Vehicle Occupant Exposure to Carbon Monoxide

Abstract

This paper focuses on the auto commuting micro-environment and presents typical carbon monoxide (CO) concentrations to which auto commuters in central Riyadh, Saudi Arabia were exposed. Two test vehicles traveling over four main arterial roadways were monitored for inside and outside CO levels during eighty peak and off-peak hours extending over an eight month period. The relative importance of several variables which explained the variability in CO concentrations inside autos was also assessed. It was found that during peak hours auto commuters were exposed to mean CO levels that ranged from 30 to 40 ppm over trips that typically took between 25 to 40 minutes. The mean ratio of inside to outside CO levels was 0.84. Results of variance component analyses indicated that the most important variables affecting CO concentrations inside autos were, in addition to the smoking of vehicle occupants, traffic volume, vehicle speed, period of day and wind velocity. An increase in traffic volume from 1,000 to 5,000 vehicles per hour (vph) increased mean CO level exposure by 71 percent. An increase in vehicle speed from 14 to 55 km/h reduced mean CO exposure by 36 percent. The number of traffic interruptions had a moderate effect on mean concentrations of CO inside vehicles.     

Preparation and Characterization of Polyaniline and Ag/ Polyaniline Composite Nanoporous Particles and Their Antimicrobial Activities

Polyaniline (PANI) and Ag/PANI nanoporous composite were prepared by an oxidative polymerization method. The oxidation process of PANI nanoparticles was occurred using (NH₄)₂S₂O₈ while the oxidation process of Ag/PANI nanoporous composite was occurred using AgNO₃ under the effect of artificial radiation. The structural, morphological, and optical properties of the PANI and Ag/PANI nanoporous structures were studied using different characterization tools. The results confirm the formation of polycrystalline nanoporous PANI and spherical nanoporous composite of Ag/PANI particles. Antibacterial activity tests against gram-positive bacteria, Bacillus subtilis and Staphylococcus aureus, and gram-negative bacteria, Escherichia coli, and Salmonella species were carried out using different concentrations of PANI nanoparticles and Ag/PANI nanoporous composites. PANI has not antibacterial effect against all studied pathogens. In contrast, Ag/PANI nanoporous composites possessed antibacterial activity that is identified by the zone of inhibition. The inhibition zones of bacteria are in order; Salmonella species?>?S. aureus?>?B. subtilis?>?E. coli. The inhibition zones of all bacteria increased with increasing concentrations of Ag/PANI nanoporous composites from 200 to 400 ppm then decreased with further increasing of the dose concentrations to 600 ppm. Finally, a simplified mechanism based on the electrostatic attraction is presented to describe the antimicrobial activity of Ag/PANI nanoporous composite.     

ESTIMATING WATER BUDGET IN A REGIONAL AQUIFER USING HSPF‐MODFLOW INTEGRATED MODEL1

ABSTRACT: Integrated water resources management is important, especially in watersheds where substantial interactions exist between the ground and surface water sources. This management warrants the need for reliable estimates of both an overall basin water budget and hydrologic fluctuations between ground water and surface water sources. The objectives of this study were to estimate the total water budget and to simulate the effects of the management of water in the Big Lost River Basin in Idaho. The study used the FIPR Hydrological Model (FHM), a hydrological model developed by the University of South Florida for the Florida Institute of Phosphate Research (FIPR). The FHM is an integrated model that simulates the full water budget of the surface and ground water systems. It has two public domain components: Hydrological Simulation Program ‐ FORTRAN (HSPF) and Modular Three‐Dimensional Finite‐Difference Ground Water Flow Model (MODFLOW). This study quantified the hydrologic fluxes between ground water and surface water and determined a comprehensive and accurate water budget for the Big Lost River. The study showed an annual amount of 10.44 m3/sec leaves the basin and never to return to the system. The study is useful in developing and calculating the annual water budget in the Big Lost River, and this process should be applicable to estimating water budgets in other basins.     

EVAPOTRANSPIRATION CONCEPTUALIZATION IN THE HSPF‐MODFLOW INTEGRATED MODELS1

In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.     

Simulation of Surface Water for Un‐Gauged Areas with Storage‐Attenuation Wetlands1

Abstract: A nontraditional application of the Hydrological Simulation Program – FORTRAN (HSPF) model to simulate freshwater discharge to upper Charlotte Harbor along Florida’s west coast was performed. This application was different from traditional HSPF applications in three ways. First, the domain of the model was defined based on the hydraulic characteristics of the landforms using small distributed parameter discretization. Second, broad wetland land forms, representing more than 20% of this area, were simulated as reaches with storage‐attenuation characteristics and not as pervious land segments (PERLNDs). Finally, the reach flow‐tables (F‐Tables) were configured in a unique way to be calibrated representing the uncertainty of the storage‐attenuation process. Characterizing wetlands as hydrography elements allows flow from the wetlands to be treated as a stage‐dependent flux. The study was conducted for the un‐gauged portion of the Peace and Myakka rivers in west‐central Florida. Due to low gradient tidal influences, a large portion of the basin is un‐gauged. The objective of this study was to simulate stream flow discharges and to estimate freshwater inflow from these un‐gauged areas to upper Charlotte Harbor. Two local gauging stations were located within the model domain and were used for calibration. Another gauge with a shorter period of record was used for verification. A set of global hydrologic parameters were selected and tested using the parameter optimization software (PEST) during the calibration. Model results were evaluated using PEST and well‐known statistical indices. The correlation coefficients were very high (0.899 and 0.825) for the two calibration stations. Further testing of this approach appears warranted for watersheds with significant wetlands coverage.     

Spatial distribution of drinking and irrigation water quality indices of Ghizer River Basin,northern Pakistan

Environmental Science and Pollution Research - Determining the water contamination of a river that threatens the dependent ecological community is a pillar for sustainable management. For this...     

Ruthana date extract inhibited proliferation of human hepatocellular carcinoma (HepG2) cells by modulation of BAX gene

Environmental Science and Pollution Research - Cancer response to chemotherapeutic agents and its side effects remain a challenge for the development of new anticancer compounds. Dates are consumed...     

Inquiries into Malaysia's socio-technical disasters: recommendations and lessons learnt

Most democratic countries hold inquiries into disasters. One of their key functions is to establish the cause of an event and to learn lessons in order to prevent a recurrence. In addition, they offer an opportunity for communal catharsis, permitting the public to vent anger, distress and frustration and to exert pressure for policy changes. Malaysia has experienced six landmark socio-technical disasters since 1968, which resulted in the proposal or amendment of various safety/emergency acts and regulations. The authors used a grounded theory approach utilising a constant comparative method to analyse the recommendations made by the inquiries into these events. Data indicate that social and technical recommendations comprise 85 and 15 per cent, respectively, of the total recommendations made by the inquiry committees. This paper offers suggestions for improving the management of inquiry tribunals, as they will remain a valuable source of information for society and corporations to learn from past incidents.     

Microbial community responses to bioremediation treatments for the mitigation of low-dose anthracene in marine coastal sediments of Bizerte lagoon (Tunisia)

Purpose

The main goals of this study were to investigate (1) the behavior of microbial communities in response to low-dose bioavailable anthracene addition in lightly contaminated sediment from Bizerte Lagoon and (2) the effects of bioremediation treatments on microbial biomass, activity, and community structure.

Methods

Sediment microcosms amended with 1 ppm anthracene were incubated in triplicate during 30 days. Biostimulation (addition of nitrogen and phosphorus fertilizer) and bioaugmentation (inoculation of a hydrocarbonoclastic bacterium) were used as bioremediation treatments. Bacterial biomass was estimated using flow cytometry. Sediment oxygen consumption was measured with oxygen microelectrodes. Bacterial community structure was assessed by molecular fingerprints (terminal restriction fragment length polymorphism; T-RFLP) analysis.

Results

Anthracene contamination resulted in a significant reduction of bacterial abundance with an impact on cell integrity. Concomitantly, sediment oxygen consumption was strongly inhibited. Correspondence analysis on T-RFLP data indicated that bacterial community structures from anthracene-contaminated microcosms were different from that of the control. Interestingly, the changes observed in microbial biomass, structure, and activities as a result of anthracene contamination were not alleviated even with the use of biostimulation and combination of biostimulation and bioaugmentation strategy for anthracene bioremediation. Nevertheless, both treatment methods resulted in different community structures relative to the contaminated and control microcosms with the appearance of distinct populations.

Conclusion

Anthracene spiking severely affected microbial communities, suggesting dominance of nontolerant populations in this lightly-contaminated sediment. Although biostimulation and/or bioaugmentation treatments did not alleviate the anthracene toxic effects, the changes observed in microbial population and structure suggest that the proposed treatments might be promising to promote bacterial growth. Further works are still required to propose a more efficient strategy to stimulate biodegradation that takes into account the complex interactions between species for resource access.