Hazard property classification of waste according to the recent propositions of the EC using different methods

Hazard classification of waste is a necessity, but the hazard properties (named “H” and soon “HP”) are still not all defined in a practical and operational manner at EU level. Following discussion of subsequent draft proposals from the Commission there is still no final decision. Methods to implement the proposals have recently been proposed: tests methods for physical risks, test batteries for aquatic and terrestrial ecotoxicity, an analytical package for exhaustive determination of organic substances and mineral elements, surrogate methods for the speciation of mineral elements in mineral substances in waste, and calculation methods for human toxicity and ecotoxicity with M factors.In this paper the different proposed methods have been applied to a large assortment of solid and liquid wastes (>1 0 0).Data for 45 wastes – documented with extensive chemical analysis and flammability test – were assessed in terms of the different HP criteria and results were compared to LoW for lack of an independent classification. For most waste streams the classification matches with the designation provided in the LoW. This indicates that the criteria used by LoW are similar to the HP limit values.This data set showed HP 14 ‘Ecotoxic chronic’ is the most discriminating HP. All wastes classified as acute ecotoxic are also chronic ecotoxic and the assessment of acute ecotoxicity separately is therefore not needed. The high number of HP 14 classified wastes is due to the very low limit values when stringent M factors are applied to total concentrations (worst case method). With M factor set to 1 the classification method is not sufficiently discriminating between hazardous and non-hazardous materials. The second most frequent hazard is HP 7 ‘Carcinogenic’. The third most frequent hazard is HP 10 ‘Toxic for reproduction’ and the fourth most frequent hazard is HP 4 “Irritant – skin irritation and eye damage”. In a stepwise approach, it seems relevant to assess HP 14 first, then, if the waste is not classified as hazardous, to assess subsequently HP 7, HP 10 and HP 4, and then if still not classified as hazardous, to assess the remaining properties.The elements triggering the HP 14 classification in order of importance are Zn, Cu, Pb, Cr, Cd and Hg. Progress in the speciation of Zn and Cu is essential for HP 14. Organics were quantified by the proposed method (AFNOR XP X30-489) and need no speciation. Organics can contribute significantly to intrinsic toxicity in many waste materials, but they are only of minor importance for the assessment of HP 14 as the metal concentrations are the main HP 14 classifiers. Organic compounds are however responsible for other toxicological characteristics (hormone disturbance, genotoxicity, reprotoxicity…) and shall be taken into account when the waste is not HP 14 classified.     

Urban structure matters,even in a small town

A recent study in Frederikshavn, Denmark, shows that urban structural variables influence travel behaviour, even in a small town of around 30 000 inhabitants. As might be expected, socio-economic and attitudinal factors play a role in the respondents' travelling patterns. However, when controlling for these factors and a range of other potential explanatory variables, clear relationships are also found between urban structural characteristics and travel activity. These relationships exist across most subgroups of the population. The statistical relationships found between urban structure and travel behaviour are confirmed in qualitative interviews. The distance from the residence to the downtown area is a key factor influencing the accessibility to a number of facilities. These differences in accessibility result in corresponding differences in the actual travelling distances and modal split.     

A submodel for anaerobic mud-water exchange of phosphate

A submodel for anaerobic mud-water exchange of phosphate is obtained from experiments in the laboratory. Phosphorus in the sediment can be divided into exchangeable and non-exchangeable phosphorus. The exchangeable phosphorus is decomposed in accordance with a first-order reaction. The phosphorus moves, after the decomposition process, from the interstitial water to the water phase, in accordance with a diffusion expression. The yearly increase of the sediment was determined by means of the lead concentration as a function of the depth.     

Behaviour of stream-dwelling brown trout towards odours present in home stream water

Summary Preference behaviour patterns of wild brown trout (Salmo trutta L.) towards odours in their home-stream water were measured in laboratory experiments. Stream-dwelling, sexually mature trout were captured by electrofishing in different sections of a stream, transferred to a hatchery, and exposed to water sampled from various stream sections and to neutral water, scented by fish captured in the same stream sections. The fish preferred stream water originating from their home stream over that from a neighboring stream. Among water samples from their home stream, they preferred water from the home sections over water from distant sections both upstream and downstream. In most cases they also preferred neutral water scented by other mature fish captured in their home section over water scented by fish from the distant sections. Trout from two neighboring stream sections showed indifferent responses towards water and fish from the adjacent section. The attractive properties of stream water sampled from home sections coincided with those obtained with neutral water scented by fish from the same sites. Accordingly, the attractive components in stream water may be intraspecific odours derived from separate spawning demes of fish present in local areas of the stream.     

Degrader density determines spatial variability of 2,6-dichlorobenzamide mineralisation in soil

The metabolite 2,6-dichlorobenzamide (BAM) is a frequent groundwater pollutant produced during degradation of the herbicide 2,6-dichlorobenzonitrile (dichlobenile). Spatial variability of BAM mineralisation is uncharacterized in surface soil, however, and factors controlling the heterogeneity remain unknown. We addressed these issues by sample-to-sample comparisons of BAM mineralisation rates and a range of soil characteristics at spatial scales ranging from meters to centimetres. For mineralisation assays nano-molar concentrations of labelled BAM were added to determine mineralisation rates under realistic conditions. We found a significant variability of BAM mineralisation which increased with decreasing spatial scale. BAM mineralisation rates were correlated to the density of BAM-degrading bacteria but not to water content, TOC, NH₄⁺, NO₃⁻, or pH. The genus Aminobacter, which contains the only BAM degraders known, was detected in MPN samples of BAM degraders by a specific PCR assay targeting the 16S rRNA gene, confirming a role of Aminobacter in BAM mineralisation.     

Reliable test methods for the determination of a natural production of chloroform in soils

Chloroform is one of the most frequently found anthropogenic groundwater contaminants. Recent investigations, however, suggested that chloroform in groundwater may also originate from a natural production in soils. As societies response to the occurrence of chloroform in groundwater may depend upon its origin as anthropogenic or naturally produced, test methods are needed to measure the potential of natural soil chloroform production. Field measurements of ambient air and soil air, and field and laboratory incubation studies were evaluated for measurement of relative soil chloroform production at a site with four different vegetation types (spruce forest, beech forest, grassland, and grain field) on comparable geological soil. All test methods showed varying soil production of chloroform with spruce forest soil being most productive and grain field soil being least productive. Field measurements of the ratio of soil air to ambient air chloroform concentrations exhibited the smallest difference between high production and low production areas, whereas laboratory incubation studies showed the largest difference. Thus, laboratory incubation studies are suggested as most efficient for estimating relative chloroform production in soil. The study indicated that soil samples should be tested not more than 14 days after sampling. Furthermore, it was found that potentially limiting compounds, such as chloride or nitrate, are not needed to be added in spike experiments to obtain reliable production results. However, it should be recognized that the processes of soil chloroform production are not known yet in all details. Other factors than those studied here may affect the test methods for soil chloroform production too.     

Decision on oil and gas exploration in an Arctic area: Case study from the Norwegian Barents Sea

This paper addresses how risks to the environment in the Arctic are handled in decisions regarding the exploration for petroleum resources. An exploration well in the Norwegian Barents Sea is used as a case to demonstrate how environmental risks are assessed together with technical and economic considerations in the Oil Company’s decisions to enter into a new area and drill a well. The paper outlines environmental challenges in petroleum activities in the Arctic, the different roles of the Authorities and Oil Companies in decisions about petroleum activities, and the Oil Company’s tools and decision criteria used in addressing risks in the decision making.It is concluded that environmental and associated reputation risks are not a major issue at the strategic level in the Oil Company, since the most controversial areas in the Norwegian Arctic offshore have already been kept out of the exploration acreage by the authorities. Risks and uncertainties penetrate every aspect of the exploration of petroleum resources, and environmental risks are not unique in this sense. The Oil Company has established technical and economic tools and decision criteria to address them, and the mitigation of environmental risks becomes an element in the technical and economic analyses that affect detailed design and operational procedures. Mitigation measures such as the minimization of discharges to the sea (the so-called “zero-discharge” policy) and oil spill contingency planning are dimensioned to meet authority requirements and expectations rather than on strict risk acceptance considerations. A significant concern is to avoid delays in the permit granting process.     

Genetic Variability in Swayne's Hartebeest, an Endangered Antelope of Ethiopia

Abstract: Swayne's hartebeest ( Alcelaphus buselaphus swaynei ) is an endangered antelope that survives in four or five relict populations in Ethiopia. We examined the two main populations (Senkele and Nechisar) for mitochondrial (D-loop) and nuclear (microsatellite) variability in order to measure levels of genetic variation within the subspecies and degree of differentiation between populations. For comparison, we examined samples from a large population of red hartebeest ( Alcelaphus buselaphus caama ). Both swaynei and caama exhibited high levels of variation. There was significant differentiation between the populations of swaynei at Senkele and Nechisar, and gene diversity in Nechisar, the smaller of the two populations, was significantly lower than that in Senkele. Many mitochondrial haplotypes and microsatellite alleles present at high frequencies among the Senkele individuals were missing in Nechisar, suggesting that the translocation of animals from Senkele undertaken in 1974 did not contribute notably to the gene pool in Nechisar. Subsamples taken from Senkele in 1988 and 1995 showed a significant change in allele frequencies, a change that probably can be attributed to a massive population decline during this period. We recommend that both populations be protected in situ to maintain as much as possible of the diversity that exists within the taxon and that a breeding program be established. In spite of the earlier unsuccessful attempt, we argue that translocation of animals for enhancement of population size as well as genetic variation in Nechisar should be considered.     

Sociopolitical drivers and environmental outcomes of protected area downgrading and degazettement in Cambodia

Regional Environmental Change - Climate change has severe impacts on the livelihoods of West-African communities with the floods of the late 2000s and early 2010s serving as factual evidence....