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681.
Shabnam Shahida Akbar Ali Muhammad Haleem Khan Muhammad Mufazzal Saeed 《Environmental monitoring and assessment》2013,185(2):1613-1626
In this work, spectrophotometer was used as a detector for the determination of uranium from water, biological, and ore samples with a flow injection system coupled with solid phase extraction. In order to promote the online preconcentration of uranium, a minicolumn packed with XAD-4 resin impregnated with nalidixic acid was utilized. The system operation was based on U(VI) ion retention at pH 6 in the minicolumn at flow rate of 15.2 mL min?1. The uranium complex was removed from the resin by 0.1 mol dm?3 HCl at flow rate of 3.2 mL min?1 and was mixed with arsenazo III solution (0.05 % solution in 0.1 mol dm?3 HCl, 3.2 mL min?1) and driven to flow through cell of spectrophotometer where its absorbance was measured at 651 nm. The influence of chemical (pH and HCl (as eluent and reagent medium) concentration) and flow (sample and eluent flow rate and preconcentration time) parameters that could affect the performance of the system as well as the possible interferents was investigated. At the optimum conditions for 60 s preconcentration time (15.2 mL of sample volume), the method presented a detection limit of 1.1 μg L?1, a relative standard deviation (RSD) of 0.8 % at 100 μg L?1, enrichment factor of 30, and a sample throughput of 42 h?1, whereas for 300 s of the preconcentration time (76 mL of sample volume), a detection limit of 0.22 μg L?1, a RSD of 1.32 % at 10 μg L?1, enrichment factor of 150, and a sampling frequency of 11 h?1 were reported. 相似文献
682.
683.
A simple GC method for simultaneous determination of pivaloylchloride, methylacetoacetate, ethylacetoacetate and 2-ethylhexanoic acid in the presence of each other has been developed using glass column packed with 1% Silicone OV-17 on Gaschrom Q 100-120 mesh with temperature programming. Various performance parameters including precision, linearity and limit of detection have been evaluated. The method was found to be suitable for the analysis of these chemicals in in-process materials and effluents associated with the manufacture of amoxicillin and ampicillin. The run time was less than 15 min. The method has been successfully applied to determine the level of these hazardous organic liquids in real time samples. 相似文献
684.
Vishandas Suthar Kazi Suleman Memon Muhammad Mahmood-ul-Hassan 《Environmental monitoring and assessment》2014,186(6):3957-3968
Natural and chemically enhanced phytoextraction potentials of maize (Zea mays L.) and sesbania (Sesbania aculeata Willd.) were explored by growing them on two soils contaminated with heavy metals. The soils, Gujranwala (fine, loamy, mixed, hyperthermic Udic Haplustalf) and Pacca (fine, mixed, hyperthermic Ustollic Camborthid), were amended with varying amounts of ethylenediaminetetraacetic acid (EDTA) chelating agent, at 0, 1.25, 2.5, and 5.0 mM kg?1 soil to enhance metal solubility. The EDTA was applied in two split applications at 46 and 60 days after sowing (DAS). The plants were harvested at 75 DAS. Addition of EDTA significantly increased the lead (Pb) and cadmium (Cd) concentrations in roots and shoots, uptake, bioconcentration factor, and phytoextraction rate over the control. Furthermore, addition of EDTA also significantly increased the soluble fractions of Pb and Cd in soil over the controls; the maximum increase of Pb and Cd was 13.1-fold and 3.1-fold, respectively, with addition of 5.0 mM EDTA kg?1soil. Similarly, the maximum Pb and Cd root and shoot concentrations, translocation, bioconcentration, and phytoextraction efficiency were observed at 5.0 mM EDTA kg?1 soil. The results suggest that both crops can successfully be used for phytoremediation of metal-contaminated calcareous soils. 相似文献
685.
Hasan Muhammad Abdullah M. Golam Mahboob Mehmuna R. Banu Dursun Zafer Seker 《Environmental monitoring and assessment》2013,185(5):3839-3851
The vast coastal and marine resources that occur along the southern edge of Bangladesh make it one of the most productive areas of the world. However, due to growing anthropogenic impacts, this area is under considerable environmental pressure from both physical and chemical stress factors. Ship breaking, or the dismantling and demolition of out-of-service ocean-going vessels, has become increasingly common in many coastal areas. To investigate the extent of ship breaking activities in Bangladesh along the Sitakunda coast, various spatial and non-spatial data were obtained, including remote sensing imagery, statistical records and published reports. Impacts to coastal and marine life were documented. Available data show that ship breaking activities cause significant physical disturbance and release toxic materials into the environment, resulting in adverse effects to numerous marine taxonomic groups such as fish, mammals, birds, reptiles, plants, phytoplankton, zooplankton and benthic invertebrates. Landsat imagery illustrates that the negatively impacted coastal area has grown 308.7 % from 367 ha in 1989 to 1,133 ha in 2010. Physicochemical and biological properties of coastal soil and water indicate substantially elevated pollution that poses a risk of local, regional and even global contamination through sea water and atmospheric transport. While damage to the coastal environment of Bangladesh is a recognized hazard that must be addressed, the economic benefits of ship breaking through job creation and fulfilling the domestic demand for recycled steel must be considered. Rather than an outright ban on beach breaking of ships, the enterprise must be recognized as a true and influential industry that should be held responsible for developing an economically viable and environmentally proactive growth strategy. Evolution of the industry toward a sustainable system can be aided through reasonable and enforceable legislative and judicial action that takes a balanced approach, but does not diminish the value of coastal conservation. 相似文献
686.
687.
The term “phytoremediation” is used to describe the cleanup of heavy metals from contaminated sites by plants. This study
demonstrates phytoremediation potential of Indian mustard (Brasicca juncea (L.) Czern. & Coss.) genotypes for chromium (Cr). Seedlings of 10 genotypes were grown hydroponically in artificially contaminated
water over a range of environmentally relevant concentrations of Cr (VI), and the responses of genotypes in the presence of
Cr, with reference to Cr accumulation, its phytotoxity and anti-oxidative system were investigated. The Cr accumulation potential
varied largely among Indian mustard genotypes. At 100 μM Cr treatment, Pusa Jai Kisan accumulated the maximum amount of Cr
(1680 μg Cr g−1 DW) whereas Vardhan accumulated the minimum (107 μg Cr g−1 DW). As the tolerance of metals is a key plant characteristic required for phytoremediation purpose, effects of various levels
of Cr on biomass were evaluated as the gross effect. The extent of oxidative stress caused by Cr stress was measured as rate
of lipid peroxidation. The level of thiobarbituric acid reactive substances (TBARS) was enhanced at all Cr treatments when
compared to the control. Inductions of enzymatic and nonenzymatic antioxidants were monitored as metal-detoxifying responses.
All the genotypes responded to Cr-induced oxidative stress by modulating nonenzymatic antioxidants [glutathione (GSH) and
ascorbate (Asc)] and enzymatic antioxidants [superoxide dismutase (SOD), ascorbate peroxidase (APX), and glutathione reductase
(GR)]. The level of induction, however, differed among the genotypes, being at its maximum in Pusa Jai Kisan and its minimum
in Vardhan. Pusa Jai Kisan was grown under natural field conditions with various Cr treatments, and Cr-accumulation capacity
was studied. The results confirmed that Pusa Jai Kisan is a hyperaccumulator of Cr and hypertolerant to Cr-induced stress,
which makes this genotype a viable candidate for use in the development of phytoremediation technology of Cr-contaminated
sites. 相似文献
688.
Alnawajha Mohammad Mohammad Kurniawan Setyo Budi Imron Muhammad Fauzul Abdullah Siti Rozaimah Sheikh Hasan Hassimi Abu Othman Ahmad Razi 《Environmental science and pollution research international》2022,29(39):58430-58453
Environmental Science and Pollution Research - The increasing intensification of the aquaculture industry requires the development of new strategies to reduce the negative impacts of wastewater on... 相似文献
689.
Ali Iftikhar Khan Muhammad Jamil Shah Azizullah Deeba Farah Hussain Haziq Yazdan Fazal Khan Mati Ullah Khan Muhammad Daud 《Environmental science and pollution research international》2022,29(25):37765-37776
Environmental Science and Pollution Research - Natural resources, especially agrarian soils, have been much contaminated with various pollutants including heavy metals since industrial revolution,... 相似文献
690.
Musa Mohammad Yi Lan Rahman Preethu Ali Muhammad Abu Sufyan Yang Li 《Environmental science and pollution research international》2022,29(58):87361-87379
Environmental Science and Pollution Research - Anthropogenic and natural factors lead to substantial environmental degradation. This shift is aligned with the country's overall development,... 相似文献