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61.
Mehmet Sinan Bilgili Gamze Varank Elif Sekman Selin Top Didem Özçimen Remziye Yazıcı 《Environmental Modeling and Assessment》2012,17(3):289-300
Since phenols and phenolic compounds in many industrial wastewaters are toxic organic contaminants for humans and aquatic
life, to remove these compounds via the most efficient way is very important for environmental remediation treatment. In this
context, almost all of the isotherm models (Freundlich, Langmuir, Temkin, Redlich–Peterson, Sips, and Khan) for adsorption
in the literature were applied to explain the adsorption mechanism of 4-chlorophenol on activated carbon in this study. Also
theoretical modeling data were obtained using model equations; interpolation and analysis of variance were made to compare
data by using statistics software. In addition, the thermodynamic and kinetic studies for adsorption mechanism were included
in the article. The adsorption of 4-chlorophenol on activated carbon fits well to the pseudo-first-order kinetic model than
the pseudo-second-order, intraparticular diffusion and Bangham models. It is also indicated that 4-chlorophenol adsorption
by granular activated carbon would be attributed to a type of transition between physical and chemical adsorption rather than
a pure physical or chemical adsorption process. As a result, an environmental remediation problem and the adsorption mechanism
on activated carbon that can be regarded as a solution to this problem are described and explained using the mathematical
models and calculations in this study. 相似文献
62.
Maria P. Papadopoulou Emmanouil A. Varouchakis George P. Karatzas 《Environmental Modeling and Assessment》2010,15(5):319-328
Karst aquifers are characterized by spatial heterogeneity due to the presence of highly permeable channels and conduits in
low-permeable fractured rocks (matrix block). Recent studies have reported a close relationship between surface and subsurface
water in karstic regions due to the water flow through a complicated network of paths formed by fracture intersections. Subsurface
flow in karstified aquifers ranges between conduit flow, in large passages with relatively high flow velocities, and diffuse
flow, in the matrix block where Darcy’s law is still valid. In this paper, we present the simulation of a complex karstified
aquifer system in Crete, Greece, where the presence of main faults drastically affects the regional flow. A discrete fracture
approach in conjunction with an equivalent porous medium approach was adopted to simulate the mixed flow in the area of interest.
The simulation results have shown that the length and the orientation of the dominant faults, primarily during the rainy season,
affect the flow field. 相似文献
63.
Michael G. Hutchins Amelie Deflandre-Vlandas Paulette E. Posen Helen N. Davies Colin Neal 《Environmental Modeling and Assessment》2010,15(2):93-109
A combined semi-distributed hydrological model (CASCADE/QUESTOR) is used to evaluate the steady-state that may be achieved
after changes in land-use or management and to explore what additional factors need to be considered in representing catchment
processes. Two rural headwater catchments of the River Derwent (North Yorkshire, UK) were studied where significant change
in land-use occurred in the 1990s and the early 2000s. Much larger increases in mean nitrate concentration (55%) were observed
in the catchment with significant groundwater influence (Pickering Beck) compared with the surface water-dominated catchment
(13% increase). The increases in Pickering Beck were considerably greater than could be explained by the model in terms of
land-use change. Consequently, the study serves to focus attention on the long-term increases in nitrate concentration reported
in major UK aquifers and the ongoing and chronic impact this trend is likely to be having on surface water concentrations.
For river environments, where groundwater is a source, such trends will mask the impact of measures proposed to reduce the
risk of nitrate leaching from agricultural land. Model estimates of within-channel losses account for 15–40% of nitrate entering
rivers. 相似文献
64.
Ans M. Mouton Andy P. Dedecker Sovan Lek Peter L. M. Goethals 《Environmental Modeling and Assessment》2010,15(1):65-79
This study aimed to compare different methods to analyse the contribution of individual river characteristics to predict the
abundance of Asellus (Crustacea, Isopoda). Six methods which provide the relative contribution and/or the contribution profile of the input variables
of artificial neural network models were therefore compared: (1) the ‘partial derivatives’ method; (2) the ‘weights’ method;
(3) the ‘perturb’ method; (4) the ‘profile’ method; (5) the ‘classical stepwise’ method; (6) the ‘improved stepwise’ method.
Consequently, the key variables which affect the habitat preferences of Asellus could be identified. To evaluate the performance of the artificial neural network model, the model predictions were compared
with the results of a multiple linear regression analysis. The dataset consisted of 179 samples, collected over a 3-year period
in the Zwalm catchment in Flanders, Belgium. Twenty-four environmental variables as well as the log-transformed abundance
of Asellus were used in this study. The different contribution methods seemed to give similar results concerning the order of importance
of the input variables. Nevertheless, their diverse computation led to differences in sensitivity and stability of the methods
and the derived outcomes on the habitat preferences. From an ecological point of view, the environmental variables describing
the stream type (width, depth, stream order and distance to mouth) were the most significant variables for Asellus in the Zwalm catchment during the period 2000–2002 for all applied methods. Indirectly, one can conclude that the water quality
is not the limiting factor for the survival of Asellus in the Zwalm catchment. 相似文献
65.
In the event of a natural or anthropogenic disturbance, environmental resource managers require a reliable tool to quickly
assess the spatial extent of potential damage to the seagrass resource. The temporal availability of the Landsat 5 Thematic
Mapper (TM) imagery provided a suitable option to detect and assess damage of the submerged aquatic vegetation (SAV). This
study examined Landsat TM imagery classification techniques to create two-class (SAV presence/absence) and three-class (SAV
estimated coverage) SAV maps of the seagrass resource. The Mahalanobis Distance method achieved the highest overall accuracy
(86%) and validation accuracy (68%) for delineating the seagrass resource (two-class SAV map). The Maximum Likelihood method
achieved the highest overall accuracy (74%) and validation accuracy (70%) for delineating the seagrass resource three-class
SAV map. The Landsat 5 TM imagery classification provided a seagrass resource map product with similar accuracy to the aerial
photointerpretation maps (validation accuracy 71%). The results support the application of remote sensing methods to analyze
the spatial extent of the seagrass resource. 相似文献
66.
The groundwater level represents a critical factor to evaluate hillside landslides. A monitoring system upon the real-time
prediction platform with online analytical functions is important to forecast the groundwater level due to instantaneously
monitored data when the heavy precipitation raises the groundwater level under the hillslope and causes instability. This
study is to design the backend of an environmental monitoring system with efficient algorithms for machine learning and knowledge
bank for the groundwater level fluctuation prediction. A Web-based platform upon the model-view controller-based architecture
is established with technology of Web services and engineering data warehouse to support online analytical process and feedback
risk assessment parameters for real-time prediction. The proposed system incorporates models of hydrological computation,
machine learning, Web services, and online prediction to satisfy varieties of risk assessment requirements and approaches
of hazard prevention. The rainfall data monitored from the potential landslide area at Lu-Shan, Nantou and Li-Shan, Taichung,
in Taiwan, are applied to examine the system design. 相似文献
67.
Karadag A 《Environmental monitoring and assessment》2012,184(3):1617-1632
This paper is a summary of a project changed into a book named by “Changing Environment, City and Identity in Soma with the
Geographical Evaluations” issued on May 2005. In this research, Soma, which is one of the most remarkable districts in Manisa
in the West Anatolia from the point of economical figures, is assessed with its physical environment potential, improving
economical activities and changing socio-economical structure. Owing to the open coal basins in the northeast and southwest
of the district where lignite is produced and the impact of the thermic power plant near the city centre, Soma has changed
on a large scale. This change has introduced some environmental problems into the district such as the devastation of the
forestry land; the infertility of farming land; and soil, water and air pollution. Even though the change under discussion
has led to many problems to deal with, it has also influenced its socio-economical structure to a large extent and revealed
new type of inhabitants having different life expectations and aims. In conclusion, in this article, changing environment
and city structure after lignite processing and thermic station establishment in Soma are discussed through the effective
geographical factors. The new city profile formed by the local dynamics in question is evaluated according to the data obtained
by the studies made in the neighbourhood. 相似文献
68.
Bai S Srikantaswamy S Krishnanandan V Naik OP 《Environmental monitoring and assessment》2012,184(1):239-249
Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献
69.
Concentration of heavy metals (Cd, Ni, Zn, Fe, Cu, Mn, Pb, Cr, Hg and As) in the waters of River Yamuna and in the soil of
agricultural fields along its course in Delhi are reported from 13 sites, spread through the Delhi stretch of Yamuna, starting
from the Wazirabad barrage till the Okhla barrage. Varying concentration of heavy metals was found. Peaks were observed in
samples collected downstream of Wazirabad and Okhla barrage, indicating the anthropogenic nature of the contamination. The
Wazirabad section of the river receives wastewater from Najafgarh and its supplementary drains, whereas the Shahdara drain
releases its pollution load upstream of the Okhla barrage. Average heavy metal concentration at different locations in the
river water varied in the order of Fe>Cr>Mn>Zn>Pb>Cu>Ni>Hg>As>Cd. The river basin soil shows higher level of contamination
with lesser variation than the water samples among sampling locations, thereby suggesting deposition over long periods of
time through the processes of adsorption and absorption. The average heavy metal concentration at different locations in soil
varied in the order of Fe>Mn>Zn>Cr>Pb>Ni>Hg>Cu>As>Cd. 相似文献
70.
The chemical forms and ecological risk of As were characterized in the sediment of the Daliao River System (DRS), which has
been affected by long-term intensive industrial, urban, and agricultural activities. Twenty-seven samples of surface sediment
were collected and analyzed for total As content and that of its chemical forms. The results indicated that the average total
As content in the sediment was 9.83 mg kg − 1 but that the levels ranged from 1.57 to 83.09 mg kg − 1. At the sites near cities, mining sites, and the estuary of the DRS, it is likely that adverse effects on aquatic organisms
occur, due to As levels in the sediment that are often higher than the threshold effect level and occasionally higher than
the probable effect level. A selectively sequential extraction indicated that the majority of As in the sediment was bound
to Fe oxides (62.1%), with moderate proportions of residual As (19.8%), specifically adsorbed As (17.9%), and a low proportion
of non-specifically adsorbed As (1.1%). In addition, the content of Fe in the sediment was positively and significantly correlated
with the contents of amorphous and crystalline Fe oxide-bound As, confirming the crucial role of Fe oxides in immobilizing
high amounts of As in superficial environments. The average molar ratio of As to Fe was 1.18 × 10 − 4 in the surface sediment of the DRS, similar to that of natural Fe oxides, but much lower than that of synthesized Schwertmannite.
Therefore, the release of As under reduced and low pH conditions can cause serious problems for water resources and for living
organisms. 相似文献