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排序方式: 共有482条查询结果,搜索用时 15 毫秒
151.
Todorović B Milijasević-Marčić S Potočnik I Stepanović M Rekanović E Nikolić-Bujanović L Cekerevac M 《Journal of environmental science and health. Part. B》2012,47(3):175-179
In vitro antibacterial activity tests of seven biofungicides (Ekstrasol, Bisolbisan, Bisolbifit, Serenade, Sonata, Timorex, F-Stop) and two disinfectants (colloidal silver alone and in combination with hydrogen peroxide) against the Pseudomonas tolaasii strain (NS3B6) were carried out by the disc-diffusion, broth microdilution and broth macrodilution method. Biofungicides tested in this study did not exhibit any antimicrobial activity in neither one of the methods used. Disc diffusion method revealed high sensitivity of the tested P. tolaasii strain to Ecocute based on colloidal silver and hydrogen peroxide. Both microdilution and macrodilution methods identified the same MICs and MBCs of Ecocute (0.19 mg/L) for P. tolaasii strain. MICs and MBCs values of silver alone were much higher (10 mg/L) compared to silver in combination with hydrogen peroxide. 相似文献
152.
This study investigated the removal of Reactive Black 5 (RB5) textile dye from aqueous solutions using cotton (Gossypium hirsutum) seed shell (CSS) as low cost adsorbents. The data were described according to the Freundlich and Langmuir isotherm models. Of these, the Langmuir model provided the best fit for the experimental data. The highest measured adsorption density was 12.19 mg/g at pH 2. An equilibrium adsorption rate of RB5 by CSS (q(e) = 11.879 mg/g) was observed at 30 minutes. In order to evaluate the adsorption kinetic mechanisms, pseudo first and second order rate kinetic models and an intraparticle diffusion model were applied, with the pseudo second order model providing an excellent fit for the data. 相似文献
153.
Trnovec T Dedík L Jusko TA Lancz K Palkovičová L Kočan A Šovčíková E Wimmerová S Tihányi J Patayová H Hertz-Picciotto I 《Chemosphere》2011,85(11):1687-1693
Investigators have typically relied on a single or few discrete time points as measures of polychlorinated biphenyl (PCB) body burden, however health effects are more likely to be the result of integrative exposure in time, optionally expressed as an area under the time curve (AUC) of PCB serum concentration. Using data from a subgroup of 93 infants from a birth cohort in eastern Slovakia—a region highly polluted by PCBs—we fit a system type model, customized to our longitudinal measures of serum PCB concentrations in cord, 6, 16, and 45 month blood specimens. The most abundant congener, PCB 153, was chosen for modeling purposes. In addition to currently used methods of exposure assessment, our approach estimates a concentration time profile for each subject, taking into account mean residence time of PCB 153 molecules in the body, duration of breast feeding, hypothetical PCB 153 concentration in steady-state without breast feeding and alternately without normal food intake. Hypothetical PCB 153 concentration in steady-state without normal food intake correlates with AUC (r = 0.84, p < 0.001) as well as with duration of breast feeding (r = 0.64, p < 0.001). It makes possible to determine each subject’s exposure profile expressed as AUC of PCBs serum concentration with a minimum model parameters. PCB body burden in most infants was strongly associated with duration of breast feeding in most, but not all children, was apparent from model output. 相似文献
154.
Lazar B Maslov L Romanić SH Gračan R Krauthacker B Holcer D Tvrtković N 《Chemosphere》2011,82(1):121-129
We analyzed 15 polychlorinated biphenyls (PCBs) and five organochlorine pesticides (OCPs) in fat tissue of 27 loggerhead sea turtles (Caretta caretta) from eastern Adriatic Sea with the curved carapace length ranging from 25.0 to 84.5 cm. The PCB profile was dominated by hexa- and hepta-chlorinated congeners, with PCB-153 (median: 114.9 ng g−1 wet mass), PCB-138 (80.0 ng g−1 w.m.), and PCB-180 (26.7 ng g−1 w.m.) detected with the highest levels. Toxic mono-ortho congeners PCB-118, PCB-105 and PCB-180 with dioxin-like toxicity were found in >70% samples. 4,4′-DDE (81.0 ng g−1 w.m.) prevailed the OCP signature, accounting for 80% of the total DDTs. A significant increasing trend in accumulation with size was found for PCB-52 (rs = 0.512, p < 0.01) and PCB-114 (rs = 0.421, p < 0.05). Comparison of our results with organochlorine contaminant (OC) pattern in some prey taxa suggest that contamination occurs primarily through the food web, with biomagnification factors of 0.14-6.99 which were positively correlated with the octanol-water partition coefficient (log Kow; p < 0.05). This study, based upon a fairly large sample size collected mostly from incidentally captured animals over a short time period (June 2001-November 2002), present a temporal snapshot of OC contamination in wild, free-ranging loggerheads from Adriatic feeding grounds and provide a baseline for monitoring the regional OC trends in this endangered species. 相似文献
155.
Josef Hrnčiřík Jiří Pšeja Jan Kupec Světlana Bernkopfová 《Journal of Polymers and the Environment》2010,18(2):98-103
This work focused on anaerobic biodegradation of blends composed of glycerol-plasticized polyvinyl alcohol (PVA) and biopolymer
(starch, gellan, xanthan) in an aqueous environment, after inoculation with digested activated sludge from a municipal wastewater
treatment plant. Glycerol degradability is comparable to degradability of used modifying agents. Modifying agents added in
the 20–40 wt% range proportionally increased biodegradation degree (Dt) calculated from balance of transformed carbon in the system. Biodegradation degree of polysaccharides and glycerol attained
95% and over. For PVA it was only 6.5% (in breakdown times up to 500 h). Content of polysaccharides favorably affects biodegradation
degree of polyvinyl alcohol blends, but at the expense of reduced mechanical properties of resultant products. 相似文献
156.
zer nar Semra Yaar Metin Kertmen Kevser Demirz Nevzat
zgü Yigit Mehmet Kitis 《Process Safety and Environmental Protection》2008,86(6):455-460
The effects of cycle time on the biodegradation of the azo dye remazol brilliant violet 5R (RBV-5R) were investigated in an anaerobic–aerobic sequencing batch reactor (SBR). System performance was determined by monitoring chemical oxygen demand (COD), color, anaerobic enzyme (azo reductase) and aerobic enzyme (catechol 2,3-dioxygenase), and aromatic amine concentration. SBR was operated in three different total cycle times (48 h, 24 h and 12 h), fed with a synthetic textile wastewater. In this study, the anaerobic period of SBR was found to allow the reductive decolorization of azo dye and the aerobic period was found to be effective on further COD removal after the anaerobic period. The percentage reductions in color by the anaerobic stage of the SBR were at 72%, 89% and 86% for the 24-h, 12-h and 6-h cycle times, respectively. Total COD removal efficiencies were over 75% for all operational conditions and about 70% of the COD removal was achieved in the first 3 h of anaerobic stages. During the decolorization of RBV-5R, two sulfonated aromatic amines (benzene-based and naphthalene-based) were formed and detected by HPLC. Aerobic phases of SBR with total cycle times of 48 h, 24 h and 12 h were able to remove benzene-based aromatic amines with removal efficiency of 64%, 92% and 89%, respectively. The results indicated that the best SBR performance in terms of color removal and aromatic amine degradation was achieved from total cycle time of 24 h. 相似文献
157.
158.
Mycosporine-like amino acids (MAAs) are a group of about 20 structurally related water-soluble compounds, widely distributed among freshwater and marine organisms. To provide a better assessment of the diversity and concentration of MAAs in aquatic environments a high-performance liquid chromatography (HPLC) method of analysis based on reverse-phase C18 column and trifluoroacetic acid and an ammonium-containing mobile phase was developed. The improvements with respect to previous methods and the extraction and clean-up procedures are described here. With this method the clean-up recovery of MAAs of high polarity (shinorine), medium polarity (palythinol), and low polarity (palythene) is greater than 99% (±1%). The method is selective enough to resolve in a single run most of the characterized MAAs found in marine organisms, including the critical and highly polar compounds shinorine, mycosporine-2-glycine, and palythine-serine, the medium polarity pair palythenic acid and shinorine methyl ester (M-333), and the low polarity isomeric pair usujirene and palythene. A chromatogram of a mixture of over 20 MAAs such as might be found in complex samples of marine organisms is given. Good precision was obtained in the separations. The relative standard deviation for retention times was below 1% and the mean relative standard deviation for integrated area estimations was below 2%. A mean column recovery of standards was 99% (±1%) whereas limits of detection (signal-to-noise, S/N=2) for different MAAs varied between 0.08 and 0.47 pmol injected. The applicability of the method was tested using extracts of three microalgae cultures, three natural phytoplankton populations, two scleractinian corals, and one species of sea anemone. Results reveal the occurrence of several unknown MAAs not previously reported in the literature. The selectivity of the method toward some recently discovered MAAs makes it especially suitable not only for studying new field samples, but also for re-examining the MAA composition of previously studied organisms.Communicated by O. Kinne, Oldendorf/Luhe 相似文献
159.
Irena Ciglenečki Srđan Pichler Esad Prohić Božena Ćosović 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):537-545
Geochemical, mineralogical and sedimentological analyses were carried out to contrast two different sites (respectively characterized
by permanently oxic and anoxic conditions) in a small, meromictic, seawater lake. In fact, due to relatively high organic
matter content, and reduced water exchange, the Rogoznica Lake has almost permanent anoxic conditions below the depth of 12 m,
where sediment can be considered an anoxic–sulphidic sedimentary environment. Different water column and sediments redox conditions
affect the distribution and speciation of major redox-sensitive metals (Fe, Mn, Mo), reduced sulphur species (RSS) and dissolved
organic C (DOC). Trace metals, especially those that accumulate in anoxic–sulphidic environments (Fe, Mo) showed a marked
enrichment in the solid phase, whereas the low solubility of sulphides leads to low porewater concentrations. The relatively
high sedimentary enrichment of Mo (up to 81 mg/kg) also confirms highly anoxic conditions within the Rogoznica Lake sediments.
Results clearly show that chemical species within the sediments will tend towards equilibrium between porewater and solid
phase according the prevailing environment conditions such as redox, pH, salinity, DOC. 相似文献
160.