Sonocatalytic degradation of tetracycline antibiotic in aqueous solution by sonocatalysis

Tetracycline (TC), one of the most common antibiotics, is often poorly bio-degraded in conventional wastewater treatment plants. In this study, the sonocatalytic degradation of TC was investigated using TiO₂ nano-particles as catalyst. The effect of pH, initial TC concentrations, reaction times, and H₂O₂ concentrations were evaluated. The efficacy of ultrasonic irradiation alone in the removal of this pollutant was negligible but removal efficiency increased upon addition of TiO₂ up to 250 mg L^?1; increase of pH and initial TC concentration attenuated TC degradation. Addition of H₂O₂ raised the removal efficiency so that complete removal of TC was achieved within 75 min.     

The Toxicology of Silica Nanoparticles: A Review

Silica nanoparticles are increasingly used in industrial, cosmetics, and medical applications. Workers in nanosilica production industries, laboratory personnel in drug production industries, patients taking drugs with nanosilica in its formulations, and everyone in society who uses cosmetics are potentially at risk to health effects induced by silica nanoparticles. Like other nanomaterials, nanosilica has unique physical and chemical properties that modify its toxic effects compared to bulk silica or microparticles of silica. Nanosilica toxicology has been studied by various in vitro and in vivo protocols and on humans, studies which are collected and summarized in the present publication. The toxic effects are outlined based on the type of body compartment, viz. cardiovascular, dermal, respiratory, neural, hepatic, genetic, immune, reproductive, and renal system. Further information, especially the experimental protocols and toxicological endpoints, are summarized in tables.     

Synthesis and antithyroid activity of 6‐n‐propyl‐5‐arylazo‐2‐thiouracils †

The synthesis of several 6‐n‐propyl‐5‐arylazo‐2‐thiouracil derivatives was achieved. The antithyroid activity of these derivatives has been determined using iodine‐125‐thiocyanate discharge technique in rats, and 6‐n‐propyl‐2‐thiouracil (PTU) as a standard. None of the 5‐arylazo‐2‐thiouracil analogs showed antithyroid activity as compared to PTU. The structure‐activity relationships (SAR) of position 5 in the PTU molecule and the requirements for better binding to the proposed receptor are discussed.     

Experimental degradation of oil in permeable sand from the Gulf of Aqaba,Red Sea

Degradation rates of light and heavy oil in permeable carbonate sands from the Gulf of Aqaba were investigated to evaluate the ability of sediments to degrade oil compounds. Silicate sands that are less permeable and different properties from carbonate sands were used for comparison. Estimates of oil degradation rates were based on oxygen consumption rates, calculated by incubating natural carbonate sands with oil. The degradation rates of light oil were twofold higher than those of heavy oil, which may be attributed to the presence of a higher carbon number in heavy oil compared with light oil. Degradation rates of light oil in carbonate sands were twofold higher than in silicate sands. Oil degradation rates calculated using the bottle incubation technique were three- to fourfold higher than rates from chamber incubations, indicating the importance of adequate mixing between oil particles and sediments during degradation processes. This study suggests that permeable sands, through their chemical and physical properties, increase oil biodegradation rates by enhancing flow through sediment particles and positively impacting bioturbation processes.     

Heavy metals in water, sediments, plants and fish of Kali Nadi U.P. (India)

The distribution of heavy metals viz., Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn in the water, sediments, plants and fish samples collected from the Kali Nadi (India) have been determined. The studies have shown that there was considerable variation in the concentration of heavy metals from one sampling station to the other which may be due to the variation in the quality of industrial and sewage wastes being added to the river at different places. The orders of the concentration of heavy metals in water, sediments, plants (Eicchornia crassipes) and fish (Heteropnuestes fossilis) were Fe > Zn > Cu > Mn > Cr > Ni > Pb > Co > Cd; Fe > Zn > Mn > Ni > Cr > Co > Cu > Pb > Cd; Fe > Mn > Zn > Cu > Ni > Co > Pb > Cr > Cd and Fe > Zn > Mn > Ni > Pb > Co > Cr > Cu > Cd, respectively.     

Future production of rainfed wheat in Iran (Khorasan province): climate change scenario analysis

Projecting staple crop production including wheat under future climate plays a fundamental role in planning the required adaptation and mitigation strategies for climate change effects especially in developing countries. The main aim of this study was to investigate the direction and magnitude of climate change impacts on grain yield of rainfed wheat (Triticum aestivum L.) production and precipitation within growing season. This study was performed for various regions in Khorasan province which is located in northeast of Iran. Climate projections of two General Circulation Models (GCM) for four locations under three climate change scenarios were employed in this study for different future time periods. A stochastic weather generator (LARS-WG5) was used for downscaling to generate daily climate parameters from GCMs output. The Decision Support System for Agrotechnology Transfer (DSSAT) Version 4.5 was employed to evaluate rainfed wheat performance under future climate. Grain yield of rainfed wheat and precipitation during growth period considerably decreased under different scenarios in various time periods in contrast to baseline. Highest grain yield and precipitation during growth period was obtained under B1 scenario but A1B and A2 scenarios resulted in sharp decrease (by ?57 %) of grain yield. Climate change did not have marked effects on evapotranspiration during the rainfed wheat growth. A significant correlation was detected between grain yield, precipitation and evapotranspiration under climate change for both GCMs and under all study scenarios. It was concluded, that rainfed wheat production may decline during the next 80 years especially under A2 scenario. Therefore, planning the comprehensive adaptation and mitigation program is necessary for avoiding climate change negative impact on rainfed wheat production.     

Fungicide tolerant Bradyrhizobium japonicum mitigate toxicity and enhance greengram production under hexaconazole stress

Bacterial strain RV9 recovered from greengram nodules tolerated 2400 μg/mL of hexaconazole and was identified by 16 S rDNA sequence analysis as Bradyrhizobium japonicum(KY940048). Strain RV9 produced IAA(61.6 μg/mL), ACC deaminase(51.7 mg/(protein·hr)), solubilized TCP(105 μg/mL), secreted 337.6 μg/mL EPS, and produced SA(52.2 μg/mL) and 2,3-DHBA(28.3 μg/mL). Exopolysaccharides produced by strain RV9 was quantified and characterized by SEM, AFM, EDX and FTIR. Beyond tolerance limit,hexaconazole caused cellular impairment and reduced the viability of strain RV9 revealed by SEM and CLSM. Hexaconazole distorted the root tips and altered nodule structure leading thereby to reduction in the performance of greengram. Also, the level of antioxidant enzymes, proline, TBARS, ROS and cell death was increased in hexaconazole treated plants.CLSM images revealed a concentration dependent increase in the characteristic green and blue fluorescence of hexaconazole treated roots. The application of B. japonicum strain RV9 alleviated the fungicide toxicity and improved the measured plant characteristics. Also,rhizobial cells were localized inside tissues as revealed by CLSM. Colonization of B.japonicum strain RV9 decreased the levels of CAT, POD, APX, GPX and TBARS by 80%, 5%,13%, 13% and 19%, respectively over plants grown at 80 μg/(hexaconazole·kg) soil. The ability to detoxify hexaconazole, colonize plant tissues, secrete PGP bioactive molecules even under fungicide pressure and its unique ability to diminish oxidative stress make B.japonicum an attractive choice for remediation of fungicide polluted soils and to concurrently enhance greengram production under stressed environment.     

Consumption-based CO2 emissions accounting and scenario simulation in Asia and the Pacific region

Environmental Science and Pollution Research - This study uses a consumer-based accounting approach to evaluate the CO2 emission factors of 17 countries in Asia and the Pacific region by including...