Emission factor estimation for oil and gas facilities

Fugitive emission rate quantification in an oil and gas facility is an important step of risk management. There are several studies conducted by the United States Environmental Protection Agency (USEPA) and American Petroleum Institute (API) proposing methods of estimating emission rates and factors. Four major approaches of estimating these emissions, in the order of their accuracy, are: average emission factor approach, screening ranges emission factor approach, USEPA correlation equation approach, and unit-specific correlation equation approach. The focus of this study is to optimize the USEPA correlation equations to estimate the emission rate of different units in an oil and gas facility. In the developed methodology, the data available from USEPA (1995) is used to develop new sets of equations. A comparison between USEPA correlation equations and the proposed equations is performed to define the optimum sets of equations. It is observed that for pumps, flanges, open-ended lines, and others, the proposed developed equations provide a better estimation of emission rate, whereas for other sources, USEPA equations supply the better estimate of emission rate.     

Mercury pollution in the coastal Urmia aquifer in northwestern Iran: potential sources,mobility, and toxicity

Environmental Science and Pollution Research - The concentration of total dissolved mercury (HgT) in surface and groundwater resources in the coastal parts of Urmia aquifer (NW of Iran) was...     

Suspended sediment load prediction based on soft computing models and Black Widow Optimization Algorithm using an enhanced gamma test

Environmental Science and Pollution Research - The suspended sediment load (SSL) prediction is one of the most important issues in water engineering. In this article, the adaptive neuro-fuzzy...     

Selection and performance estimation of Green Lean Six Sigma Projects: a hybrid approach of technology readiness level,data envelopment analysis,and ANFIS

Environmental Science and Pollution Research - Nowadays budget and schedule constraints have forced organizations to select six sigma projects based on pre-defined success criteria. Also,...     

Toxic heavy metals and nutrient concentration in the milk of goat herds in two Iranian industrial and non-industrial zones

Environmental Science and Pollution Research - This work aimed to explore the concentration of nickel, manganese, iron, copper, chromium, and lead in the milk of goat herds in the industrial area...     

Relationship between electric spark sensitivity and activation energy of the thermal decomposition of nitramines for safety measures in industrial processes

This study presents a new simple correlation between electric spark sensitivity of nitramines and their activation energies of thermolysis, which are important for safety measures in industrial processes. The new correlation can help to elucidate the mechanism of initiation of energetic materials by electric spark. It can be used to predict the magnitude of electric spark sensitivity of new nitramines, which is difficult to measure. The methodology assumes that electric spark sensitivity of a nitramine with general formula C_aH_bN_cO_d can be expressed as a function of its activation energy of thermal decomposition as well as optimized elemental composition and the contribution of specific molecular structural parameters. The new correlation has the root mean square and the average deviations of 1.37 and 1.09 J, respectively, for 21 nitramines with different molecular structures. The proposed new method is also tested for 16 nitramines so that there is no experimental data of electrostatic sensitivity for them.     

A heuristic approach to stochastic cutoff grade optimization for open pit mining complexes with multiple processing streams

Cutoff grade specifies the available supply of metallic ore from an open pit mine to the multiple processing streams of an open pit mining complex. An optimal cutoff grade strategy maximizes the net present value (NPV) of an open pit mining operation subject to the mining, processing, and marketing/refining capacity constraints. Even though, the quantities of material flowing from the mine to the market are influenced by the expected variation in the available metal content or inherent uncertainty in the supply of ore, the majority of cutoff grade optimization models not only disregard this aspect and may lead to unrealistic cash flows, but also they are limited in application to an open pit mining operation with single processing facility. The model proposed herein determines the optimal cutoff grade policy based on a stochastic framework that accounts for uncertainty in supply of ore to the multiple ore processing streams. An application on a large-scale open pit mining operation develops a unique cutoff grade policy along with a portfolio of mining, processing, and marketing/refining rates. Owing to the geological uncertainty, the approach addresses risk by showing a difference of 14% between the minimum and maximum production rates, cash flows and NPV.     

Underutilization of occupant restraint systems in motor vehicle injury crashes: A quantitative analysis from Qatar

Introduction: Restraint systems (seat belts and airbags) are important tools that improve vehicle occupant safety during motor vehicle crashes (MVCs). We aimed to identify the pattern and impact of the utilization of passenger restraint systems on the outcomes of MVC victims in Qatar.

Methods: A retrospective study was conducted for all admitted patients who sustained MVC-related injuries between March 2011 and March 2014 inclusive.

Results: Out of 2,730 road traffic injury cases, 1,830 (67%) sustained MVC-related injuries, of whom 88% were young males, 70% were expatriates, and 53% were drivers. The use of seat belts and airbags was documented in 26 and 2.5% of cases, respectively. Unrestrained passengers had greater injury severity scores, longer hospital stays, and higher rates of pneumonia and mortality compared to restrained passengers (P = .001 for all). There were 311 (17%) ejected cases. Seat belt use was significantly lower and the mortality rate was 3-fold higher in the ejected group compared to the nonejected group (P = .001). The overall mortality was 8.3%. On multivariate regression analysis, predictors of not using a seat belt were being a front seat passenger, driver, or Qatari national and young age. Unrestrained males had a 3-fold increase in mortality in comparison to unrestrained females. The risk of severe injury (relative risk [RR] = 1.82, 95% confidence interval [CI], 1.49–2.26, P = .001) and death (RR = 4.13, 95% CI, 2.31–7.38, P = .001) was significantly greater among unrestrained passengers.

Conclusion: The nonuse of seat belts is associated with worse outcomes during MVCs in Qatar. Our study highlights the lower rate of seat belt compliance in young car occupants that results in more severe injuries, longer hospital stays, and higher mortality rates. Therefore, we recommend more effective seat belt awareness and education campaigns, the enforcement of current seat belt laws, their extension to all vehicle occupants, and the adoption of proven interventions that will assure sustained behavioral changes toward improvements in seat belt use in Qatar.