Retrieval of heavy metal ions from solution via ferritisation

The paper summarises the results of the studies on retrieval of heavy metal ions in solution by ferritisation and its potential application in waste-water treatment. The optimum procedure for ferritisation of heavy metal ions in solution has been evolved with respect to pH, concentration of Fe2+, rate and time of aeration and temperature. The recommended procedure consists of controlled aeration of the solution containing heavy metal ions and ferrous ions at pH 9.5-10.5 at about 50 degrees C, until the black, granular, magnetic ferrite separates out. The metal ferrites can also be formed, even without heating or forced aeration, by ageing the mixed metal hydroxide precipitate at pH 10 to 11. The metal ferrites formed have been characterised by X-ray diffractometry. The laboratory-scope experiments conducted with synthetic heavy metal solutions as well as actual wastewater from a tanning industry showed that heavy metal ions can be effectively removed from solution to sub-ppm levels. The metal ferrites thus recovered may find commercial application as microwave absorbers, catalysts, metal scavengers, etc. This technique seems to have potential application in simultaneous, one step removal of different heavy metal ions from industrial wastewaters.     

Algal-bacterial interactions in metal contaminated floodplain sediments

The aim of the present study was to investigate algal-bacterial interactions in a gradient of metal contaminated natural sediments. By means of multivariate techniques, we related the genetic structure (denaturing gradient gel electrophoresis, DGGE) and the physiological structure (community-level physiological profiling, CLPP) of the bacterial communities to the species composition of the algal communities and to the abiotic environmental variables, including metal contamination. The results revealed that genetic and physiological structure of the bacterial communities correlated with the species composition of the algal community, but hardly to the level of metal pollution. This must be interpreted as an indication for a strong and species-specific linkage of algal and bacterial species in floodplain sediments. Metals were, however, not proven to affect either the algal or the bacterial communities of the Dutch river floodplains.     

The influence of radical architecture on cadmium bioaccumulation in the black mangrove, Avicennia germinans L

Two groups of Avicennia germinans plants with differences in the radical architecture were exposed under hydroponic conditions to 95ppm of cadmium (Cd) for a period of 24h. Later, Cd concentration in roots, stems and leaves was determined by graphite furnace atomic absorption spectrophotometry. Our results showed that, for both groups of plants, the roots accumulated higher concentration of Cd as compared to stems and leaves, though, the plants of group B displayed enhanced radical architecture, better growth performance, and lower Cd concentration as compared to plants of group A. In contrast, low values of leaves/roots Cd transportation index, and bioaccumulation factor were found in plants of group B. These results suggest that the higher radical architecture developed in plants of group B might better adjust the uptake of Cd as a result of an integrated network of multiple response processes for instances, production of organic acids, antioxidative replay, cell-wall lignification and/or suberization. Further studies will be focused in understanding the role of the radical system in mangrove plants with the rhizosphere activation and root adsorption to soil Cd under natural conditions.     

A new look at the psychological contract during organizational socialization: The role of newcomers' obligations at entry

Previous studies have demonstrated that the psychological contract is largely shaped during socialization. This study adopts a complementary perspective and analyzes how the psychological contract at the start of employment shapes the subsequent socialization process. Drawing upon social exchange theory, we propose that newcomers with a higher sense of their personal obligations at entry will perceive orientation training as more useful and develop better relationships with their supervisors and peers, which in turn will facilitate their work adjustment. Results of a longitudinal survey on a sample of 144 recruits from a European Army show that newcomers with a higher initial sense of their employee obligations toward their employer report higher perceived training utility, higher leader–member exchange (LMX) with their instructors, and higher team–member exchange (TMX) with their platoon peers. Moreover, perceived training utility and LMX predict the fulfillment of employers' obligations; and training utility predicts the level of newcomers' employee obligations. Finally, training utility, LMX, and TMX predict some of three indicators of newcomers' adjustment, namely, role clarity (training utility and LMX), group integration (TMX), and organizational values understanding (training utility). These results highlight how newcomers' obligations at the start of employment contribute to the social exchange dynamic underlying organizational socialization. Copyright © 2015 John Wiley & Sons, Ltd.     

Affirmative action programs: an organizational justice perspective

Affirmative Action Programs (AAPs) are becoming increasingly common in the workplace. Typically their effectiveness has been assessed by the number of women and minorities hired and promoted. A neglected, but important measure of effectiveness is how AAPs are perceived by employees. When employees perceive that AAPs violate notions of fairness, negative attitudes and behaviors may occur and lead to decreased organizational performance. A model of perceived AAP fairness is presented using an organizational justice perspective. An initial (partial) test of the model is conducted and avenues for future research are discussed.     

Work–family conflicts of women in the Air Force: their influence on mental health and functioning

This paper examined the effects of work and family stressors and conflicts on Air Force women's mental health and functioning. We analyzed data from a 1993 survey of representative stratified samples of 525 Air Force women from the active duty reserve and guard forces. The analyses of the data are guided by the comprehensive model of work–family conflict that has been tested by Frone, Russell, and Cooper (1992) using a large representative community sample. Structural equation modeling analyses provided support for the work–family conflict model. The analyses also provided support for an extension of the model, which included the separate effects of marital and parental roles on mental health. The extended model demonstrated that job and parental stresses had direct effects on work–family conflicts and that job and marital distress and family–work conflict had an independent adverse effect on mental health. Whereas job and parental involvement had a beneficial effect on distress, they had an adverse effect on work–family conflicts. Copyright © 1999 John Wiley & Sons, Ltd.     

Single-laboratory evaluation and modification of U.S. EPA methods 7470 and 7471 for the determination of mercury in aqueous and solid hazardous wastes

The current U.S. Environmental Protection Agency (U.S. EPA) protocols for mercury determinations in aqueous and solid waste samples (SW-846 Methods 7470 and 7471) using recirculating cold-vapor atomic absorption spectrometry (CV-AAS) have been evaluated. The U.S. EPA methods are not sufficiently flexible to permit special quality control (QC) measures, have limited detectability for low-level mercury concentrations, and are plagued by spectral interferences caused by the nonspecific absorption of primary mercury radiation by volatile organic vapors. The U.S. EPA protocols have been modified in a single-laboratory study to facilitate additional QC measures, to enhance detectability for low-level mercury concentrations, and to eliminate nonspecific vapor absorption interferences. Volumetric manipulations for additional QC measures, if required, are facilitated by performing the sample digestions in Erlenmeyer flasks rather than in the current Biochemical Oxygen Demand (BOD) reduction-aeration bottles. Typical manipulations for additional QC measures that are now feasible include dilution of concentrated samples and multiple aliquot sampling for post-digestion spike and replicate analyses. Instrument detectability is improved 10-fold by using a gas sparging bottle as a dedicated reduction-aeration vessel and a silver wool-amalgamation CV-AAS system operated in an open configuration. The on-line amalgamation/thermal desorption process of the modified CV-AAS system eliminates interfering water and organic matrix vapors prior to the mercury absorption measurement. Good accuracy and precision have been obtained with the amalgamation CV-AAS system for the analyses of four reference sediment materials. The amalgamation CV-AAS measurements on the reference sediment digests have been successfully performed at absolute mercury concentration levels that are only 1 to 4 times above the instrumental detection limit of the U.S. EPA recirculating CV-AAS method.     

Soil and soil water studies at the HUMEX site

Changes to natural organic compounds by acid deposition and subsequent effects on Al mobilization are not well understood. The HUMEX catchment-scale acidification experiment in western Norway offers a unique possibility for an integrated assessment of these interactions. In this report, the soil and soil water chemical data from the HUMEX site, from before and after the onset of experimental acidification, are used to characterize the catchment. Changes in soil water chemistry are discussed and controls on dissolved organic carbon are addressed in relation to Al mobilization. Decreases in the concentration of dissolved organic carbon (DOC) and organic Al fractions were found in soil water after the treatment started. These changes were related to an increase in soil water sulphate concentrations. The sulphate levels showed a significant increase (on a 95% level) in four of ten soil horizons while nitrate remained nearly unchanged. In organic soils, where the dissolved organic carbon content was high, the major control for monomeric aluminum concentration appeared to be the amount of exchangeable aluminum in the soil. In mineral soils, the gibbsite dissolution may govern inorganic Al concentrations in soil water, though substantial undersaturation was found when DOC was high.     

Demonstration of a high field electrostatically enhanced venturi scrubber on a magnesium furnace fume emission

A 566 m³/m (20,000 acfm) permanent installation demonstration system, consisting of the Air Pollution Systems' High Intensity Ionizer and a variable throat venturi scrubber (called the Scrub-E) has been installed on a magnesium recovery furnace. The furnace produces submicron fume particles of MgO, MgCl₂, and ZrCl₄. The system is designed to demonstrate the effectiveness of the High Intensity Ionizer versus high venturi pressure drop on the furnace emissions. The High Intensity Ionizer array operates stably at field strengths of 10–15 kV/cm and at velocities in excess of 18 m/sec (60 fps) while maintaining high charging efficiencies. The report covers the system design, technology, applications, and project developments. An Environmental Protection Agency proposed charged droplet Scrub-E is also discussed covering the design, technology, and proposed demonstration program.