Synthesis, Characterization, and Hydrolytic Degradation of Copolymers of 2-Methylene-1,3-dioxepane with Ethylene and with Styrene

2-Methylene-1,3-dioxepane (MDP) was copolymerized with ethylene (E) at a pressure of approximately 1000 psi and a temperature of approximately 70°C with AIBN as the free radical initiator. The copolymers obtained, poly(MDP-co-E), were characterized by elemental analysis, IR, ¹H-NMR and ¹³C-NMR spectroscopy, DSC, and GPC. The copolymers contained 2–15 mol% ester units. MDP was also copolymerized with styrene (S) at 120°C with di-t-butyl peroxide as the initiator to prepare the copolymer, poly(MDP-co-S). The number-average molecular weights of both types of copolymers were in the range of 6000 to 11,000, and the weight-average molecular weights were in the range of 9000 to 17,000. The melting temperatures of poly(MDP-co-E) decreased with increasing ester unit content in the copolymer. For the MDP-S copolymers, the glass transition temperatures decreased with increasing ester unit content. Both poly(MDP-co-E) and poly(MDP-co-S) were degraded by methanolysis, and their molecular weights decreased by the expected amounts based on the ester unit content.     

Bird Use of Restoration and Reference Marshes Within the Barn Island Wildlife Management Area, Stonington, Connecticut, USA

/ Tidal marshes have been actively restored in Connecticut for nearly 20 years, but evaluations of these projects are typically based solely on observations of vegetation change. A formerly impounded valley marsh at the Barn Island Wildlife Management Area is a notable exception; previous research at this site has also included assessments of primary productivity, macroinvertebrates, and use by fishes. To determine the effects of marsh restoration on higher trophic levels, we monitored bird use at five sites within the Barn Island complex, including both restoration and reference marshes. Use by summer bird populations within fixed plots was monitored over two years at all sites. Our principal focus was Impoundment One, a previously impounded valley marsh reopened to full tidal exchange in 1982. This restoration site supported a greater abundance of wetland birds than our other sites, indicating that it is at least equivalent to reference marshes within the same system for this ecological function. Moreover, the species richness of birds and their frequency of occurrence at Impoundment One was greater than at 11 other estuarine marshes in southeastern Connecticut surveyed in a related investigation. A second marsh, under restoration for approximately ten years, appears to be developing in a similar fashion. These results complement previous studies on vegetation, macroinvertebrates, and fish use in this system to show that, over time, the reintroduction of tidal flooding can effectively restore important ecological functions to previously impounded tidal marshes.KEY WORDS: Estuarine; Tidal marsh; Wetland birds; Restoration     

Citizen Advisory Groups in Remedial Action Planning: Paper Tiger or Key to Success?

In accordance with the Great Lakes Water Quality agreement and the Great Lakes Critical Protections Act, the Great Lakes States have developed (or are developing) remedial action plans (RAPs) for severely degraded areas of concern (AOCs). To provide citizen input into the planning process, state environmental agencies have established citizens' advisory groups (CAGs) for each AOC. These CAGs have been hailed as the key to RAP success, yet little is known about their role in the planning process. In this paper, we examine the constitution, organization and activities of CAGs in three Lake Michigan AOCs by comparing CAGs to municipal planning commissions, citizen advisory commissions and councils of government. We find that CAGs, like other advisory bodies, can provide public input into the planning process, foster communication between government agencies and special interest groups, and facilitate intergovernmental co-ordination. Also like other advisory bodies, however, CAGs can fail to represent all constituencies in the AOCs, have limited influence on agencies plans and activities, and lack the authority to assure the co-operation of local governments.     

Integrating planning and sustainability theory for local benefit

The premise of this article is that prevailing planning theory has emerged primarily from a Newtonian (modernist) social context and is not well integrated conceptually with current developments in sustainability theory as represented by its various contributory disciplines. Approaches in the biophysical sciences, for example, are increasingly based on nonlinear, complexly interrelated conceptions of revolutionary development, whereas planning approaches are typically more compartmentalised, mechanistic and linear in character. To construct more workable linkages for local community/environmental planning, revolutionary theory is employed in this article to deal with the epistemological and methodological differences indicated. The proposed synthesis combines mutually reinforcing conceptions of epistemology, cultural pluralism, community and progress. Implications for practice of local planning are drawn with reference to the long-term goal of socioenvironmental sustainability, defined as a balance of economic, environmental and equity considerations.     

Antidepressant and antipsychotic agents

Numerous studies have been reviewed concerning the relationship of the catecholamines and indoleamines to depression and its treatment with antidepressant drugs. The profusion of data on the subject suggests the amines may be implicated in the disease, however no convincing hypothesis is available which unites the two. A similar situation seems to exist concerning the antipsychotic agents, dopamine and schizophrenia. The evidence appears to be overwhelming relating dopamine in the action of these agents and yet serious inconsistencies have been reported suggesting the need for a revision of the hypothesis regarding the mode of action of antipsychotic agents.     

Congenital myotonic dystrophy: An often unsuspected cause of severe polyhydramnios

Two cases of severe polyhydramnios are presented in which the unsuspected diagnosis of myotonic dystrophy was made in the patient and the fetus.     

A screening study of the treatability of dioxins and furans in bleach plant filtrates and mill wastewaters

Findings are presented of a study to provide the pulp and paper industry with basic data regarding the feasibility for treatment of bleach plant filtrates or combined treated mill effluents for 2,3,7,8-TCDD and 2,3,7,8-TCDF reduction.