Capital and Operating Costs of Selected Air Pollution Control Systems—V

Several methods are available for estimating the capital costs of systems and each has its own degree of accuracy. These methods range from presenting overall installed costs on a per unit basis, to detailed cost estimates based on preliminary designs, schematics, and contractor quotes. The least accurate method is the equating of overall capital costs to a basic operating parameter such as tons per hour or cfm since this method only produces accuracies in the "order of magnitude" category, at best. The detailed cost estimate, in turn, can produce accuracies of ±5 % depending on the amount of preliminary engineering involved. These estimates, however, take many months of engineering effort and require process and engineering flow sheets, material and energy balances, plot plans, and equipment arrangement drawings before a cost estimate can be developed. For first-cut estimating purposes, the technique described in this article for developing capital costs for a specific pollution control system is based on the factored method of establishing direct and indirect installations costs as a function of known equipment costs. The cost factors developed are based on both quoted and estimated installation costs of pollution control systems. The annual operating costs for these systems are based on unit costs for utilities and operating and maintenance labor together with fixed percentages of capital costs for the indirect costs.     

ASsessment Of Alcohol Ethoxylate Surfactants And Fatty Alcohols Mixtures In River Sediments And Prospective Risk Assessment

A feasible and relatively readily available analytical method was adapted for the assessment of alcohol ethoxylates (AE) and fatty alcohols (FA) in sediments. This study illustrates the simultaneous measurement of 38 of 114 possible alcohol ethoxylate ethoxymers (AE) and fatty alcohols (FA) found in commercially important AE products. We predicted toxicity for all identified fractions, as well as the total mixture toxicity, relative to three exposure scenarios via sewage treatment plants (STP) for these widely used chemicals in consumer products and hence generate a preliminary environmental risk screening for AE and FA in sediments. The method is based on derivatization of solvent or solid-phase extracts with 2-fluoro-N-methylpyridinium p-toluenesulfonate (Pyr+). The derivatized extracts were analyzed with liquid chromatography/mass spectrometry (LC/MS) operating in the positive ion electrospray mode. The extraction efficiency of AE and FA in three different sediments of varying composition was evaluated with spike-recovery studies, ranging from 64% to 80%. The detection limits for individual ethoxymers typically ranged from 1 to 5ngg⁻¹on a dry weight basis. The mean limit of detection (LOD) was 6ngg⁻¹and the median LOD was 3ngg⁻¹. AE and FA in sediments were found to be stable for two weeks if preserved with 3% (v/v) formalin and stored at 4–6^∘C. Based on equilibrium partitioning, background concentrations of AE and FA were predicted to be below concentrations known to elicit chronically toxic effects. Total worst case mixture toxicities for all AE ethoxymers combined with FA were predicted to result in a risk quotient less than 0.6. Activated sludge treatment (STP) significantly reduced the release of total AE and FA by four-fold, suggesting that the total mixture risk quotient would be < 0.15 for sediment dependent organisms.     

Charging versus exclusion: Choice between recreation management tools

Overuse of recreation sites seems to justify regulation, and the principal tools for this are fee charging or physical exclusion. Both seem equally costly to administer. Both involve equal costs to consumers if recreationists visit from one origin, but if they come from different origins, costs may be greater and consumers' surplus less under either tool, depending on the shape of the demand curve. Which is the more equitable tool depends on the relative representation of rich and poor participants from near and distant origins. Potentially beneficial use of site revenues is an advantage of charging. Neither availability of substitutes nor variation in daily demand seems likely to change these results substantially, but a system of booking admissions before the trip outset might neutralize the advantages of charging. The optimal level of use varies with the regulatory tool chosen. The optimal admissions under exclusion could be fewer than or more than under charging, or may even be equal to unregulated use.     

Evaluating Quality of Life, Economic Vulnerabilities, and Drivers of Ecosystem Change

We examined regional conditions and trends related to quality of life and potential vulnerabilities of these factors to changes in the condition of natural resources in the Mid-Atlantic Region, USA. We selected a variety of variables on economic and socio-demographic conditions that demonstrate links between the condition of natural areas and human concerns and that quantify dependencies on resources. We extracted data from economic and population census databases for counties within the study area and present a subset of results of the cluster analyses used to describe condition and potential risks due to distinct combinations of variables. We found that the same variables used to judge quality of life were often correlated with increasing population and thus were likely to be related to land pressures and risks to natural resources. Within the region, economic dependence on resource-harvesting industries such as forestry and fisheries was low (less than 4% of total earnings at most), however, the potential for natural amenities to attract residents appeared to be growing as the self-employed and otherwise mobile people settled in areas with affordable housing and natural amenities. Suburban residential spread had been occurring in both the close-in and distant suburbs of the region's urban areas and some rural, growth appeared to be driven, in part, by businesses migrating to suburbs. Further work is needed to tease apart causal factors for the trends we observed, but correlations clearly existed in some areas between increasing populations and quality of natural surroundings.     

Iodine in terrestrial wildlife on the U.S. department of energy's Hanford Site in southcentral Washington

Iodine-129 in controlled amounts has been released into the air from the operating chemical separations facilities on the Hanford Site. Small amounts of ¹²⁹I have accumulated in surface soils especially at locations near the chemical separations facilities. Enriched levels of ¹²⁹I also occur in the thyroid glands of mule deer (Odocoileus hemionus) residing on the Hanford Site.Stable iodine is present in low concentrations in Hanford Site soils and it is not avidly accumulated by wild plants. Soils at high elevations have greater concentrations of ¹²⁷I than low elevations soils. Mule deer thyroids had higher concentrations of stable iodine than the thyroids of black-tailed jackrabbits. Stable iodine in black-tailed jackrabbit thyroids varied with the season with maximal concentrations in summer.Iodine-131 has not been released into the air from operating chemical separations facilities for more than 10 yr. Because of its short half-life ¹³¹I of Hanford Site origin has disappeared from the Hanford Site. In the event of a future restart of the chemical separations facilities black-tailed jackrabbits can be used as biological indicators of ¹³¹I in the terrestrial environment of the Hanford Site.     

Coupled changes in oxygen concentration and pH caused by metabolism of benthic coral reef organisms

Benthic marine primary producers affect the chemistry of their surrounding environment through metabolic processes. Photosynthesis and respiration will elevate or depress the concentration of oxygen in the diffusive boundary layer. Likewise, acid–base regulation and biomineralization/dissolution for calcifying species can alter the relative concentration of inorganic carbon species and thus pH. Here, we measured the relative ability of several common benthic primary producers from coral reef systems of the central Pacific and the Caribbean to simultaneously affect seawater oxygen concentration and pH values. Repeated measurements over a diel cycle confirmed that several primary producers substantially alter surrounding seawater chemistry over time. The majority of fleshy algae exhibited a stoichiometric ratio of oxygen to hydrogen ions not significantly different from one during daylight hours. In contrast, calcifiers exhibited significantly lower oxygen to hydrogen ion ratios that were unique for each species and were inversely correlated with known rates of calcification. These data provide the first quantitative estimates of the simultaneous influence of several species of benthic primary producers on water column oxygen concentrations and pH across different tropical reef systems. Finally, because more productive fleshy taxa have the potential to raise both oxygen and pH during the day to a greater extent than calcified species, our results suggest that some fleshy taxa may provide a buffering capacity to future ocean acidification scenarios.     

Effects of river-flow regulation on anuran occupancy and abundance in riparian zones

The natural flow regimes of rivers worldwide have been heavily altered through anthropogenic activities, and dams in particular have a pervasive effect on riverine ecosystems. Flow-regulation effects of dams negatively affect species diversity and abundance of a variety of aquatic animals, including invertebrates and fishes. However, the effects on semiaquatic animals are relatively unknown. We conducted anuran calling surveys at 42 study locations along the Broad and Pacolet Rivers in South Carolina to address the potential effects of flow regulation by damming on anuran occupancy and abundance. We estimated occupancy and abundance with Program PRESENCE. Models incorporated distance upstream and downstream from the nearest dam as covariates and urbanization pressure as an alternative stressor. Distance from dam was associated with occupancy of 2 of the 9 anuran species in our analyses and with abundance of 6 species. In all cases, distance downstream from nearest dam was a better predictor of occupancy and abundance than distance upstream from nearest dam. For all but one species, distance downstream from nearest dam was positively correlated with both occupancy and abundance. Reduced occupancy and abundance of anurans likely resulted from downstream alterations in flow regime associated with damming, which can lead to reduced area of riparian wetlands that serve as anuran breeding habitat. Our results showed that damming has a strong negative effect on multiple anuran species across large spatial extents and suggest that flow regulation can affect semiaquatic animals occupying riparian zones.     

Organizational exit pressures and role stress: Impact on mental health

Hypotheses regarding role stress, chronic burden and two forms of vulnerability to mental health symptoms are tested in a longitudinal sample of 590 caregivers working in group homes for the mentally ill. In addition, an organizational exit pressure hypothesis is offered. Measures of exit pressure are identified and incorporated into predictive models of stress and mental health. Exit pressures affect somatization directly and interact with role ambiguity to affect subsequent levels of anxiety and somatization. The results suggest that selection pressures in and out of social settings should be conceptualized as part of models of stress and mental health.     

The Role of Soil Surface Crusting in Desertification and Strategies to Reduce Crusting

Soil crusting decreases infiltration, increases erosion, and impedes vegetation establishment, so reducing the impact of crusting is of major importance in combating desertification. Although surface crusting has been the subject of considerable research over the past 50 years or more, the practical management of soil crusts remains a challenge for many dryland communities. Crusting occurs in two steps, an initial aggregate breakdown period that occurs under rainfall and a subsequent hardening phase during drying. Several factors influence crust development, but the single most important one is soil aggregate stability. Strategies to reduce crusting can be based either on protecting the surface from raindrop impact or improving aggregate stability, or a combination of both. However, crust control is labor and/or capital intensive and must be thought out clearly in terms of the benefits to be achieved.