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981.
982.
Karanja oil, containing 6.2% free fatty acids (FFAs), was considered for biodiesel production using a single-step solid-phase acid catalyzed process. Different types of zeolites and Amberlyst15 catalysts were tested and biodiesel was produced. Under similar conditions, the highest biodiesel yield was achieved using an Amberlyst15 catalyst, which contained 3–5% of moisture. The effects of operating parameters of the reaction such as reaction temperature, catalyst amount, and methanol-to-oil ratio were studied. An increase of methanol:oil ratio revealed a non-monotonic increase in biodiesel yields. Similar non-monotonic behavior was observed when Jatropha oil was used. Leaching and catalyst reusability were also considered. No significant effects of leaching were observed and catalyst reusability appeared to be affected by methanol interactions. The presence of a co-solvent, Tetrahydrofuran (THF), increased the biodiesel yield. Furthermore, an optimum amount of THF (THF:methanol volume ratio of 1:2) gave rise to the highest biodiesel yield. A biodiesel yield of 93% was achieved at 120 °C using a single-step process with Amberlyst15 as a catalyst, THF as a co-solvent, and a methanol:oil ratio of 30:1. 相似文献
983.
Proliferation of Glycogen Accumulating Organisms (GAOs) accounts as one of the major bottlenecks in biological phosphorus removal systems. GAO outcompeting polyphosphate accumulating organisms (PAOs) results in lower P-removal. Thus, finding optimal conditions that favour PAO in front of GAO is a current focus of research. This work shows how nitrite can provide a novel strategy for PAO enrichment. A propionate-fed GAO-enriched biomass (70% Defluviicoccus I, 18% Defluviicoccus II and 10% PAO) was subjected more than 50 d under anaerobic-anoxic conditions with nitrite as electron acceptor. These operational conditions led to a PAO-enriched sludge (85%) where GAO were washed out of the system (<10%), demonstrating the validity of the new approach for PAO enrichment. In addition, the presented suppression of Defluviicocus GAO with nitrite represents an add-on benefit to the nitrite-based systems since the proliferation of non-desirable GAO can be easily ruled out and added to the other benefits (i.e. lower aeration and COD requirements). 相似文献
984.
Aniza K. Verma Avanish K. Srivastava Beer Singh Dilip Shah Smriti Shrivastava Chandra Kant P. Shinde 《Chemosphere》2013,90(8):2254-2260
1-(4-Chlorophenyl))-N-hydroxymethanimine and cyclohexyl-N-hydroxymethanimine were synthesized and a well-established oxime, i.e., 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride was purchased. Thereafter; all were loaded over Al2O3 using incipient wetness technique. The prepared systems were characterized using surface area analyzer, scanning electron microscope, energy dispersive X-ray spectrophotometer, Fourier transform infrared spectrophotometer and thermogravimetric analyzer. Kinetics of the degradation of sarin (GB) and simulant, i.e. diethylchlorophosphate (DEClP) was studied over synthesized oxime impregnated Al2O3 and results were compared with well reported oxime impregnated Al2O3. Kinetics of reaction was found to be following the pseudo first order reaction kinetics. The order of reactivity of the prepared systems was found to be cyclohexyl-N-hydroxymethanimine/Al2O3 > 1-(4-chlorophenyl)-N-hydroxymethanimine/Al2O3 > 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride/Al2O3 > Al2O3. From the reaction kinetics it was observed that the reaction with DEClP was faster than with GB. Cyclohexyl-N-hydroxymethanimine/Al2O3 was found to be the most reactive system with half-life of 0.94 and 15 h for DEClP and GB respectively. 相似文献
985.
Vikram Bhardwaj Dhruv Sen Singh Abhay K. Singh 《Environmental monitoring and assessment》2010,171(1-4):321-344
Chhoti Gandak river basin, situated in the Ganga Plain, is one of India’s most productive cane-sugar industrial belts. Soil and groundwater samples were collected to investigate the impacts of these industries on the environment of the Chhoti Gandak river basin with special reference to soil and water. The results show that concentration of most metals are affected by industrial activities and surrounding agricultural practices. It is evidenced by increased heavy metal concentration in the soils as well as in the aquifers. Metals such as Pb, Cu, and Zn in the soil around the industrial sets are found significantly higher than their normal values in the soil. Metals like Fe and Mn in the groundwater are more than the permissible limit prescribed by the World Health Organization. In this study, an attempt was made to distinguish between the naturally occurring and anthropogenically induced metals in the soil. Analysis of geochemical properties, disposal of industrial wastes, inadequate application of agrochemicals, and their impact on environment indicate the sustainable implementation of integrated wastewater management plan in these industrial sets and also in similar situations. 相似文献
986.
Bibhash C. Verma Siba Prasad Datta Raj K. Rattan Anil K. Singh 《Environmental monitoring and assessment》2010,171(1-4):579-593
Soil organic matter not only affects sustainability of agricultural ecosystems, but also extremely important in maintaining overall quality of environment as soil contains a significant part of global carbon stock. Hence, we attempted to assess the influence of different tillage and nutrient management practices on various stabilized and active soil organic carbon pools, and their contribution to the extractable nitrogen phosphorus and sulfur. Our study confined to the assessment of impact of agricultural management practices on the soil organic carbon pools and extractable nutrients under three important cropping systems, viz. soybean–wheat, maize–wheat, and rice–wheat. Results indicated that there was marginal improvement in Walkley and Black content in soil under integrated and organic nutrient management treatments in soybean–wheat, maize–wheat, and rice–wheat after completion of four cropping cycles. Improvement in stabilized pools of soil organic carbon (SOC) was not proportional to the applied amount of organic manures. While, labile pools of SOC were increased with the increase in amount of added manures. Apparently, green manure (Sesbania) was more effective in enhancing the lability of SOC as compared to farmyard manure and crop residues. The KMnO4-oxidizable SOC proved to be more sensitive and consistent as an index of labile pool of SOC compared to microbial biomass carbon. Under different cropping sequences, labile fractions of soil organic carbon exerted consistent positive effect on the extractable nitrogen, phosphorus, and sulfur in soil. 相似文献
987.
Hydrogeochemical studies were carried out in the Penna–Chitravathi river basins to identify and delineate the important geochemical processes which were responsible for the evolution of chemical composition of groundwater. The area is underlain by peninsular gneissic complex of Archaean age, Proterozoic meta-sediments, and strip of river alluvium. Groundwater samples were collected covering all the major hydrogeological environs in pre- and post-monsoon seasons. The samples were analyzed for major constituents such as Ca2?+?, Mg2?+?, Na?+?, K?+?, CO3 ???, HCO3 ???, Cl???, SO2 ???4, NO3 ???, and F???. The groundwater in general is of Na?+?–Cl???, Na?+?–HCO3 ???, Ca2?+?–Mg2?+?–HCO3 ???, and Ca2?+?–Mg2?+?–Cl??? types. Na?+? among cations and Cl??? and/or HCO3 ??? among anions dominate the water; Na?+? and Ca2?+? are in the transitional state with Na?+? replacing Ca2?+? and HCO3 ??? Cl??? due to physiochemical changes in the aquifer and water–rock interactions. The Ca2?+?–Mg2?+?–Cl??? HCO3 ??? type water in one third samples suggest that ion exchange and dissolution processes are responsible for its origin. Change in storage of aquifer in a season does not influence the major geochemical makeup of groundwater. Gibbs plots indicate that the evolution of water chemistry is influenced by water–rock interaction followed by evapotranspiration process. The aquifer material mineralogy together with semiarid climate, poor drainage system, and low precipitation factors played major role in controlling groundwater quality of the area. 相似文献
988.
Furquan Ahmad Ansari Altaf Husain Khan Devendra Kumar Patel Huma Siddiqui Shachi Sharma Mohammad Ashquin Iqbal Ahmad 《Environmental monitoring and assessment》2010,170(1-4):491-497
In order to evaluate the exposure of the northern India rural population to polyaromatic hydrocarbon (PAH) inhalation, indoor pollution was assessed by collecting and analyzing the respirable particulate matter PM2.5 and PM10 in several homes of the village Bhithauli near Lucknow, UP. The home selection was determined by a survey. Given the nature of biomass used for cooking, homes were divided into two groups, one using all kinds of biomass and the second type using plant materials only. Indoor mean concentrations of PM2.5 and associated PAHs during cooking ranged from 1.19 ± 0.29 to 2.38 ± 0.35 and 6.21 ± 1.54 to 12.43 ± 1.15 μg/m3, respectively. Similarly, PM10 and total PAHs were in the range of 3.95 ± 1.21 to 8.81 ± 0.78 and 7.75 ± 1.42 to 15.77 ± 1.05 μg/m3, respectively. The pollutant levels during cooking were significantly higher compared to the noncooking period. The study confirmed that indoor pollution depends on the kind of biomass fuel used for cooking. 相似文献
989.
Raj Kumar Singh Manoj Datta Arvind Kumar Nema 《Environmental Modeling and Assessment》2010,15(6):549-567
In developing countries, several old municipal solid waste dumps (unlined landfills) exist adjacent to large cities, releasing
contaminants to the underlying aquifer, thus posing the hazard of groundwater contamination. These uncontrolled waste dumps
need to be prioritized in terms of the groundwater contamination hazard posed by them, so that necessary control and remedial
measures can be undertaken in a phased manner. This paper presents a time-dependent system for evaluating groundwater contamination
hazard rating of municipal solid waste dumps. The system is based on source–pathway–receptor relationships and evaluates the
relative value of hazard posed by a site over its entire leaching life, on a scale of 0–1,000. The system parameters have
been selected based on literature and expert opinions. The Delphi technique is used to derive the relative importance weights
of the system parameters. The proposed system is compared with six selected existing hazard rating systems. The comparison,
made by way of score range analysis, shows that the proposed system exhibits a much wider range of hazard scores for various
scenarios of site conditions, and hence the proposed system is more sensitive to varied site conditions. The application of
different systems to six municipal solid waste dumps located in four cities of India shows that, whereas the existing systems
individually produce clustered scores and return the same rank to more than one site, the proposed system produces significantly
varying scores and return different ranks to different sites. This demonstrates that the proposed system improves decision
making and makes a better basis for prioritization of municipal solid waste dumps for adopting control and remedial measures. 相似文献
990.
Munmun Chakarvorty Jayanta Kumar Pati Shiva Kumar Patil Swati Shukla Ambalika Niyogi Arun Kumar Saraf 《Environmental monitoring and assessment》2014,186(5):2965-2978
The winter fog in India is a recurrent phenomenon for more than a decade now affecting the entire Himalayan and sub-Himalayan regions covering an area of nearly 500,000 km2. Every winter (December–January), the air and surface transports in cities of northern India (Amritsar, New Delhi, Agra, Gwalior, Kanpur, Lucknow, and Allahabad) are severely disrupted with visibility reduced to <50 m at times. Since dust particles are known to act as nuclei for the fog formation, this study is aimed to carry out physicochemical characterization of the dust particulates accumulated during a protracted fog period from one of the severely fog affected cities of north India (Allahabad; 25°27′33.40″N–81°52′45.47″E). The dust-loaded tree leaves belonging to Ficus bengalensis and Ficus religiosa from 50 different locations between January 24 and 31, 2010 are sampled and characterized. The mass of dust, color, grain shape, size, phase constituents, and mineral magnetic parameters, such as magnetic susceptibility, SIRM, χ fd%, and S-ratio, show minor variation and the regional influence outweighs local anthropogenic contributions. The dust compositions show fractionated rare earth element pattern with a pronounced negative Eu anomaly similar to upper continental crust and further suggesting their derivation from sources located in parts of north and central India. 相似文献