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571.
572.
EPA's “Third Symposium on Fabric Filters for Particle Collection,” held in Tucson December 5 and 6, 1977, emphasized the results obtained from both laboratory and field experience. Data from selected new and/or continuing research programs as well as from new pilot and field applications are reviewed.  相似文献   
573.
574.
The thermal decomposition of SF6 is known to be oxygen-independent. Nevertheless, because of its high stability, the use of SF6 as a "conservative" surrogate in incinerator performance evaluation has been advocated and researched. This paper shows that refractory decreases markedly the stability of SF6. The resulting increase in SF6 decomposition was from 0 percent to 95 percent at 900°C, and the temperatures at which 90-99 percent decomposition occurred were lowered by 300-150°C. Refractory also decreased the stability of CCl4 and C2Cl4, but to a lesser extent. The difference between the decompositions of C2Cl4 and SF6 was reduced from several orders of magnitude to a factor of 2-4. Such a drastic and adverse change in relative stability could render SF6 unsuitable as a "conservative" surrogate. The requirements for a "conservative" surrogate and the need for caution in its use are discussed, and further research areas are indicated.  相似文献   
575.
  总被引:8,自引:0,他引:8  
Sidhu S  Graham J  Striebich R 《Chemosphere》2001,42(5-7):681-690
Motor vehicle emissions are a major anthropogenic source of air pollution and contribute to the deterioration of urban air quality. In this paper, we report results of a laboratory investigation of particle formation from four different alternative diesel fuels, namely, compressed natural gas (CNG), dimethyl ether (DME), biodiesel, and diesel, under fuel-rich conditions in the temperature range of 800-1200 degrees C at pressures of approximately 24 atm. A single pulse shock tube was used to simulate compression ignition (CI) combustion conditions. Gaseous fuels (CNG and DME) were exposed premixed in air while liquid fuels (diesel and biodiesel) were injected using a high-pressure liquid injector. The results of surface analysis using a scanning electron microscope showed that the particles formed from combustion of all four of the above-mentioned fuels had a mean diameter less than 0.1 microm. From results of gravimetric analysis and fuel injection size it was found that under the test conditions described above the relative particulate yields from CNG, DME, biodiesel, and diesel were 0.30%. 0.026%, 0.52%, and 0.51%, respectively. Chemical analysis of particles showed that DME combustion particles had the highest soluble organic fraction (SOF) at 71%, followed by biodiesel (66%), CNG (38%) and diesel (20%). This illustrates that in case of both gaseous and liquid fuels, oxygenated fuels have a higher SOF than non-oxygenated fuels.  相似文献   
576.
577.
  总被引:2,自引:0,他引:2  
Soil samples from paddy fields, uplands, and urban areas (gardens and roadsides) collected from Vietnam, Thailand, and Taiwan were analysed to determine the residual levels of persistent organochlorine compounds such as DDTs, HCHs, and PCBs. DDT concentration in soil samples from Vietnam were found to be highest, with a mean value of 110 ng g(-1), and were followed by those in Taiwanese soils with a mean value of 20 ng g(-1). HCH concentrations were highest in soil samples from Vietnam (a mean value of 4.8 ng g(-1)) and were followed by those from Taiwan (a mean value of 1.4 ng g(-1)). Concentrations of PCBs were found to be highest in Taiwanese soil samples, with a mean of 95 ng g(-1). Interestingly, relatively high concentrations of PCBs in rural cultivated-soil samples from Vietnam were recorded with a mean value of 25 ng g(-1), probably suggesting PCB release from different kinds of weapons used during the Second Indochina war. The lowest concentrations of DDTs, HCHs, and PCBs were obtained in soil samples from Thailand, with mean values of 8.3 ng g(-1), 0.4 ng g(-1), and 2.7 ng g(-1), respectively.  相似文献   
578.
    
Oxidation of d-limonene, which is a common monoterpene, can lead to new aerosol particle formation in indoor environments. Thus, products containing d-limonene, such as citrus fruits, air refresheners, household cleaning agents, and waxes, can act as indoor air aerosol particle sources. We released d-limonene into the room air by peeling oranges and measured the concentration of aerosol particles of three different size ranges. In addition, we measured the concentration of d-limonene, the oxidant, and the concentration of ozone, the oxidizing gas. Based on the measurements we calculated the growth rate of the small aerosol particles, which were 3–10 nm in diameter, to be about , and the losses of the aerosol particles that were due to the coagulation and condensation processes. From these, we further approximated the concentration of the condensable vapour and its source rate and then calculated the formation rate of the small aerosol particles. For the final result, we calculated the nucleation rate and the maximum number of molecules in a critical cluster. The nucleation rate was in the order of and the number of molecules in a critical-sized cluster became 1.2. The results were in agreement with the activation theory.  相似文献   
579.
  总被引:4,自引:0,他引:4  
Aranami K  Readman JW 《Chemosphere》2007,66(6):1052-1056
A 12-days photolysis experiment of triclosan, a widely used bactericide, was performed in freshwater and seawater under a low intensity artificial white light source. Photodegradation of triclosan was observed in both the freshwater and seawater samples. Assuming a first-order reaction, half-lives of triclosan in the freshwater and seawater were approximately 8 and 4 days, respectively. 2,8-Dichlorodibenzo-p-dioxin (DCDD) was detected in both the freshwater and seawater samples after 3 days of irradiation. The photodegradation of triclosan and the production of DCDD suggest that triclosan could be less stable and DCDD might be more stable in seawater than freshwater. As a result, DCDD produced from triclosan survives for a longer time in seawater.  相似文献   
580.
The characterisation by ICP-MS of an isolated Pu-U hot particle originating from the nuclear weapons accident in Palomares (Spain) shows, for the first time, that its uranium content is highly enriched in (235)U. The enrichment has been confirmed by independent analyses of two surface soil samples collected in a heavily contaminated area close to the impact point of one of the bombs. This finding clarifies better the composition of the weapons involved in the accident and is of importance when the inventory of U and Pu in the contaminated area are to be calculated.  相似文献   
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