WATER SUPPLY AS A LIMITING FACTOR IN WESTERN ENERGY DEVELOPMENT1

ABSTRACT: This paper discusses the consumptive water needs of the various energy conversion processes including oil shale retorting, coal gasification and liquefaction, electric power generation, and slurry pipelines. Projected energy development water needs in the upper Colorado River and Upper Missouri River basins are compared with projected agricultural needs and water available. The comparative cost and values of water to energy and agricultural development are discussed to emphasize this as well as the political and social factors entering into the picture.     

BACTERIAL RELATIONSHIPS IN STORMWATERS1

ABSTRACT: Data were developed within a three-year period for indicator bacteria and three species of bacterial pathogens following rural storm event hydrographs. The first flush concept was confirmed in all hydrographs. Bacterial density peaking occurred at or before the hydrograph peaks. FC and FS values were higher in more developed areas than the primary rural test site and their numerical ratios followed similar trends. Chlorine demand of storm waters varied between 8 and 16 mg/l and, the ozone requirement was greater than 32 mg/l in the same waters. Aftergrowth of total coliform bacteria occurred following chlorine and ozone doses of 16 mg/l and 32 mg/l respectively. Fecal coliform, fecal streptococci, Salmonella sp., and Pseudomonas sp. all were reduced to near detectable limits by the disinfectants up to 8 days. Staphylococcus sp. demonstrated a propensity to restablish their populations. Multiple regression analysis of the bacterial groups and species in storm waters suggested the fecal streptococci to have been the most useful group in evaluating bacterial storm water quality, with staphylocci have been closely related insofar as their statistical significance was concerned.     

Air pollution in California: Manufacturing vs. services

Relative to manufacturing, service activities are often considered by planners and officials to generate considerably less environmental pollution. This hypothesis is tested by means of an examination of the economic linkages of both manufacturing and service activities and of the resulting direct and indirect emissions of five air pollutants per dollar of output in the California statewide air basin and in four regional basins within the state. Overall acceptance or rejection of the hypothesis depends in part on the particular pollutant and air basin considered but, most importantly, on the judgement as to what activities are to be considered as service activities.This paper is based on research sponsored by the California Air Resources Board under Agreement A7-143-30.     

Metabolites of the phenylurea herbicides chlorotoluron, diuron, isoproturon and linuron produced by the soil fungus Mortierella sp.

Phenylurea herbicides are used worldwide, and often pollute surface- and groundwater in concentrations exceeding the limit value for drinking water (0.1 μg l⁻¹). Bacteria degrade phenylurea herbicides by successive N-dealkylation to substituted aniline products. Little is known about the corresponding fungal pathways, however. We here report degradation of chlorotoluron, diuron, isoproturon and linuron by the soil fungus Mortierella sp. Gr4. Degradation was fastest with linuron and resulted in successively dealkylated metabolites and 3,4-dichloroaniline. A major new metabolite was detected that has not yet been fully identified. Thin layer chromatography and nuclear magnetic resonance spectroscopy indicate that it is a non-aromatic diol. Degradation of isoproturon, chlorotoluron and diuron involved successive N-demethylation and, in the case of isoproturon and chlorotoluron, additional hydroxylation. A new hydroxylated isoproturon metabolite was detected. The study thus shows that the fungal pathways differ from the bacterial pathways and yield new metabolites of possible environmental concern.     

Application of a combined measurement and modeling method to quantify windblown dust emissions from the exposed playa at Mono Lake, California

Particulate matter < or =10 microm (PM10) emissions due to wind erosion can vary dramatically with changing surface conditions. Crust formation, mechanical disturbance, soil texture, moisture, and chemical content of the soil can affect the amount of dust emitted during a wind event. A refined method of quantifying windblown dust emissions was applied at Mono Lake, CA, to account for changing surface conditions. This method used a combination of real-time sand flux monitoring, ambient PM10 monitoring, and dispersion modeling to estimate dust emissions and their downwind impact. The method identified periods with high emissions and periods when the surface was stable (no sand flux), even though winds may have been high. A network of 25 Cox sand catchers (CSCs) was used to measure the mass of saltating particles to estimate sand flux rates across a 2-km2 area. Two electronic sensors (Sensits) were used to time-resolve the CSC sand mass to estimate hourly sand flux rates, and a perimeter tapered element oscillating microbalance (TEOM) monitor measured hourly PM10 concentrations. Hourly sand flux rates were related by dispersion modeling to hourly PM10 concentrations to back-calculate the ratio of vertical PM10 flux to horizontal sand flux (K-factors). Geometric mean K-factor values (K(f)) were found to change seasonally, ranging from 1.3 x 10(-5) to 5.1 x 10(-5) for sand flux measured at 15 cm above the surface (q15). Hourly PM10 emissions, F, were calculated by applying seasonal K-factors to sand flux measurements (F = K(f) x q15). The maximum hourly PM10 emission rate from the study area was 76 g/m2 x hr (10-m wind speed = 23.5 m/sec). Maximum daily PM10 emissions were estimated at 450 g/m2 x day, and annual emissions at 1095 g/m2 x yr. Hourly PM10 emissions were used by the U.S. Environmental Protection Agency (EPA) guideline AERMOD dispersion model to estimate downwind ambient impacts. Model predictions compared well with monitor concentrations, with hourly PM10 ranging from 16 to over 60,000 microg/m3 (slope = 0.89, R2 = 0.77).     

Radon emissions from natural gas power plants at The Pennsylvania State University

Burning natural gas in power plants may emit radon (²²²Rn) into the atmosphere. On the University Park campus of The Pennsylvania State University, atmospheric radon enhancements were measured and modeled in the vicinity of their two power plants. The three-part study first involved measuring ambient outdoor radon concentrations from August 2014 through January 2015 at four sites upwind and downwind of the power plants at distances ranging from 80 m to 310 m. For each plant, one site served as a background site, while three other sites measured radon concentration enhancements downwind. Second, the radon content of natural gas flowing into the power plant was measured, and third, a plume dispersion model was used to predict the radon concentrations downwind of the power plants. These predictions are compared to the measured downwind enhancements in radon to determine whether the observed radon concentration enhancements could be attributed to the power plants’ emissions. Atmospheric radon concentrations were consistently low as compared to the EPA action level of 148 Bq m^?3, averaging 34.5 ± 2.7 Bq m^?3 around the East Campus Steam Plant (ECSP) and 31.6 ± 2.7 Bq m^?3 around the West Campus Steam Plant (WCSP). Significant concentrations of radon, ranging from 516 to 1,240 Bq m^?3, were detected in the natural gas. The measured enhancements downwind of the ECSP averaged 6.2 Bq m^?3 compared to modeled enhancements of 0.08 Bq m^?3. Measured enhancements around the WCSP averaged ?0.2 Bq m^?3 compared to the modeled enhancements of 0.05 Bq m^?3, which were not significant compared to observational error. The comparison of the measured to modeled downwind radon enhancements shows no correlation over time. The measurements of radon levels in the vicinity of the power plants appear to be unaffected by the emissions from the power plants.

Implications: Radon measurements at sites surrounding power plants that utilize natural gas did not indicate that the radon concentrations originated from the plants’ emissions. There were elevated radon concentrations in the natural gas supply flowing into the power plants, but combustion dilution puts the concentration below EPA action levels coming out of the stack, so no hazardous levels were expected downwind. Power plant combustion of natural gas is not likely to pose a radiation health hazard unless very different gas radon concentrations or combustion dilution ratios are encountered.     

Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources

Urban stormwater runoff is being recognized as a substantial source of pollutants to receiving waters. A number of investigators have found significant levels of metals in runoff from urban areas, especially in highway runoff. As an initiatory study, this work estimates lead, copper, cadmium, and zinc loadings from various sources in a developed area utilizing information available in the literature, in conjunction with controlled experimental and sampling investigations. Specific sources examined include building siding and roofs; automobile brakes, tires, and oil leakage; and wet and dry atmospheric deposition. Important sources identified are building siding for all four metals, vehicle brake emissions for copper and tire wear for zinc. Atmospheric deposition is an important source for cadmium, copper, and lead. Loadings and source distributions depend on building and automobile density assumptions and the type of materials present in the area examined. Identified important sources are targeted for future comprehensive mechanistic studies. Improved information on the metal release and distributions from the specific sources, along with detailed characterization of watershed areas will allow refinements in the predictions.     

Interspecific differences in fouling of two congeneric ascidians (Eudistoma olivaceum and E. capsulatum): is surface acidity an effective defense?

Ascidian specimens were collected from the Indian River Lagoon, Florida, USA, in November 1987. Eudistoma olivaceum (Van Name) was fouled by only two species of epifaunal invertebrates and the percent cover of epibionts was negligible. Colonies of E. capsulatum (Van Name) were fouled by up to 17 species of epifaunal invertebrates, epibionts covered an average of 12.5% of the surface area of these colonies. Extracts of E. olivaceum exhibited potent cytotoxic, antimicrobial and antiviral activity in laboratory bioassays, while the activity of extracts of E. capsulatum was insignificant. The toxicity of extracts of each ascidian was negatively related to the percent cover of fouling organisms. Surface acidity of each ascidian was positively related to the percent cover of epibionts: E. olivaceum was nearly neutral (pH=6), while E. capsulatum was highly acidic (pH=1 to 2). Larval settlement and growth of ancestrulae of the cheilostome bryozoan Bugula neritina (Linnaeus) were inhibited at very low concentrations of crude extract of E. olivaceum. Crude extracts of E. capsulatum inhibited settlement and growth of B. neritina only at concentrations of approximately an order of magnitude greater than those of E. olivaceum. Differences in the degree to which these congeneric ascidians are fouled is related to differences in the chemical defenses they possess. Acidity is not an effective inhibitor of settlement by epifaunal invertebrates.     

Natural attenuation of chlorinated solvents at Area 6, Dover Air Force Base: characterization of microbial community structure

A polyphasic approach based on cultivation and direct recovery of 16S rRNA gene sequences was utilized for microbial characterization of an aquifer contaminated with chlorinated ethenes. This work was conducted in order to support the evaluation of natural attenuation of chlorinated ethenes in groundwater at Area 6 at Dover Air Force Base (Dover, DE). Results from these studies demonstrated the aquifer contained relatively low biomass (e.g. direct microscopic counts of < 10(7) bacteria/g of sediment) comprised of a physiologically diverse group of microorganisms including iron reducers, acetogens, sulfate reducers, denitrifiers, aerobic and anaerobic heterotrophs. Laboratory microcosms prepared with authentic sediment and groundwater provided direct microbiological evidence that the mineralization of vinyl chloride and cis-dichloroethene as well as each step in the complete reductive dechlorination of tetracloroethene to ethene can occur in the Area 6 aquifer. Enrichment cultures capable of the oxidative degradation of cis-1,2-dichloroethene (cis-DCE) and vinyl chloride (VC) were obtained from groundwater across the aquifer demonstrating the possible importance of direct, non-cometabolic oxidation of cis-DCE and VC in natural attenuation. Culture-independent analyses based upon recovery of 16S rRNA gene sequences revealed the presence of anaerobic organisms distributed primarily between two major bacterial divisions: the delta subdivision of the Proteobacteria and low-G + C gram positive. Recovery of sequences affiliated with phylogenetic groups containing known anaerobic-halorespiring organisms such as Desulfitobacterium, Dehalobacter, and certain groups of iron reducers provided qualitative support for a role of reductive dechlorination processes in the aquifer. This molecular data is suggestive of a functional linkage between the microbiology of the site and the apparent natural attenuation process. The presence and distribution of microorganisms were found to be consistent with a microbially driven attenuation of chlorinated ethenes within the aquifer and in accord with a conceptual model of aquifer geochemistry which suggest that both reductive and oxidative mechanisms are involved in heterogeneous, spatially distributed processes across the aquifer.