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231.
Bai S Srikantaswamy S Krishnanandan V Naik OP 《Environmental monitoring and assessment》2012,184(1):239-249
Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献
232.
Concentration of heavy metals (Cd, Ni, Zn, Fe, Cu, Mn, Pb, Cr, Hg and As) in the waters of River Yamuna and in the soil of
agricultural fields along its course in Delhi are reported from 13 sites, spread through the Delhi stretch of Yamuna, starting
from the Wazirabad barrage till the Okhla barrage. Varying concentration of heavy metals was found. Peaks were observed in
samples collected downstream of Wazirabad and Okhla barrage, indicating the anthropogenic nature of the contamination. The
Wazirabad section of the river receives wastewater from Najafgarh and its supplementary drains, whereas the Shahdara drain
releases its pollution load upstream of the Okhla barrage. Average heavy metal concentration at different locations in the
river water varied in the order of Fe>Cr>Mn>Zn>Pb>Cu>Ni>Hg>As>Cd. The river basin soil shows higher level of contamination
with lesser variation than the water samples among sampling locations, thereby suggesting deposition over long periods of
time through the processes of adsorption and absorption. The average heavy metal concentration at different locations in soil
varied in the order of Fe>Mn>Zn>Cr>Pb>Ni>Hg>Cu>As>Cd. 相似文献
233.
de-la-Ossa-Carretero JA Del-Pilar-Ruso Y Giménez-Casalduero F Sánchez-Lizaso JL 《Environmental monitoring and assessment》2012,184(4):2133-2149
Physicochemical characteristics of sediment and benthic communities were studied in the proximity of seven sewage outfalls
with differences in flow and wastewater treatment in the Western Mediterranean Sea. Redox potential was the only abiotic parameter
which showed a pattern related with distance to outfalls, whereas granulometry, percentage of organic matter, metal concentrations
or pH did not show changes related with outfall presence. Benthic community analysis proved to be the most suitable monitoring
tool. The results showed that the highest impacted stations corresponded with those closest to outfall with the highest flow
and only pre-treatment, whilst a decrease of this tendency was detected in the locations where secondary treatment takes place.
Meta-analysis showed a decrease of amphipods and tanaids abundance as well as redox potential, as the indicators with the
clearest response to sewage presence. 相似文献
234.
The chemical forms and ecological risk of As were characterized in the sediment of the Daliao River System (DRS), which has
been affected by long-term intensive industrial, urban, and agricultural activities. Twenty-seven samples of surface sediment
were collected and analyzed for total As content and that of its chemical forms. The results indicated that the average total
As content in the sediment was 9.83 mg kg − 1 but that the levels ranged from 1.57 to 83.09 mg kg − 1. At the sites near cities, mining sites, and the estuary of the DRS, it is likely that adverse effects on aquatic organisms
occur, due to As levels in the sediment that are often higher than the threshold effect level and occasionally higher than
the probable effect level. A selectively sequential extraction indicated that the majority of As in the sediment was bound
to Fe oxides (62.1%), with moderate proportions of residual As (19.8%), specifically adsorbed As (17.9%), and a low proportion
of non-specifically adsorbed As (1.1%). In addition, the content of Fe in the sediment was positively and significantly correlated
with the contents of amorphous and crystalline Fe oxide-bound As, confirming the crucial role of Fe oxides in immobilizing
high amounts of As in superficial environments. The average molar ratio of As to Fe was 1.18 × 10 − 4 in the surface sediment of the DRS, similar to that of natural Fe oxides, but much lower than that of synthesized Schwertmannite.
Therefore, the release of As under reduced and low pH conditions can cause serious problems for water resources and for living
organisms. 相似文献
235.
The analysis of heavy metals is very important for assessing the feasibility of the agricultural utilization for the municipal
sludge. In this paper, a four-step sequential extraction method was applied to extract heavy metals (Cu, Zn, Mn, Cr, and Ni)
in municipal sludges from seven individual wastewater treatment plants located in Jilin and Heilongjiang Province, China,
for estimating the mobility and bioavailability of the metal ions in the agricultural application. The total concentrations
of heavy metals and their chemical fractions after the sequential extraction were determined. Principal component analysis
(PCA) was applied to analyze the relations of heavy metals fractions in the municipal sludges. Experimental results indicated
that the total concentrations of Cu, Zn, Cr, and Ni in all sludge samples were below the threshold values set out by the Chinese
legislation (GB18918-2002). Specially, Zn had a high bioavailability and mobility, Cu and Cr had potential bioavailability,
while Mn mainly existed in the residual fraction of municipal sludge. On the other hand, Ni had different mobility in different
municipal sludge. PCA results were confirmed by the environmental behavior of heavy metals. 相似文献
236.
Karakaya and Sultansuyu Dam Lakes, located in the eastern part of Turkey, are important water sources, both for irrigation
and fishery. The main goal of the study was to investigate water qualities of dam lakes using a set of biomarkers in the fish
Cyprinus carpio. For this aim, field sample and laboratory-acclimated fish were compared to identify changes in selected biomarkers. The
activities of ethoxyresorufin-O-deethylase, glutathione S-transferase, glutathione reductase, and carboxylesterase were determined in liver samples. Also, plasma and liver lactate
dehydrogenase, aspartate aminotransferase, and alanine aminotransferase activities were assayed. Brain acetylcholinesterase
and carboxylesterase activities were also determined. The hepatosomatic index and condition factors were calculated. Plasma
vitellogenin assays were evaluated for the presence of xenoestrogen. Physicochemical values of water samples showed the existence
of eutrophication risk, and also, some chemicals in both lakes were determined to be over tolerable limits. The comparisons
of samples from both dam lake and laboratory-acclimated fish showed that the lakes may be at risk of pollution by some xenobiotics,
namely xenoestrogens and acetylcholinesterase-inhibiting agents. 相似文献
237.
Majid Soleimani Lope G. Tabil Ike Oguocha Jimmy Fung 《Journal of Polymers and the Environment》2018,26(2):532-542
The objective of this work was to improve the impact and thermal properties of polylactic acid (PLA)-based biocomposite by appropriate application of cellulosic fiber and a bioelastomer. Biocomposites formulations with fiber contents of up to 20% in combination with a bioelastomer were extrusion-compounded in a twin-screw extruder followed by molding in an injection molding system. Fibers used in the formulations included three types of cellulosic fiber; namely, raw fiber from oat hull biomass (RF), hydrolysis byproduct (ATF) which was the solid fraction obtained from an acid-catalyzed hydrolysis of RF, and delignified fibers (AD30, AD65, AD100) which were the products of delignification of ATF. Formulated biocomposites were characterized for thermal (glass transition and melting temperatures, and enthalpy of melting) and physico-mechanical (tensile and bending strengths, stiffness, impact energy, and water absorption) properties. Among all types of biofibers, RF resulted in poor properties in the biocomposites due to the high hemicellulose content in the structure. On the other hand, the ratio of lignin to cellulose (in the absence of hemicellulose) in the modified fibers did not significantly affect the physico-mechanical and thermal properties of the biocomposites. The elastomer applied in the formulations improved the impact energy, thermal properties, and elongation at break of the composites. However, it adversely affected the strength and water resistance of biocomposites, especially in the presence of hemicellulose. The results indicated that, depending on the application, a wide range of PLA green composites with different physico-mechanical properties can be achieved. 相似文献
238.
Mostafa Yusefi Mohammad Khalid Faizah Md Yasin Luqman Chuah Abdullah Mohammad Reza Ketabchi Rashmi Walvekar 《Journal of Polymers and the Environment》2018,26(2):474-486
In this work, performance of cow dung (CD) reinforced poly(lactic acid) (PLA) biocomposites was investigated for the potential use in load bearing application. CD of average 4 mm size was blended with PLA at different CD ratios (0–50 wt%) and their effects on the biocomposite properties were studied. The results showed an improvement in the flexural properties, while the tensile and impact strength dropped by 20 and 28% with the addition of 50% CD. The decline in the tensile and impact strength was due to micro-cracking and voids formation at higher CD content. Also, the incorporation of CD slightly decreased the thermal stability of the biocomposite. However, dynamic mechanical properties of the biocomposites generally improved. SEM analysis of tensile and impact fractured surfaces indicated that the CD had a reasonable adhesion with matrix. Moreover, the SEM micrographs of soil burial studies showed an accelerated degradation of higher CD wt% biocomposites. 相似文献
239.
Warangkhana Phromma Rathanawan Magaraphan 《Journal of Polymers and the Environment》2018,26(6):2268-2280
Natural rubber (NR) with polycaprolactone (PCL) core–shell (NR-ad-PCL), synthesized by admicellar polymerization, was acted as an impact modifier for poly(lactic acid) (PLA). PLA and NR-ad-PCL were melt-blended using a co-rotating twin screw extruder. The morphology of PLA/NR-ad-PCL blends showed good adhesion as smooth boundary around rubber particles and PLA matrix. Only 5 wt% of rubber phase, NR-ad-PCL was more effective than NR to enhance toughness and mechanical properties of PLA. The contents of the NR-ad-PCL were varied from 5, 10, 15 and 20 wt%. From thermal results, the incorporation of the NR-ad-PCL decreased the glass transition temperature and slightly increased degree of crystallinity of PLA. Mechanical properties of the PLA/NR-ad-PCL blends were investigated by dynamic mechanical analyser, pendulum impact tester and universal testing machine for tension and flexural properties. The increasing NR-ad-PCL contents led to decreasing Young’s and storage moduli but increasing loss modulus. Impact strength and elongation at break of the PLA/NR-ad-PCL blends increased with increasing NR-ad-PCL content up to 15 wt% where the maximum impact strength was about three times higher than that of pure PLA and the elongation at break increased to 79%. 相似文献
240.
Ernestine Alabaraoye Mathew Achilonu Robert Hester 《Journal of Polymers and the Environment》2018,26(6):2207-2218
Chitin has been produced from different sea waste sources including, molluscs (mussel and oyster shell), crustacean (prawn and crab) and fish scale (pang and silver scales) using deproteinization and demineralization as chemical methods. The conditions of chemical extraction process determine the quality of chitin. The obtained results revealed that, about 1 and 10% HCl and NaOH were adequate concentrations for deproteinization and demineralization process respectively. Chitin from oyster and crab shell waste had the highest yield of 69.65 and 60.00% while prawn, mussel shell, pang and silver scales had the lowest yield of 40.89, 35.03, 35.07 and 31.11% respectively. Chitin solubility is controlled by the quantity of protonated acetyl groups within the polymeric chain of the chitin backbone, thus on the percentage of acetylated and non-acetylated d-glucos-acetamide unit. Good solubility results were obtained in mussel, oyster and crab shells respectively. The chitin molecular weight characteristics and activity are controlled by the degree of acetylation (DA) and the distribution of acetyl group extending in the polymer chain. DA is determined by acid-base titration methods and molecular weight determined by Brookfield viscometry. Both methods are found to be effective. 相似文献