metals (K, Ba, Zn, Pb, Cd, Ag, Tl, and U) and marine source metals (Na, Mg, Ti, V, and Ca) was observed. The resulting normalized Al enrichment factor (EF) indicated very high or significant pollution of Cd, Ag, Cu, Zn, Mo, and Pb at Huangpu, which may cause serious environmental effects. Conflicting results between the PCA and EF can be attributed to the background values used, indicating that background values must be selected carefully.     

Fraction characteristics of rare earth elements in the surface sediment of Bohai Bay, North China

Surface sediment samples were collected at 27 stations of Bohai Bay, North China. Sequential extractions were carried out in this study. REE were leached out from four labile fractions: Exchangeable (L1), bound to carbonates (L2), bound to Fe–Mn oxides (L3), bound to organic matter (L4), and the remainder was residual (R5). The total contents of REE fluctuate slightly in Bohai Bay, and are mainly concentrated in the middle region, showing relatively higher levels in the north than that in the south of Bohai Bay. Percentages of L1, L2, L3, L4, and R5 for REE suggest that the residual fraction accounts for the major component of REE, whereas Fe–Mn oxides also play important roles in combining labile REE. As the REE complex is not stabilized, the competition of complex could induce dissociation of the complex and redistribution of the REE in various environments. According to REE patterns and Y/Ho ratios of samples, REE are not anthropogenic or oceanic sources but riverine input, whereas suitable environment varieties can slightly affect the patterns and fractionations of REE. As powerful tracers for the variable of environment, higher anomaly of Eu and Ce in southern regions indicates a greater reduction in the condition of surface sediment in the south than that in the north of Bohai Bay.