A new method for municipal solid waste incinerator (MSWI) fly ash inertization, based on colloidal silica

Municipal solid waste incineration (MSWI) is a straightforward way to manage waste, however the disposal of process byproducts, mainly bottom and fly ash, is still a problem, because of their hazardous contents. Fly ash is a byproduct of many other processes that involve combustion to produce energy. In this paper we present and discuss a new method for MSWI fly ash inertization, mainly based on the use of colloidal silica as a stabilization agent for metals. In the patented procedure, fly ash of different provenance can be used to produce an inert and non-hazardous material, that can be reused. In fact to make the recovery process more efficient, landfilling should be totally avoided. For this reason, to enhance the possibility of reuse, a washing process, for salts recovery, is proposed as a final step of the inertization procedure. The obtained inert material is called COSMOS (COlloidal Silica Medium to Obtain Safe inert), and it is composed of calcium carbonate, calcium sulfate, silicon oxide and a wide quantity of non-soluble amorphous compounds. COSMOS does not contain any corrosive salts. This makes it extremely interesting for cement industry applications with several other advantages, and environmental benefits. The new proposed inertization procedure appears very promising, because it allows MSWI fly ash to be considered a valuable resource. Thanks to the obtained results, a demonstration project, in the frame of LIFE+, has been funded by the European Commission (LIFE+ 2008 project ENV/IT/000434, ).     

Some considerations on the use of simple box models of contaminant fate in soils

A simple box model computing time-averaged concentrations in soil and water of contaminants such as pesticides, following a pulse emission under the assumption of constant removal rates, is presented and evaluated against a benchmark model and some lysimeter experiments representative of different soil and climate settings in Europe. The simple box model allows capturing to some extent the trends of contaminant releases observed from lysimeters or predicted by the benchmark model. This suggests that the correct order of magnitude of environmental concentrations and loads of contaminants can be described as a first approximation by a very simple back-of-the-envelope calculation. In the calculation, the time lag between contaminant application and the start of runoff or leaching should be considered. In the absence of more detailed information, repeating the calculation for the extreme cases of zero and one month lag yields a reasonably realistic range, and the geometric mean of the two is suggested as a first guess estimate. This configures a practical approach for the screening of contaminant losses especially suited for the mapping of predicted environmental concentrations (PECs) for assessment at broad scale (such as continental Europe, a country or a large catchment), where contingent determinants of contaminant fate tend to be averaged out and use of more detailed models usually promises to yield little improvement of PECs.     

Grab and passive sampling applied to pesticide analysis in the São Lourenço river headwater in Campo Verde – MT,Brazil

In this study, the quality of surface water in the headwaters of São Lourenço River in Mato Grosso, Brazil, was evaluated in relation to contamination by pesticides. For this purpose, samples were collected between December 2015 and June 2016 by grab sampling and by passive sampling using an integrative polar organic compound sampler installed in the field during four 14-day cycles between March and June 2016. The analyses were performed by gas chromatography (CG/MS) and by liquid chromatography (UPLC-MS/MS). The results showed the detection of two pesticides (atrazine and pyraclostrobin) of the five analyzed by passive sampling and eight active principles among the 20 analyzed (malathion, diuron, carbofuran, carbendazim, trifluralin, imidacloprid, metolachlor, and acetamiprid) by grab sampling. The detection of 10 pesticides, even almost a decade after the beginning of a recovery process of the ciliary forest, confirms the headwaters' vulnerability to these contaminants and passive sampling proved to be an important tool in capturing small concentrations of pesticides constituting an interesting complement to grab sampling.     

Metal concentrations in used engine oils: Relevance to site assessments of soils

Used engine oils contain metals, which upon entering soils may pose risks to human health or the environment. In this study, previously published concentrations of 23 metals in 213 used engine oil samples from the early 1970s to the mid-1990s are statistically evaluated. Neat (100%) used engine oils were found to contain relatively high concentrations of lead, calcium, and zinc, attributable to piston blow-by of leaded gasoline, calcium salt detergent additives, and zinc-bearing anti-corrosion/anti-oxidation additives, respectively. Wear metal concentrations were lower. The lead concentration in used engine oils in the U.S. declined between the 1970s and early 1990s, potentially providing a basis to constrain the “age” of used engine oil(s) in soils. The concentrations of 23 metals in used engine oils were compared to soil risk benchmarks in 15 representative jurisdictions in the U.S., Canada, Australia, and Europe. The maximum concentrations in neat (100%) used engine oil of eight metals – Be, Co, Fe, Mn, Ni, Se, Ag, and Ti – were lower than their collective minimum benchmarks in soils for the jurisdictions surveyed, indicating their concentrations in soils could not be reasonably expected to exceed any soil benchmarks. Nine metals (As, Ba, Cd, Cr, Cu, Pb, Sn, V and Zn), but particularly arsenic, cadmium, lead, tin, and zinc, were identified as potential contaminants of concern (PCOC) for soils from locations impacted with used engine oils, owing to their higher median concentrations (i.e., 2.5, 1.4, 1038, 5.0, and 922 mg/kg in oil, respectively) relative to most soil benchmarks. Site-specific benchmarks and metal concentrations at reasonable oil in soil concentrations require consideration when developing the suite of PCOC metal analytes for conducting site assessments of soils impacted by used engine oil.     

Specific Features of Wild Boar,Sus scrofa,Rooting Activity at the Northern Boundary of Its Range in Western Siberia

Russian Journal of Ecology -     

Ecophysiology of Steppe Mouse Subspecies <Emphasis Type="Italic">Mus spicilegius spicilegus</Emphasis>, Peteni, 1883 (Rodentia,Mammalia) at the South Boundary of its Distribution

Diet, food preferences and main ecophysiological characteristics such like energy requirements and thermoregulation characteristics of Mus spicilegus spicilegus (Petenyi, 1882) were studied. The most preferred foods for the mice were seeds of weed species that composed more than 85% of their diet. The results of food selection experiments shows that the total daily consumption by mice is 2.77 ± 0.76 g/animal/day or 5.5 kJ/g/day or 84.9 kJ/animal/day. From the total daily energy consumption 16.4% go back to nature in the form of feces and urine and the rest 83.6% animals utilized for assimilation. The results of the temperature preferences for Mus s. spicilegus shows preferred temperature zone from around 26 to 36°C where mice spent about 72% of the experimental time. The lowest value of oxygen consumption for resting metabolism rate (RMR) was registered at 30°C–3.20 ± 0.71 cm³ O₂/g/h. It is possible to consider that the thermoneutral zone is around these temperature values. The obtained results give reason to conclude that from an ecophysiologycal point of view the climate in the south boundary of distribution provides optimal conditions for species development. The main cause for population decreasing probably is the loss of open habitats including natural steppe grasslands.     

Assessment of the State of Lung Lichen, <Emphasis Type="Italic">Lobaria pulmonaria</Emphasis> (L.) Hoffm., in Forest Communities with Different Times Since Disturbance in the Northeast of European Russia

Quantitative parameters of cenopopulations of Lobaria pulmonaria, an endangered cyanolichen, have been studied in spruce phytocenoses of Karelia recovering after disturbance through the successional stage of aspen stands for a period ranging from 80 to 450 years. The results show that, as the time since disturbance increases, the total number of L. pulmonaria thalli and the number of colonized substrate units increase as well, with no stabilization of these parameters being observed in the series of communities studied. The total area of thalli in the phytocenoses is restored within approximately 200 years after the last disturbance. In old-growth forests (>400 years), L. pulmonaria thalli colonize a broad spectrum of tree species in different life states, including lower branches of young spruce trees. Even if they serve as temporary substrates, this can markedly strengthen the potential of the species for further expansion within the community in case of shortage in the main phorophyte (aspen). Thus, the proportion of regressive populations decreases, while that of colonizing populations increases, which is indicative of successful reproduction of the species.     

Making spatial development scenario for south of Bushehr province,Iran, based on strategic foresight

In recent years, the science of foresight has been entered into planning activities by urban and regional planners and this science has impacted on planning activities. This study discusses spatial development in the south of Bushehr province using the foresight approach. The general aim of this research is to compile scenarios for the development of the mentioned study area which comprises the southern part of Bushehr province including four counties of Dayyer, Jam, Kangan and Asaluyeh. The main reason for selecting this region is their direct impressibility by major changes in the country’s oil and gas industry. This research has extremely made use of the Delphi and cross-impact analysis methods to develop foresight scenarios. Using the Delphi method, 30 initial factors were identified in the economic, political-security, linkages, science and technology, manufacturing, natural, social, infrastructural and residential issues and then the cross-impact matrix was used to investigate the impact of factors on each other. In the next step, the ranking of direct and indirect factors was determined by Micmac software and on this basis, the final refining in the selection of drivers was done. In the final stage, axes of future scenarios were presented and then the future scenarios were drawn. Results of this research indicate that two main drivers namely Iran’s international relations and energy resources are the main axes of scenarios. These two drivers have more uncertainty and higher importance than other factors and the results in four scenarios showing the possibility of each situation’s occurrence.     

Effects of meteorology on ground-level ozone (GLO) concentrations and identifying the hot spots having significantly higher GLO concentration in a semi-urban area

The present study aims to analyse the influences of five meteorological parameters (temperature, wind speed, barometric pressure, rainfall, and solar radiations) on ground-level ozone (GLO) concentrations over the region of Ranchi Municipal Corporation (Jharkhand, India). The diurnal variation of GLO concentration and the meteorological parameters were analysed in each month to understand the associations. The results indicated that the correlation coefficients of GLO concentration with SR, AT, and DPT are found to be positive in each month and also statistically significant. But, the association between WS and GLO concentration was not uniform between the study days. Furthermore, the study also demonstrates an approach for identifying the hot spots that are having the higher level of GLO concentration. The hot spot maps were produced for each month to understand the shifting of the locations of hot spot locations. The results reveal that the hot spot locations are changes frequently in each case. Since the hot spot analysis was conducted with limited data, the presented hot spots are indicative and dependent on the meteorological conditions of the specific period and cannot be considered as a robust epidemiological study.     

Closing the material cycle of biomass-derived fly ashes: a regional case study of natural ageing in Finland

Journal of Material Cycles and Waste Management - The amount of biomass-derived ashes is expected to rise in the EU due to targets to increase the use of renewable energy resources. To promote the...