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511.
Juan Peris-Vicente Ana Marzo-Mas Pasqual Roca-Genovés Samuel Carda-Broch Josep Esteve-Romero 《环境科学学报(英文版)》2016,28(4):284-292
A method based on micellar liquid chromatography has been developed to simultaneously monitor four pesticides largely post-harvest applied to citrus:thiabendazole,pyrimethanil,o-phenylphenol and imazalil.Water samples were filtered and directly injected without other treatment,thus avoiding extraction steps.The composition of the mobile phase was optimized using a chemometrical approach to achieve and excellent resolution to 0.07 mol/L SDS/5%,V/V 1-pentanol buffered at p H 3.Mobile phase run through a C18 column at 1 m L/min at room temperature.The detection was performing by UV–Visible absorbance using a wavelength program:0–10 min,305 nm(for thiabendazole);10–12;265 nm(for pyrimethanil)and 12–18,220 nm(o-phenylphenol and imazalil).The developed method was validated following the guidelines of the US Environmental Protection Agency in terms of:quantitation range,(0.5–4 to 15μg/m L),linearity(r20.9995),sensitivity(LOD,0.18–1.4μg/m L),precision(9.2%),trueness(93.9%–103.7%),and ruggedness(9.9%).It was found that the fungicides remain up to eight days in surface water at outdoor conditions.The method was used to screen the presence of the analytes in several waste water samples,and was proved to be useful in routine analysis. 相似文献
512.
Ho Long Jerves-Cobo Ruben Barthel Matti Six Johan Bode Samuel Boeckx Pascal Goethals Peter 《Environmental science and pollution research international》2022,29(25):37277-37290
Environmental Science and Pollution Research - Rivers act as a natural source of greenhouse gases (GHGs). However, anthropogenic activities can largely alter the chemical composition and microbial... 相似文献
513.
Pereira Beatriz Salustiano de Freitas Caroline Vieira Rogerio Martins Brienzo Michel 《Journal of Material Cycles and Waste Management》2022,24(6):2126-2140
Journal of Material Cycles and Waste Management - Fruit production worldwide is over 675 million tons per year. Brazil is responsible for the production of 43.6 million tons of fruits per year,... 相似文献
514.
Nicolas P. Zegre Andrew J. Miller Aaron Maxwell Samuel J. Lamont 《Journal of the American Water Resources Association》2014,50(5):1257-1272
In the Appalachian region of the eastern United States, mountaintop removal mining (MTM) is a dominant driver of land‐cover change, impacting 6.8% of the largely forested 4.86 million ha coal fields region. Recent catastrophic flooding and documented biological impairment downstream of MTM has drawn sharp criticism to this practice. Despite its extent, scale, and use since the 1970s, the impact of MTM on hydrology is poorly understood. Therefore, the goal of this study was a multiscale evaluation to establish the nature of hydrologic impacts associated with MTM. To quantify the extent of MTM, land‐cover change over the lifetime of this practice is estimated for a mesoscale watershed in southern West Virginia. To assess hydrologic impacts, we conducted long‐term trend analyses to evaluate for systematic changes in hydrology at the mesoscale, and conducted hydrometric and response time modeling to characterize storm‐scale responses of a MTM‐impacted headwater catchment. Results show a general trend in the conversion of forests to mines, and significant decreases in maximum streamflow and variability, and increases in base‐flow ratio attributed to valley fills and deep mine drainage. Decreases in variability are shown across spatial and temporal scales having important implications for water quantity and quality. However, considerable research is necessary to understand how MTM impacts hydrology. In an effort to inform future research, we identify existing knowledge gaps and limitations of our study. 相似文献
515.
Gómez-Ariza JL Santos MM Morales E Giráldez I Sánchez-Rodas D Vieira N Kemp JF Boon JP Ten-Hallers-Tjabbes CC 《Chemosphere》2006,64(7):1100-1108
Imposex in female snails, a bioindicator of TBT contamination, and the presence of organotins in snails' tissue and sediments were studied at nine sites off the western Iberian Peninsula. The study was part of a European project (acronym HIC-TBT) co-financed by the EU-LIFE programme, intending to investigate and communicate the impact of organotins from ships in marine ecosystems. Snails and sediments were sampled during two cruises in May/June 1999 and in January 2000 in areas of high, intermediate and low-shipping density. Imposex was found in female snails from several sampling sites, some of which had an imposex incidence of 100%. Differences in sensitivity were found between species; hence comparison of imposex levels between locations where different species were collected was not straightforward. Total organotin concentrations in sediments (sum of butyl and phenyltin compounds) ranged from 21 to 185 ng Sn g(-1) with higher values for most sites sampled in the vicinity of shipping lanes. Organotin concentration in snails' tissue ranged from <5 to 196 ng Sn g(-1), which are similar to those found in snails from other offshore areas contaminated by TBT. Overall, these results give further support to the recent ban on the use of organotin based antifouling paints to all ship size. 相似文献
516.
Complexation of the antibiotic tetracycline with humic acid 总被引:10,自引:0,他引:10
The effect of solution chemistry and sorbate-to-sorbent ratio on the interaction of the antibiotic tetracycline with Elliott soil humic acid (ESHA) was investigated using equilibrium dialysis and FITEQL modeling. Tetracycline speciation strongly influenced its sorption to ESHA. Sorption was strongly pH-dependent with a maximum around pH 4.3, and competition with H+ and electrolyte cation (Na+) was evident. The pH-dependent trend was consistent with complexation between the cationic/zwitterionic tetracycline species and deprotonated sites in ESHA (mainly carboxylic functional groups). Modification of ESHA by Ca2+ addition increased tetracycline sorption suggesting that ternary complex formation (ESHA-metal-tetracycline) may be important at higher concentrations of multivalent metal cations. The macroscopic data (pH-envelope and sorption isotherms) were successfully modeled using a discrete logK function with the FITEQL 4.0 chemical equilibrium program indicating that ESHA-tetracycline interaction could be reasonably represented as complex formation of a monoacid with discrete sites in humic acid. Sorption-desorption hysteresis was observed; both sorption and desorption isotherms were well described by the Freundlich equation. 相似文献
517.
Solid phase speciation of arsenic by sequential extraction in standard reference materials and industrially contaminated soil samples 总被引:14,自引:0,他引:14
Van Herreweghe S Swennen R Vandecasteele C Cappuyns V 《Environmental pollution (Barking, Essex : 1987)》2003,122(3):323-342
Availability, mobility, (phyto)toxicity and potential risk of contaminants is strongly affected by the manner of appearance of elements, the so-called speciation. Operational fractionation methods like sequential extractions have been applied for a long time to determine the solid phase speciation of heavy metals since direct determination of specific chemical compounds can not always be easily achieved. The three-step sequential extraction scheme recommended by the BCR and two extraction schemes based on the phosphorus-like protocol proposed by Manful (1992, Occurrence and Ecochemical Behaviours of Arsenic in a Goldsmelter Impacted Area in Ghana, PhD dissertation, at the RUG) were applied to four standard reference materials (SRM) and to a batch of samples from industrially contaminated sites, heavily contaminated with arsenic and heavy metals. The SRM 2710 (Montana soil) was found to be the most useful reference material for metal (Mn, Cu, Zn, As, Cd and Pb) fractionation using the BCR sequential extraction procedure. Two sequential extraction schemes were developed and compared for arsenic with the aim to establish a better fractionation and recovery rate than the BCR-scheme for this element in the SRM samples. The major part of arsenic was released from the heavily contaminated samples after NaOH-extraction. Inferior extraction variability and recovery in the heavily contaminated samples compared to SRMs could be mainly contributed to subsample heterogeneity. 相似文献
518.
Yiridomoh Gordon Yenglier Bonye Samuel Ziem Derbile Emmanuel Kanchebe Owusu Victor 《Environment, Development and Sustainability》2022,24(1):810-831
Environment, Development and Sustainability - Climate extremes over the years have been a major concern for the globalized world. The hardest hit from these climate extremes are women farmers with... 相似文献
519.
Zhang Zichen Omine Kiyoshi Flemmy Samuel Oye 《Journal of Material Cycles and Waste Management》2022,24(6):2291-2302
Journal of Material Cycles and Waste Management - Soft clays with high water content are normally treated by cement or cement-based solidifying agent for utilization as geomaterial in the... 相似文献
520.
Flemmy Samuel O. Omine Kiyoshi Zhang Zichen 《Journal of Material Cycles and Waste Management》2022,24(4):1355-1367
Journal of Material Cycles and Waste Management - The utilization of drinking water sludge (DWS) as geomaterial is important to reduce its volume that needs to be disposed of and to increase... 相似文献