复合生物法净化SVE尾气研究

鉴于目前土壤修复过程中广泛采用的气相抽提系统技术(SVE)相应尾气净化技术的缺失,为有效提高气相抽提系统技术后端尾气净化效率,提出采用复合生物法净化SVE尾气。以甲苯为目标污染物,以活性炭为主要填料,利用焦化污水处理厂的活性污泥接种挂膜研究了生物过滤反应器对模拟气体的净化性能及其影响因素(包括进气流量、停留时间、入口浓度、入口体积负荷),并将复合生物法与活性炭吸附法进行了性能比较。实验结果表明:生物过滤反应器的去除效率随进气流量的增大而降低,随气体停留时间的延长而提高,随入口浓度的增大而降低,反应器的体积去除负荷随入口体积负荷的增大而增大,这说明生物过滤反应器能有效去除甲苯废气,且去除效果优于活性炭吸附法。     

UASB-曝气法应用于饮料废水中出现的问题及分析

UASB-曝气法应用在饮料废水处理的前期运行良好,但运行后期出现了出水不达标的异常现象,通过运行数据和UASB常见问题的分析,发现使系统出现异常的原因是UASB反应器内部腐蚀、三相分离器不完善等的常见问题。针对这些问题提出了相应的解决措施和二次启动厌氧池的建议,以使该系统恢复运行效果。     

地铁站台导流栏杆对人员疏散的影响研究

为研究地铁站台导流栏杆对人员疏散的影响,以某地铁车站为研究对象,采用数值模拟方法研究地铁站台导流栏杆的设置方式及长度对人员疏散的影响,为地铁车站导流栏杆的设置及优化提供参考。研究结果表明:随着固定导流栏杆长度的增加,人员疏散时间呈现增加趋势,固定导流栏杆长度为14 m时比不设导流栏杆时疏散效率降低了20.8%,人员在长度为14 m的固定导流栏杆内呈现通道型排队现象;随着可推拉导流栏杆长度的增加,人员疏散时间呈现减小趋势,可推拉导流栏杆长度为6 m时比固定导流栏杆长度为14 m时的疏散效率提高了9.7%。     

Maize tassel-modified carbon paste electrode for voltammetric determination of Cu(II)

The preparation and application of a practical electrochemical sensor for environmental monitoring and assessment of heavy metal ions in samples is a subject of considerable interest. In this paper, a carbon paste electrode modified with maize tassel for the determination of Cu(II) has been proposed. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were used to study morphology and identify the functional groups on the modified electrode, respectively. First, Cu(II) was adsorbed on the carbon paste electrode surface at open circuit and voltammetric techniques were used to investigate the electrochemical performances of the sensor. The electrochemical sensor showed an excellent electrocatalytic activity towards Cu(II) at pH 5.0 and by increasing the amount of maize tassel biomass, a maximum response at 1:2.5 (maize tassel:carbon paste; w/w) was obtained. The electrocatalytic redox current of Cu(II) showed a linear response in the range (1.23 μM to 0.4 mM) with the correlation coefficient of 0.9980. The limit of detection and current–concentration sensitivity were calculated to be 0.13 (±0.01) μM and 0.012 (±0.001) μA/μM, respectively. The sensor gave good recovery of Cu(II) in the range from 96.0 to 98.0 % when applied to water samples.     

Impact of chlorine exposure time on disinfection byproduct formation in the presence of iopamidol and natural organic matter during chloramination

Chloramines,in practice,are formed onsite by adding ammonia to chlorinated drinking water to achieve the required disinfection.While regulated disinfection byproducts(DBPs)are reduced during chloramine disinfection,other DBPs such as iodinated(iodo-)DBPs,that elicit greater toxicity are formed.The objective of this study was to investigate the impact of prechlorination time on the formation of both halogen-specific total organic halogen(TOX)and iodo/chlorinated(chloro-)DBPs during prechlorination/chloramination in source waters(SWs)containing iopamidol,an X-ray contrast medium.Barberton SW(BSW)and Cleveland SW(CSW)containing iopamidol were prechlorinated for 5–60 min and afterwards chloraminated for 72 hr with ammonium chloride.Chlorine contact time(CCT)did not significantly impact total organic iodine(TOI)concentrations after prechlorination or chloramination.Concentrations of total organic chlorine(TOCl)formed during prechlorination did not significantly change regardless of pH and prechlorination time,whileTOClappearedtodecreaseafter 72 hrchloraminationperiod.Dichloroiodomethane(CHCl_2I)formation during prechlorination did not exhibit any significant trends as a function of p H or CCT,but after chloramination,significant increases were observed at pHs 6.5 and 7.5 with respect to CCT.Iodo-HAAs were not formed during prechlorination but were detected after chloramination.Significant quantities of chloroform(CHCl_3)and trichloroacetic acid(TCAA)were formed during prechlorination but formation ceased upon ammonia addition.Therefore,prechlorination studies should measure TOX and DBP concentrations prior to ammonia addition to obtain data regarding the initial conditions.     

2000-2009年安徽省能源消费与碳排放分析

根据联合国政府气候变化专门委员会(IPCC)2006年版碳排放指南中的计算公式和碳排放系数缺省值,计算了安徽省2000年-2009年能源消费和碳排放情况。结果表明:安徽省能源消费由2000年的4878.82万t标准煤增长到2009年的8895.90万t标准煤,平均年增长率为6.9%,其中第二产业部门能源消费量均占能源消费总量的79%以上;能源消费产生的二氧化碳由2000年的4107.48万t增长到2009年的8536.12万t,其中在各种能源消费碳排放量中原煤的碳排放量最大,占总碳排放量的77%82%;碳排放强度总体上呈现下降的趋势,低于全国平均碳排放强度,但高于全球和美国;碳排放的因素分析得出碳排放量与人口、人均GDP、能源强度呈现高度相关性。     

The effects of fipronil exposure on oxidative stress,non-specific immunity,autophagy, and apoptosis in the common carp

Environmental Science and Pollution Research - The increase in the area treated with the insecticide fipronil has caused concern for aquatic organisms such as fish. Here, we assessed the effect of...     

Polystyrene microplastics induce blood–testis barrier disruption regulated by the MAPK-Nrf2 signaling pathway in rats

Environmental Science and Pollution Research - As a persistent pollutant, microplastics (MPs) have been reported to induce sperm quantity decrease in mice. However, the related mechanism remains...     

Exploring the interactive coupled relationship between urban construction and resource environment in Wuhan,China

Environment, Development and Sustainability - Megacities are facing internal and external constraints and challenges with the accelerated urbanization. Urbanization can provide convenient and...     

铅迫胁下黄瓜幼苗期叶片内源激素的变化

土壤中的重金属污染会对植物造成伤害,在细胞内重金属离子会通过不同途径干扰和破坏细胞的正常代谢。植物激素能调节和控制植物的生长和发育。以黄瓜(Cucumis sativus L.)为材料,通过人工模拟重金属污染环境,对不同质量浓度铅胁迫下黄瓜幼苗的叶片,采用高效液相色谱法进行生长素(IAA)、细胞分裂素(Z)、赤霉素(GA3)、脱落酸(ABA)的分离、纯化和测定。探讨重金属污染对植物内源激素水平方面的变化的影响,进一步了解重金属污染对植物产生伤害的机制及抵御胁迫所发生的变化,从而采取有效措施解决重金属污染的问题。结果发现:所测的几种激素均表现出明显的变化规律:GA3、ABA升高,IAA、Z含量先上升后下降;同时经比较分析得出,随着铅质量浓度的增大,IAA/ABA、Z/ABA及GA3/ABA之比下降,Z/IAA升高。结果表明黄瓜幼苗期抵抗重金属污染的能力与内源激素水平及内源激素平衡有关。