Coupled modeling of cement/claystone interactions and radionuclide migration

The interactions between cement and a clayey host-rock of an underground repository for intermediate-level radioactive waste are studied with the reactive transport code HYTEC for supporting performance assessment. Care is taken in using relevant time scales (100,000 years) and dimensions. Based on a literature review, three hypotheses are considered with respect to the mineralogical composition of the claystone and the neo-formed phases. In the long term, the pH is buffered for all hypotheses and important mineral transformations occur both in cement and the host-rock. The destruction of the primary minerals is localized close to the cement/claystone interface and is characterized by the precipitation of secondary phases with retention properties (illite, zeolite). However, beyond the zone of intense mineral transformations, the pore water chemistry is also disturbed over a dozen meters due to an attenuated but continuous flux of hydroxyl, potassium and calcium ions. Four interdependent mechanisms control the profile in the whole system: diffusion of the alkaline plume, mineralogical buffering, ion exchange and clogging of the pore space at the cement/claystone interface. The migration of a selected group of radionuclides (Cs, Ra, Tc and U) is explicitly integrated in the simulations of the strongly coupled system. Theoretical profiles of distribution coefficient (Kd) and solubility limit values are derived from the simulations, and their sensitivity with respect to the system evolution is estimated.     

Microbial biomass in a soil amended with different types of organic wastes.

Application of different types of organic wastes may have a marked effect on soil microbial biomass and its activity. The objective of this study was to quantify the amount of microbial biomass in a loamy-clayey soil, amended with different types of organic waste residues (composts of municipal solid waste of different ages, sewage sludge and farmyard manure) and incubated for 8 weeks at 25 degrees C and two-thirds of field capacity, using the fumigation-extraction method. Both microbial biomass-C and -N (BC and BN, respectively) appeared to be dependent on the type of organic waste residues, on their degree of stability, and on their chemical characteristics. In general, organic wastes increased the microbial biomass-C content in the soil and the microbial BC was positively correlated with the organic C content, the C/N, neutral detergent fibre/N (NDF/N) and acid detergent fibre/N (ADF/ N) ratios. The microbial biomass content decreased according to the period of incubation, especially when the compost used was immature. The microbial biomass-N was positively correlated with the total N and percentage of hemicellulose. The microbial biomass-C was linearly related with the microbial biomass-N and the ratio BC/BN was exponentially related with the BC.     

Role of active floodplains for nutrient retention in the river Rhine

We evaluated the importance of floodplains for nutrient retention in two distributaries of the river Rhine (Waal and IJssel) by monitoring N and P retention in a body of water during downstream transport. We hypothesized that (i) retention of P is much larger than retention of N and (ii) nutrient retention increases with an increasing amount of the discharge flowing through floodplains (QF). The second hypothesis was tested by comparing retention between the rivers Waal (low QF) and IJssel (high QF), as well as at different discharges. Total nitrogen (TN) did not decrease significantly during downstream transport in both rivers, whereas 20 to 45% of total phosphorus (TP) disappeared during transport in the river IJssel. This difference between N and P retention-supporting the first hypothesis-was probably caused by differences in sedimentation through a much lower proportion of N adsorbed to particles than of P (2-3% of N vs. 50-70% of P). Phosphorus retention was only observed in the IJssel and not in the Waal, and absolute P retention (g P s(-1) km(-1)) in the IJssel increased with increasing QF. The second hypothesis was, nevertheless, not fully supported, because the percentage P retention (% of P load) decreased (instead of increased) with increasing QF. The percentage P retention increased with decreasing river depth and flow velocity; it seemed related to the efficiency of sediment trapping.     

Laboratory-scale measurement of trace gas fluxes from landfarm soils

Trace gas emissions from refinery and bioremediation landfarms were investigated in a mesocosm-scale simulator facility. Five simulators were constructed and integrated with a data acquisition system and trace gas analyzers, allowing automated real-time sampling and calculation of total hydrocarbon (THC), CO2, and water vapor fluxes. Experiments evaluating the influence of simulated cultivation and rainfall on trace gas fluxes from the soil surfaces were conducted. Results were compared with published field results. Results showed that cultivating dry or moderately wet soil resulted in brief enhancements of THC fluxes, up to a factor of 10, followed by a sharp decline. Cultivating dry soil did not enhance respiration. Cultivating wet soil did result in sustained elevated levels of respiration. Total hydrocarbon emissions were also briefly enhanced in wet soils, but to a lesser magnitude than in dry soil. Hydrocarbon fluxes from refinery landfarm soil were very low for the duration of the experiments. This lead to the conclusion that elevated THC fluxes would only be expected during waste application. An evaluation of the influence of simultaneous water vapor fluxes on other trace gas fluxes highlighted the importance in lab-scale experiments of correcting trace gas fluxes from soils. The results from this research can be used to guide management practices at landfarms and to provide data to aid in assessing the effect of landfarms.     

Cancer cluster among police detachment personnel

An apparent cancer cluster at a police detachment in a coastal British Columbia community was investigated. Police personnel suspected that the detachment building may have been a factor. Police personnel (20 current and 154 previous employees) associated with the detachment since 1963, the date of occupancy, were traced. After all 174 cases were contacted directly, or next of kin in case of death, a total of 16 cases of cancer or suspected cancers were reported. Of these 16, eight cases of cancer were confirmed through a cancer registry. Cancers included testicular, cervical, colon, skin (including melanoma), leukemias and lymphomas with an age range of diagnosis between 22 and 44 years. There was no evidence for an underlying event, factor or condition in the police building that could be attributed to the observed cancer cases. A possible association between these cancers and the use of police traffic radar is discussed.     

Employee reactivity and adaptation to observation on the job

In the course of studying police dispatchers, five observers recorded the reactions of the employees (N = 37) to their presence throughout the work shift on three separate occasions. Four major research questions were considered: (a) extent of reaction, (b) relationship between interactions with the observer and changes in employees' work activities, (c) independence of verbal and nonverbal behavioral reactions, and (d) adaptation. On average, subjects or other employees initiated 10 interactions per hour with observers. These interactions were classified as subject-initiated (a) verbal, content related to research procedures; (b) verbal, non-research-related in content; (c) nonverbal only or (d) other employee-initiated verbal comment. Interaction with the observer was not related to the amount of work the subject did. Subjects' nonverbal and verbal responses were unrelated to each other as well as to the verbal responses of other employees. A priori expectations concerning adaptation to observation were tested with a 3 × 3 (segment by day) repeated-measures factorial design. Significant adaptation (P < 0·01) occurred within and between days in subjects' comments about research procedures and all comments from other employees. However, other behaviors showed with no evidence of adaptation or actual increases. The implications of these findings for measuring reactivity and deciding when adaptation has occurred are discussed.     

Community Exchange and Training in the Suid Bokkeveld: A UNCCD Pilot Project to Enhance Livelihoods and Natural Resource Management

Community knowledge exchanges have played a key role in developmental processes in the Suid Bokkeveld community of South Africa. Two exchange visits were undertaken with the support of the Department of Agriculture and an NGO, the Environmental Monitoring Group, which have led to local economic development and enhanced capacity to manage natural resources in a sustainable manner. These pilot projects were undertaken within the framework of the Community Exchange and Training Programme of the Global Mechanism of the United Nations Convention to Combat Desertification (UNCCD). The methodology applied included facilitation to develop a community-based vision for development, in terms of which the community exchange process was designed. A Facilitation Team of service providers conducted preparatory workshops, and identified potential partner communities. Two exchange visits were carried out, one focused on Rooibos production and marketing, and the other on community-based eco-tourism. Following report-back and planning workshops, emerging community-driven initiatives were supported through their formative stages. The initiatives have not only resulted in enhanced livelihoods, but the methodology has also been applied widely in a number of different contexts.     

Environmental Monitoring in The Netherlands: Past Developments and Future Challenges

During the past three decades environmental monitoringsystems covering an immense variety of environmentalproblems emerged rapidly throughout the world. In The Netherlands the entire spectrum of monitoring systemsis present. Their development is especially interesting because of the Dutch complex environmental landscape: a result of the combination of a natural setting with a high small-scale variation and an intense use of the available space by both industry and agriculture. This necessitates a well balanced environmental policy wherein monitoring ofboth environmental compartments and environmental policy itself plays an important role. In this article we focus on abiotic systems, whereby the development of monitoring will be related to that of environmental policy in general. Some general lines emerge: from quantity towards quality, from single pollutants towards environmentally harmful processes as a whole, and from a focus on human health and safety towards integrated environmental management. Because The Netherlands is a highly organized and highly educatedsociety, reacting fast and flexible to new problems, this progression has happened quickly. However, still much remains to be desired and flexibility not necessarily guarantees optimal routes of development. Paramount is the development of sophisticated and robust monitoring systems that truly support integrated environmental management. This asks forclear objectives based on solid scientific insights.     

Spatial Extent Of Degraded Sediment Quality In Puget Sound (Washington State, U.S.A.) Based Upon Measures Of The Sediment Quality Triad

A survey was designed and conducted to determine the severity, spatial patterns, and spatial extent of degraded sediment quality in Puget Sound (Washington State, USA). A weight of evidence compiled from results of chemical analyses, toxicity tests, and benthic infaunal analyses was used to classify the quality of sediments. Sediment samples were collected from 300 locations within a 2363 km² area extending from the US/Canada border to the inlets of southern Puget Sound and Hood Canal. Degraded conditions, as indicated with a combination of high chemical concentrations, significant toxicity, and adversely altered benthos, occurred in samples that represented about 1% of the total area. These conditions invariably occurred in samples collected within urbanized bays and industrial waterways, especially near the urban centers of Everett, Seattle, Tacoma, and Bremerton. Sediments with high quality (as indicated by no toxicity, no contamination, and the presence of a relatively abundant and diverse infauna) occurred in samples that represented a majority (68%) of the total study area. Sediments in which results of the three kinds of analyses were not in agreement were classified as intermediate in quality and represented about 31% of the total area. Relative to many other estuaries and marine bays of the USA, Puget Sound sediments ranked among those with minimal evidence of toxicant-induced degradation.     

Uncertainty in integrated assessment: A social scientific perspective

In the context of integrated assessment, the authors address the issue of uncertainty and subjectivity in modelling. In relating bias to different perspectives, the authors introduce the methodology of multiple model routes, which are reflections of different perceptions of reality and various policy preferences. As heuristic they use three perspectives, which are distinguished in cultural theory. The article describes case-studies on the population and health controversy in order to illustrate the possibilities of their approach. The article concludes with discussing the lessons learned by applying this methodology.