Journal of Material Cycles and Waste Management - Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and... 相似文献
Currently, activated coke is widely used in the removal of multiple pollutants from industrial flue gas. In this paper, a series of novel FexLayOz/AC catalysts was prepared by the incipient wetness impregnation for NH3-SCR denitrification reaction. The introduction of Fe-La bimetal oxides significantly improved the denitrification performance of activated coke at mid-high temperature, and 4% Fe0.3La0.7O1.5/AC exhibited a superior NOx conversion efficiency of 90.1% at 400 °C. The catalysts were further characterized by BET, SEM, XRD, Raman, EPR, XPS, FTIR, NH3-TPD, H2-TPR, et al., whose results showed that the perovskite-type oxide of LaFeO3 and oxygen vacancies were produced on the catalysts’ surfaces during roasting. Fe-La doping enhanced the amount of acid sites (mainly Lewis and other stronger acid sites) and the content of multifarious oxygen species, which were beneficial for NOx removal at mid-high temperature. Moreover, it was investigated that the effect of released CO from activated coke at mid-high temperature on the NOx removal through the lifetime test, in which it was found that a large amount of CO produced by pyrolysis of activated coke could promote the NOx removal, and long-term escaping of CO on the activated coke carrier did not have a significant negative impact on catalytic performance. The results of the TG-IR test showed that volatile matter is released from the activated coke while TG results showed that the weight loss rate of 4% Fe0.3La0.7O1.5/AC only was 0.0015~0.007%/min at 300–400 °C. Hence, 4% Fe0.3La0.7O1.5/AC had excellent thermal stability and denitrification performance to be continuously used at mid-high temperature. Finally, the mechanisms were proposed on the basis of experiments and characterization results.
通过降低氢气的温度,可以实现更高密度的氢气储存,进而有效提升存储及运输的效率。为探究储氢温度对加氢站泄漏爆炸事故的影响规律,利用FLACS 软件对加氢站内长管拖车在不同储氢温度条件下(50、100、200 与300 K)发生泄漏后的氢气扩散和爆炸事故进行分析。研究结果表明:随着储氢温度的降低,高压氢气射流撞击防爆墙后可燃气云达到稳定的时间、扩散范围和冻伤区域均逐渐增大,而最大爆炸超压和爆炸危险距离则呈现出先增大后减小的趋势;储氢温度为50 K 时的轻微冻伤距离比储氢温度100 K 和200 K 时分别增加了近1 倍和7 倍,严重冻伤距离也最大;储氢温度为100 K 时泄漏气云爆炸产生的超压峰值比常温氢气爆炸提高了近3 倍,危险区域也最大;储氢温度为200 K 时,达到爆炸超压峰值的时间最快,储氢温度为50 K 时最慢。 相似文献