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901.
Concentration of heavy metals (Cd, Ni, Zn, Fe, Cu, Mn, Pb, Cr, Hg and As) in the waters of River Yamuna and in the soil of
agricultural fields along its course in Delhi are reported from 13 sites, spread through the Delhi stretch of Yamuna, starting
from the Wazirabad barrage till the Okhla barrage. Varying concentration of heavy metals was found. Peaks were observed in
samples collected downstream of Wazirabad and Okhla barrage, indicating the anthropogenic nature of the contamination. The
Wazirabad section of the river receives wastewater from Najafgarh and its supplementary drains, whereas the Shahdara drain
releases its pollution load upstream of the Okhla barrage. Average heavy metal concentration at different locations in the
river water varied in the order of Fe>Cr>Mn>Zn>Pb>Cu>Ni>Hg>As>Cd. The river basin soil shows higher level of contamination
with lesser variation than the water samples among sampling locations, thereby suggesting deposition over long periods of
time through the processes of adsorption and absorption. The average heavy metal concentration at different locations in soil
varied in the order of Fe>Mn>Zn>Cr>Pb>Ni>Hg>Cu>As>Cd. 相似文献
902.
de-la-Ossa-Carretero JA Del-Pilar-Ruso Y Giménez-Casalduero F Sánchez-Lizaso JL 《Environmental monitoring and assessment》2012,184(4):2133-2149
Physicochemical characteristics of sediment and benthic communities were studied in the proximity of seven sewage outfalls
with differences in flow and wastewater treatment in the Western Mediterranean Sea. Redox potential was the only abiotic parameter
which showed a pattern related with distance to outfalls, whereas granulometry, percentage of organic matter, metal concentrations
or pH did not show changes related with outfall presence. Benthic community analysis proved to be the most suitable monitoring
tool. The results showed that the highest impacted stations corresponded with those closest to outfall with the highest flow
and only pre-treatment, whilst a decrease of this tendency was detected in the locations where secondary treatment takes place.
Meta-analysis showed a decrease of amphipods and tanaids abundance as well as redox potential, as the indicators with the
clearest response to sewage presence. 相似文献
903.
The chemical forms and ecological risk of As were characterized in the sediment of the Daliao River System (DRS), which has
been affected by long-term intensive industrial, urban, and agricultural activities. Twenty-seven samples of surface sediment
were collected and analyzed for total As content and that of its chemical forms. The results indicated that the average total
As content in the sediment was 9.83 mg kg − 1 but that the levels ranged from 1.57 to 83.09 mg kg − 1. At the sites near cities, mining sites, and the estuary of the DRS, it is likely that adverse effects on aquatic organisms
occur, due to As levels in the sediment that are often higher than the threshold effect level and occasionally higher than
the probable effect level. A selectively sequential extraction indicated that the majority of As in the sediment was bound
to Fe oxides (62.1%), with moderate proportions of residual As (19.8%), specifically adsorbed As (17.9%), and a low proportion
of non-specifically adsorbed As (1.1%). In addition, the content of Fe in the sediment was positively and significantly correlated
with the contents of amorphous and crystalline Fe oxide-bound As, confirming the crucial role of Fe oxides in immobilizing
high amounts of As in superficial environments. The average molar ratio of As to Fe was 1.18 × 10 − 4 in the surface sediment of the DRS, similar to that of natural Fe oxides, but much lower than that of synthesized Schwertmannite.
Therefore, the release of As under reduced and low pH conditions can cause serious problems for water resources and for living
organisms. 相似文献
904.
The analysis of heavy metals is very important for assessing the feasibility of the agricultural utilization for the municipal
sludge. In this paper, a four-step sequential extraction method was applied to extract heavy metals (Cu, Zn, Mn, Cr, and Ni)
in municipal sludges from seven individual wastewater treatment plants located in Jilin and Heilongjiang Province, China,
for estimating the mobility and bioavailability of the metal ions in the agricultural application. The total concentrations
of heavy metals and their chemical fractions after the sequential extraction were determined. Principal component analysis
(PCA) was applied to analyze the relations of heavy metals fractions in the municipal sludges. Experimental results indicated
that the total concentrations of Cu, Zn, Cr, and Ni in all sludge samples were below the threshold values set out by the Chinese
legislation (GB18918-2002). Specially, Zn had a high bioavailability and mobility, Cu and Cr had potential bioavailability,
while Mn mainly existed in the residual fraction of municipal sludge. On the other hand, Ni had different mobility in different
municipal sludge. PCA results were confirmed by the environmental behavior of heavy metals. 相似文献
905.
Warren C Duzgoren-Aydin NS Weston J Willett KL 《Environmental monitoring and assessment》2012,184(2):1107-1119
Hurricanes are relatively frequent ecological disturbances that may cause potentially long-term impacts to the coastal environment.
Hurricane Katrina hit the Mississippi Gulf Coast in August 2005, and caused a storm surge with the potential to change the
trace element content of coastal surface sediments. In this study, surface estuarine and marine sediments were collected monthly
following the storm from ten sites along the Mississippi Gulf Coast (Mobile Bay, Grand Bay Bayous Heron and Cumbest, Pascagoula,
Ocean Springs, Biloxi Gulf, Back Biloxi Bay, Gulfport Gulf, Gulfport Courthouse Rd, and Gulfport Marina). Concentrations of
V, Cr, Mn, Fe, Co, Ni, Zn, As, Cd, and Pb were measured by inductively coupled plasma–mass spectrometry to evaluate their
temporal and spatial variations in the year following Hurricane Katrina. Sediments were characterized by pH, particle size
distribution and total carbon and nitrogen content. Trace element contents of the sediments were determined in both <2 mm
and <63 μm grain size fractions. Results revealed no significant temporal and spatial variability in trace element concentrations,
in either size fraction. Potential ecological risk of the sediments was assessed by using NOAA SQuiRTs’ guideline values;
most concentrations remained below probable adverse effects guidelines to marine organisms suggesting that trace elements
redistributed by Hurricane Katrina would not cause an adverse impact on resident organisms. Instead, the concentrations of
trace elements were site-dependent, with specific contaminants relating to the use of the area prior to Hurricane Katrina. 相似文献
906.
Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation
and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish
Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The
activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate
dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase
and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma
vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence
of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons
of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics,
namely xenoestrogens and acetylcholinesterase-inhibiting agents. 相似文献
907.
T. R. Gireeshkumar P. M. Deepulal N. Chandramohanakumar 《Environmental monitoring and assessment》2013,185(3):2535-2552
Sequential chemical extraction using chelating agents were used to study the P dynamics and its bioavailability along the surface sediments of the Cochin estuary (southwest coast of India). Sediments were analyzed for major P species (iron bound P, calcium bound P, acid soluble organic P, alkali soluble organic P and residual organic P), Fe, Ca, total carbon, organic carbon, total nitrogen and total sulfur contents. An abrupt increase in the concentration of dissolved inorganic P with increasing salinity was observed in the study region. Iron-bound P exhibited a distinct seasonal pattern with maximum values in the monsoon season when fresh water condition was prevailed in the estuary. As salinity increased, the percentage of iron-bound P decreased, while that of calcium-bound P and total sedimentary sulfur increased. C/P and N/P ratios were low which indicate that large amounts of organic matter enriched with P tend to accumulate in surface sediments. The high organic P contribution in the sedimentary P pool may indicate high organic matter load with incomplete mineralization, as well as comparatively greater percentage of humic substance and resistant organic compounds. Principal component analysis is employed to find the possible processes influencing the speciation of P in the study region and indicate the following processes: (1) the spatial and seasonal variations of calcium bound P and acid soluble organic P was mainly controlled by sediment texture and organic carbon content, (2) sediment redox conditions control the distribution of iron bound P and (3) the terrigenous input of organic P is a significant processes controlling total P content in surface sediments. The bioavailable P was very high in the surface sediments which on an average accounts for 59 % in the pre-monsoon, 65 % in the monsoon and 53 % in the post-monsoon seasons. The surface sediments act as a potential internal source of P in the Cochin estuary. 相似文献
908.
C. Kesavachandran B. S. Pangtey V. Bihari M. Fareed M. K. Pathak A. K. Srivastava N. Mathur 《Environmental monitoring and assessment》2013,185(2):1265-1272
The World Health Organization has estimated that air pollution is responsible for 1.4 % of all deaths and 0.8 % of disability-adjusted life years. NOIDA, located at the National Capital Region, India, was declared as one of the critically air-polluted areas by the Central Pollution Control Board of the Government of India. Studies on the relationship of reduction in lung functions of residents living in areas with higher concentrations of particulate matter (PM) in ambient air were inconclusive since the subjects of most of the studies are hospital admission cases. Very few studies, including one from India, have shown the relationship of PM concentration and its effects of lung functions in the same location. Hence, a cross-sectional study was undertaken to study the effect of particulate matter concentration in ambient air on the lung functions of residents living in a critically air-polluted area in India. PM concentrations in ambient air (PM1, PM2.5) were monitored at residential locations and identified locations with higher (NOIDA) and lower concentrations (Gurgaon). Lung function tests (FEV1, PEFR) were conducted using a spirometer in 757 residents. Both air monitoring and lung function tests were conducted on the same day. Significant negative linear relationship exists between higher concentrations of PM1 with reduced FEV1 and increased concentrations of PM2.5 with reduced PEFR and FEV1. The study shows that reductions in lung functions (PEFR and FEV1) can be attributed to higher particulate matter concentrations in ambient air. Decline in airflow obstruction in subjects exposed to high PM concentrations can be attributed to the fibrogenic response and associated airway wall remodeling. The study suggests the intervention of policy makers and stake holders to take necessary steps to reduce the emissions of PM concentrations, especially PM1, PM2.5, which can lead to serious respiratory health concerns in residents. 相似文献
909.
Nédia de Castilhos Ghisi Marta Margarete Cestari 《Environmental monitoring and assessment》2013,185(4):3201-3207
The glyphosate-based herbicide, Roundup®, is one of the most used pesticides worldwide. In concert with the advent of transgenic crops resistant to glyphosate, the use of this pesticide has led to an increase in agricultural yields. The objective of this study was to evaluate the genotoxic effect that the herbicide Roundup® (at a concentration of 6.67 μg/L, corresponding to 3.20 μg/L glyphosate) can have on the fish Corydoras paleatus. Treatment groups were exposed for 3, 6, and 9 days, and effects were analyzed using the piscine micronucleus test (PMT) and comet assay. A group subjected to filtered water only was used as a negative control. The PMT did not show differences between the control and exposed groups for any of the treatment times. In contrast, the comet assay showed a high rate of DNA damage in group exposed to Roundup® for all treatment times, both for blood and hepatic cells. We conclude that for the low concentration used in this research, the herbicide shows potential genotoxic effects. Future research will be important in evaluating the effects of this substance, whose presence in the environment is ever-increasing. 相似文献
910.
Majid Soleimani Lope G. Tabil Ike Oguocha Jimmy Fung 《Journal of Polymers and the Environment》2018,26(2):532-542
The objective of this work was to improve the impact and thermal properties of polylactic acid (PLA)-based biocomposite by appropriate application of cellulosic fiber and a bioelastomer. Biocomposites formulations with fiber contents of up to 20% in combination with a bioelastomer were extrusion-compounded in a twin-screw extruder followed by molding in an injection molding system. Fibers used in the formulations included three types of cellulosic fiber; namely, raw fiber from oat hull biomass (RF), hydrolysis byproduct (ATF) which was the solid fraction obtained from an acid-catalyzed hydrolysis of RF, and delignified fibers (AD30, AD65, AD100) which were the products of delignification of ATF. Formulated biocomposites were characterized for thermal (glass transition and melting temperatures, and enthalpy of melting) and physico-mechanical (tensile and bending strengths, stiffness, impact energy, and water absorption) properties. Among all types of biofibers, RF resulted in poor properties in the biocomposites due to the high hemicellulose content in the structure. On the other hand, the ratio of lignin to cellulose (in the absence of hemicellulose) in the modified fibers did not significantly affect the physico-mechanical and thermal properties of the biocomposites. The elastomer applied in the formulations improved the impact energy, thermal properties, and elongation at break of the composites. However, it adversely affected the strength and water resistance of biocomposites, especially in the presence of hemicellulose. The results indicated that, depending on the application, a wide range of PLA green composites with different physico-mechanical properties can be achieved. 相似文献