全文获取类型
收费全文 | 135篇 |
免费 | 3篇 |
国内免费 | 8篇 |
专业分类
废物处理 | 19篇 |
环保管理 | 11篇 |
综合类 | 17篇 |
基础理论 | 33篇 |
污染及防治 | 49篇 |
评价与监测 | 12篇 |
社会与环境 | 5篇 |
出版年
2023年 | 6篇 |
2022年 | 8篇 |
2021年 | 10篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 9篇 |
2017年 | 6篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 19篇 |
2012年 | 2篇 |
2011年 | 11篇 |
2010年 | 1篇 |
2009年 | 15篇 |
2008年 | 9篇 |
2007年 | 9篇 |
2006年 | 2篇 |
2005年 | 5篇 |
2004年 | 2篇 |
2002年 | 4篇 |
2000年 | 2篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有146条查询结果,搜索用时 328 毫秒
121.
Kauser Jahan Raúl Ordóñez Ravi Ramachandran Shira Balzer Michael Stern 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):395-404
Nonylphenol is the primary breakdown product of nonylphenol ethoxylates, a certain class of nonionic surfactants. Nonylphenol
has been found to be toxic to aquatic organisms and has been suspected of being harmful to humans due to its xenoestrogenic
properties. Although there are known releases of nonylphenol to the environment, there is a lack of data describing the extent
of biodegradation. This study thus focuses on much needed information on the biodegradation kinetics of nonylphenol. Oxygen
uptake, cell growth and nonylphenol removal data were collected using batch reactors in an electrolytic respirometer. Nonylphenol
removal, cell growth and substrate removal rates were modeled by the Monod, Haldane, Aiba, Webb, and Yano equations. The differential
equations were solved by numerical integration to simulate cell growth, substrate removal, and oxygen uptake as a function
of time. All models provided similar results with the Haldane model providing the best fit. The values of the kinetic parameters
and the activation energy for nonylphenol were determined. These values can be used for predicting fate and transport of nonylphenol
in the environment. The validity of applying each model to the biodegradation of nonylphenol was analyzed by computing the
R
2 values of each equation. 相似文献
122.
Juhasz AL Smith E Weber J Rees M Rofe A Kuchel T Sansom L Naidu R 《Chemosphere》2008,71(10):1963-1969
Considerable information is available in the literature regarding the uptake of arsenic (As) from contaminated soil and irrigation water by vegetables. However, few studies have investigated As speciation in these crops while a dearth of information is available on As bioavailability following their consumption. In this study, the concentration and speciation of As in chard, radish, lettuce and mung beans was determined following hydroponic growth of the vegetables using As-contaminated water. In addition, As bioavailability was assessed using an in vivo swine feeding assay. While As concentrations ranged from 3.0 to 84.2mg As kg(-1) (dry weight), only inorganic As (arsenite and arsenate) was detected in the edible portions of the vegetables. When As bioavailability was assessed through monitoring blood plasma As concentrations following swine consumption of As-contaminated vegetables, between 50% and 100% of the administered As dose was absorbed and entered systemic circulation. Arsenic bioavailability decreased in the order mung beans>radish>lettuce=chard. 相似文献
123.
Degradation of fenamiphos in soils collected from different geographical regions: the influence of soil properties and climatic conditions 总被引:1,自引:0,他引:1
Cáceres T Megharaj M Naidu R 《Journal of environmental science and health. Part. B》2008,43(4):314-322
The persistence of fenamiphos (nematicide) in five soils collected from different geographical regions such as Australia, Ecuador and India under three temperature regimes (18, 25 and 37 degrees C) simulating typical environmental conditions was studied. The effect of soil properties (soil pH, temperature and microbial biomass) on the degradation of fenamiphos was determined. The rate of degradation increased with increase in temperature. Fenamiphos degradation was higher at 37 degrees C than at 25 and 18 degrees C (except under alkaline pH). The degradation pathway differed in different soils. Fenamiphos sulfoxide (FSO) was identified as the major degradation product in all the soils. Fenamiphos sulfone (FSO2), and the corresponding phenols: fenamiphos phenol (FP), fenamiphos sulfoxide phenol (FSOP) and fenamiphos sulfone phenol (FSO2P) were also detected. The degradation of fenamiphos was faster in the alkaline soils, followed by neutral and acidic soils. Under sterile conditions, the dissipation of the pesticide was slower than in the non-sterile soils suggesting microbial role in the pesticide degradation. The generation of new knowledge on fenamiphos degradation patterns under different environmental conditions is important to achieve better pesticide risk management. 相似文献
124.
Field‐scale estimation of gas permeability and subsequent computation of pore‐gas velocity profiles are critical elements of sound soil venting design. It has been our experience, however, in U.S. Environmental Protection Agency's (EPA's) technical assistance program, provided by the Office of Research and Development in support EPA regional offices, that many venting practitioners are unaware of equations and data interpretation methods appropriate for gas permeability estimation and pore‐gas velocity computation. To ameliorate this situation, we use data collected at a U.S. Coast Guard Station in Traverse City, Michigan, to demonstrate gets permeability estimation and pore‐gas velocity calculation for steady‐state, axisymmetric, two‐dimensional gas flow in a domain open to the atmosphere. For gas permeability estimation, we use random guesses constrained with decreasing intervals of radial and vertical permeabilityand analysis of root mean square errors to ensure attainment of a global versus local minimum. We demonstrate confidence in permeability estimation by providing plots of observed versus simulated pressure response. Finally, we illustrate how plots of pore‐gas velocity as a function of distance and flow rate can be helpful in venting design. 相似文献
125.
With costs of energy and materials increasing compared to other inputs in manufacturing, labour and capital can no longer be regarded as the only criteria for choice of appropriate technology. In the article below the authors offer a broader range of inputs and conclude that optimizing only labour and capital results in erroneous technology choices. 相似文献
126.
Nasreen Islam Khan David Bruce Ravi Naidu Gary Owens 《Environmental geochemistry and health》2009,31(Z1):221-238
Dietary intake of water and food has been identified as one of the major pathways for arsenic (As) exposure in the rural population
of Bangladesh. Therefore, realistic assessment and measurement of dietary intake patterns are important for the development
of an accurate estimate of As exposure and human health risk assessment. One important consideration is to identify an appropriate
tool for measuring dietary intake. In this study an interviewer-administered Food Frequency Questionnaire (FFQ) was implemented
to determine age and gender specific dietary intake. The developed FFQ was unique because it developed a synergy between field
dietary assessment and As concentration measurements in various environmental media. The resulting integrated database provided
an accurate framework for the process of As exposure and human health risk assessment. The preliminary results reported here
from the FFQ demonstrated that this technique could be used in rural areas as a tool to assess As exposure and the associated
human health risk. 相似文献
127.
Ajay Kumar Sabyasachi Rout R. K. Singhal P. M. Ravi R. M. Tripathi 《Journal of Coastal Conservation》2016,20(4):289-297
Bio-diffusion mixing rates (Db) were estimated from depth profiles of excess 210Pb and 137Cs in three sediment cores collected from Mumbai Harbour Bay (MHB) using a steady state vertical advection - diffusion model. The mean of 210Pb and 137Cs derived Db values along the studied area were obtained to be about 23 and 36 cm2y?1 respectively. These derived values were within the range of literature values reported for other equivalent environment internationally. The relatively higher Db values for 137Cs profiles demonstrated that particles have diffused more intensely within the surface layer of sediments over 1 year. Conversely, low Db values for 210Pb indicate slow mixing rates in the sediment profile which might be resulted from low 210Pb flux and diffusion of 222Rn to the seafloor. The significant differences between 210Pb and 137Cs derived Db values among cores indicate that there appeared to be as regional differences in sediment properties and local variability in the intensity of seafloor mixing. Furthermore, Db values also depend on differences in characteristic time and depth scales of radionuclides in cores, benthic fauna abundances, organic carbon flux to the sediments and primary production in overlying surface waters. Comparison of 210Pb derived Db values with those calculated from 137Cs distributions reveals better agreement for core 2 than core 1 and 3. The agreement may be fortuitous because 137Cs appears significantly deeper than 210Pb in all cores. It was also observed that Db values increases as sediment accumulation rate increases for both radionuclide. 相似文献
128.
为探究湛江近海域海洋沉积物中类二噁英多氯联苯(dioxin-like polychlorinated biphenyls,Dl PCBs)的生物学毒性效应,选取湛江近海域2个地点(近工业区TS和近生活区JSW)采集沉积物样品,制备近海域沉积物Dl PCBs提取物,将斑马鱼胚胎暴露于不同浓度的Dl PCBs提取物,测定斑马鱼胚胎7-乙氧基异吩恶唑脱乙基酶(ethoxyresorufin-O-deethylase,EROD)活性和cyp1a m RNA相对表达量。结果发现,JSW采样点Dl PCBs提取物染毒组EROD酶活性变化与TS采样点Dl PCBs提取物一致,在各染毒浓度下,斑马鱼仔鱼EROD酶活性为对照组的1.1~1.8倍。TS和JSW采样点不同浓度Dl PCBs提取物暴露斑马鱼胚胎96 h后,使斑马鱼仔鱼cyp1a m RNA相对表达量是对照组的3.36~19.45倍。说明一定浓度的近海沉积物Dl PCBs能诱导斑马鱼仔鱼EROD酶活性和cyp1a m RNA表达量升高,且呈现浓度-效应关系。 相似文献
129.
The present study was undertaken to evaluate biochemical markers of chronic carbofuran exposure to rats in terms of lipid peroxide and intrasynaptosomal calcium levels and to correlate them with the histopathological changes in brain regions. A significant increase in lipid peroxidation (LPO) in terms of thiobarbituric acid reactive substances (TBARS) was observed in the cerebral cortex (65%) and brain stem (33%) after carbofuran exposure. This was accompanied by a significant increase (87%) in the intracellular free-Ca2+ [Ca2+]i levels. N-acetylcysteine (NAC) administration, on the other hand, reversed the carbofuran-induced increase in LPO and [Ca2+]i. Histopathological studies of carbofuran-exposed brain revealed high frequency of pyknotic neurons in the cerebral cortex and microhaemorrhages in the brain stem. NAC supplementation to carbofuran-treated animals resulted in normalisation of the brain architecture as seen by a reduction in the number of pyknotic nuclei in the cerebral cortex. These findings indicate that increased LPO and elevated [Ca2+]i levels are involved in the development of carbofuran neurotoxicity and are eventually responsible for the pathological alterations. The study also demonstrates potential neuroprotective effect of NAC treatment in carbofuran neurotoxicity. 相似文献
130.
Ravi Babu Kalahasthi Rajmohan Hirehal Raghavendra Rao Rajan Bagalur Krishna Murthy M. Karuna Kumar 《毒物与环境化学》2013,95(2):393-400
The objective of this study was to determine the effect of nickel (Ni) exposure on serum amylase activity in nickel-plating workers in Bangalore (India). Sixty-nine subjects using Ni during the electroplating process formed the exposed group. An equal number of age- and sex-matched subjects working in the administration section formed the control group. Urine Ni levels were determined using a flameless atomic absorption spectrophotometer. Serum amylase activity was determined using spectrophotometric method with 2-chloro-4-nitrophenyl-α-D-maltotrioside as substrate. A significant increase in urine Ni and serum amylase activity was noted in nickel platers as compared with the control group. The level of serum amylase activity was positively and significantly associated with Ni content in urine of nickel platers. Stepwise multiple regression analysis was used to assess the effects of Ni exposure, life style confounding factors and presence of gastrointestinal problems on serum amylase activity. The analysis showed that the subjects who had urine Ni levels beyond 10?µg?g?1 of creatinine, nickel platers category, smoking and body mass index variables were significantly associated with serum amylase activity. The results of this study suggest that the increased serum amylase activity observed in nickel-exposed subjects could be used as a biomarker for investigating pancreatic function in Ni exposure. 相似文献