全文获取类型
收费全文 | 2984篇 |
免费 | 5篇 |
国内免费 | 35篇 |
专业分类
安全科学 | 58篇 |
废物处理 | 149篇 |
环保管理 | 302篇 |
综合类 | 410篇 |
基础理论 | 1125篇 |
污染及防治 | 605篇 |
评价与监测 | 192篇 |
社会与环境 | 182篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 117篇 |
2017年 | 122篇 |
2016年 | 184篇 |
2015年 | 59篇 |
2014年 | 18篇 |
2013年 | 28篇 |
2012年 | 431篇 |
2011年 | 218篇 |
2010年 | 35篇 |
2009年 | 34篇 |
2008年 | 52篇 |
2007年 | 72篇 |
2006年 | 74篇 |
2005年 | 396篇 |
2004年 | 534篇 |
2003年 | 409篇 |
2002年 | 51篇 |
2001年 | 40篇 |
2000年 | 19篇 |
1999年 | 34篇 |
1998年 | 6篇 |
1997年 | 11篇 |
1996年 | 3篇 |
1995年 | 11篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1991年 | 9篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1983年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 2篇 |
1961年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有3024条查询结果,搜索用时 15 毫秒
991.
Oliver Falk Hubertus Wichmann Petra Jopke Christiane Schmidt-Nädler Birthe Matthies Müfit Bahadir Roland Meyer-Pittroff 《Environmental Sciences Europe》2004,16(4):255-261
Aims and Scope
In Germany, 120,000 tons per year of waste edible fats are collected from the catering and the food industry Until recently, these fats have widely been used as a nutritional additive for poultry and other animals fodder. Due to the BSE crisis and some affairs based on dioxins in feeding stuff, waste fats are now barely used as fodder. Currently, these fats substitute fresh vegetable oils in the chemical industry and are used as raw material for the production of biodiesel. Therefore, alternative fields of application are required. In this context, the Deutsche Bundesstiftung Umwelt (DBU) is sponsoring a joint research project which deals with the production and testing of cooling lubricants based on monoesters made from waste edible fats.Methods
In a first step, characteristics and quality of wasteedible fats of different origins were chemically analysed and monitored. The investigations covered the following fat specific parameters: total contamination, sulphate ash, water content, peroxide number, iodine value, kinematical viscosity, neutralisation number (free fatty acids) and fatty acid spectra. In the next step, a process development/optimisation was carried out for the production of methylesters based on the raw material waste fat, leading to the construction of a pilot plant. To investigate the fate of trace pollutants during the production process of waste-fat methylester, samples were systematically contaminated with polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and the elements Al, Cd, Cr, Cu, Ni, P, Pb, Sn, and Zn. These contaminated fat samples were transesterified in laboratory scale. The primary and by-products were analysed subsequently.Results
Valuable hints on the design of the technical process of fatty adid methylester production based on waste edible fats were gained by regarding the fat specific parameters. For example, filtration and dewatering of the waste fats proved necessary. The saturated fatty acids, most wanted for the production of cooling lubricants due to their high oxidation stability, were present in the range of 11,3% to 31,6%. Due to the low content of free fatty acids, a base catalysed process occurred more suitable for the transesterification of the waste edible fats. Trace analytical investigations concerning inorganic and organic pollutants proved a low basic contamination of the waste edible fats. Experiments with systematic contamination of the fats indicated an accumulation of the heavy metals in the glycerol phase during the transesterification process, whereas the organic pollutants were detected in the methylester fraction by amounts of 80% to 95%.Outlook
In a next step, the further processing of the methylesters to monoesters with alcohols of the chain length C2 to C8 will be presented. Associated results of chemical-analytical investigations on the process and the application of the cooling lubricants will also be given. 相似文献992.
993.
J.??áslavskyEmail author P.?Kotla?íková K.?Bene?ová 《Environmental Chemistry Letters》2004,2(2):89-92
Semipermeable membrane devices (SPMDs) are nowadays used as passive samplers of organic pollutants. The knowledge of the sampling rate values (RS) of each substance trapped on membranes is necessary to calculate their average concentration. Here we calculate RS values for 16 polycyclic aromatic hydrocarbons using the comparison of active sampling method results and the amounts sequestered by SPMDs at varying exposure times.Selected article from the Regional Symposium on Chemistry and Environment, Krusevac, Serbia, June 2003, organized by Dr. Branimir Jovancicevic. 相似文献
994.
995.
Sperm competition and the level of polyandry in a bushcricket with large nuptial gifts 总被引:4,自引:0,他引:4
Leon?R.?HockhamEmail author Jefferson?A.?Graves Michael?G.?Ritchie 《Behavioral ecology and sociobiology》2004,57(2):149-154
Variation in paternity due to sperm competition or post-copulatory female choice has a major influence on animal mating system evolution and on the levels of genetic variability in natural populations. However, there are relatively few studies comparing the outcome of sperm-competition experiments in the laboratory with natural variation in polyandry among families from the field. In the bushcricket Ephippiger ephippiger, females mate multiply, and the males provide them with a large, nutritious, and probably expensive, donation at mating. We examined paternity in a series of laboratory matings, where females mated with two males, and amongst a series of families collected from a natural population. In the laboratory, paternity was highly bimodally distributed: 24% of families had offspring fathered by the first male to mate, 68% by the second male (in only 8% was paternity shared). In the field, paternity was more mixed: only 27% of families had a single father, 14% had more than two fathers, whilst 59% had two fathers. While unsuccessful matings may contribute to the highly biased paternity in the laboratory, they cannot fully explain the high incidence of complete P2 families. Nonrandom sperm utilisation is therefore likely. Greater sperm mixing in the field probably results from females mating with more males, but the distribution of paternity also reflects an active process of nonrandom sperm utilisation. Confidence of paternity due to last male advantage may be relatively high in this species, and therefore may have facilitated the evolution of the large spermatophore in E. ephippiger.Communicated by D. Gwynne 相似文献
996.
997.
In this paper, we explore how scenarios of future water withdrawals in a river basin are influenced by scale-dependent quantifications of the driving forces for two global-scale storylines. Either global-scale information or region-specific information is used to do the quantifications. In addition, we analyze the impact of including or not some restricted regional-scale information in the employed water use model. To develop scenarios of water withdrawals in the German part of the Elbe River basin, we applied the modules for domestic, thermoelectric power and manufacturing water use of the global water model WaterGAP, using scale-dependent driving forces scenarios and other scale-dependent model input. In the global-scale quantitative interpretations of the storylines of the IPCC SRES scenarios A1 and B2, all major driving forces of water withdrawals in the basin—population, thermoelectric power production and industrial gross domestic product—show vigorous increases between 2000 and 2025, while from the regional perspective, smaller increases but mostly decreases appear to be plausible. These discrepancies are partly due to the fact that for the global-scale interpretations only the historic developments until 1990 were taken into account, and not until 2000 as in the regional case. The resulting scenarios of sectoral water withdrawals in 2025 differ strongly between the two scale-dependent interpretations of the storylines, with the global one leading to much higher absolute water withdrawals and much lower withdrawal decreases between 2000 and 2025. Therefore, for regional assessments of water withdrawals, we recommend to embed the scenario analysis in global-scale storylines by performing regional-scale quantifications of the global qualitative driving forces scenarios, based on a limited amount of region-specific information. 相似文献
998.
Spatial proximity of emissions sources to receptors may affect sensitivity to potential adverse human health effects. This research investigates whether receptor sensitivity to the location of emission sources can be utilized efficiently to minimize health risk in selecting sites for industrial enterprises, thermal electric stations, etc. A sensitivity function that is independent of the location of pre-existing emission sources is derived and applied to Minsk, Belarus. The function estimates exposures based on weather and climatic conditions as well as the distribution of population density at a given locality. Arraying prospective sites based on their sensitivity function magnitude provides a technique for minimizing health risk based on receptor sensitivity to the spatial proximity of atmospheric emissions sources. 相似文献
999.
1000.