改进的灰色关联分析在滑坡危险性评价中的应用——以广东省滑坡危险性评价为例

利用改进的灰色关联分析方法,采用“中心化”无量纲的处理方法,对广东滑坡灾害危险性的影响因素进行灰色关联度分析。通过地形地貌条件、地层岩性特征、地质构造特征、岩土体结构特性、水文地质条件、植被覆盖率、降雨分布、地震、人类经济工程活动等9个评价因素与滑坡危险性的关联度计算,得出各影响因素与滑坡危险性评价的关系,具有一定的客观性、科学性和合理性。     

Catastrophe theory to assess water security and adaptation strategy in the context of environmental change

Economic development, population growth, urbanization and climate change have led to an increasing water shortage across the globe. Ensuring water security under changing environment will be the greatest challenge for water resources managers in near future. In this paper, catastrophe theory based multi-criteria evaluation model has been proposed to assess water security under different management strategies to recommend the best water management strategy to achieve water security in the context of global environmental change. The assessment model involves future scenarios of climate change, population growth and economic development. Total 16 indicators related to climate, socio-economy and water availability and consumption have been proposed to measure water security under three management strategies viz. business-as-usual, water demand management and water supply management. The model has been applied to Yulin city of North West China to assess water security as well as to identify the water management strategy under changing environment. The results show that under business-as-usual situation the water shortage rate will reach up to 44 % by the year 2020 and up to 70 % by the year 2030 in Yulin. Water supply is required to increase by 41 % to meet the water demand under supply management strategy which is beyond the safe baseline rate. The study reveals that water demand management can reduce the gap between water supply and demand to a reasonable amount and therefore, can be considered as the most effective approach for adapting with environment change.     

附着硅藻指数在河流水质监测中的适用性技术研究

对广西龙江和柳江中段共18个样点进行了附着硅藻的采样调查,并采用相关分析法、主成分分析法、最优分割分类法、箱须图法、逐步判别分析法和双向指示种分类法等数学方法研究分析了16个硅藻指数在龙江与柳江中段水质监测中的适用性.结果表明,3次4组不同水质类别中,IPS(Specific Pollution Sensitivity Index)和TDI(Trophic Diatom Index)指数与样点的箱须图都表现出合理的趋势,而且IPS和TDI间、及与环境因子及其他硅藻指数间的相关性显著.表明IPS和TDI适合进行龙江与柳江中段的水质生物监测评价,而本文提出的硅藻指数适用性技术也具有一定的推广价值.     

随机介质理论下隧道围岩渐进破坏过程数值实验研究

将强度折减法引入到隧道围岩安全评价中,结合"浅埋暗挖快速施工双线小间距隧道、盾构下穿立交结构隧道和结构面含有节理、不规则裂隙的山体公路隧道"等工程实例,借助材料真实破坏分析软件RFPA-2D,建立每个强度折减系数下的有限元模型。模型采用了黏弹性人工边界来消除边界条件对计算精度的影响,并借助随机介质理论实现了围岩细观结构单元的非均值性和随机分布的缺陷,揭示了不同工况下隧道围岩的动态渐进破坏过程、基元相变损伤演变机理和岩体结构面破坏特征,认为隧道围岩的宏观破坏是由岩体非线性材料细观单元的非均值性造成的,计算结果借助不同折减步中裂纹发展趋势和单元破坏的数量判断隧道围岩是否失稳破坏,并计算出具有安全储备意义上的安全系数。同时,结合ABAQUS和RFPA-2D两种不同有限元模型,对比分析了随机介质理论和连续介质理论结合强度折减法在隧道围岩稳定性评价中的差异。     

Structure and function of rhizosphere and non-rhizosphere soil microbial community respond differently to elevated ozone in field-planted wheat

To assess the responses of the soil microbial community to chronic ozone (O₃), wheat seedlings (Triticum aestivum Linn.) were planted in the field and exposed to elevated O₃ (eO₃) concentration. Three treatments were employed: (1) Control treatment (CK), AOT40 = 0; (2) O₃-1, AOT40 = 1.59 ppm•h; (3) O₃-2, AOT40 = 9.17 ppm•h. Soil samples were collected for the assessment of microbial biomass C, community-level physiological profiles (CLPPs), and phospholipid fatty acids (PLFAs). EO₃ concentration significantly reduced soil microbial carbon and changed microbial CLPPs in rhizosphere soil, but not in non-rhizosphere soil. The results of the PLFAs showed that eO₃ concentrations had significant effects on soil community structure in both rhizosphere and non-rhizosphere soils. The relative abundances of fungal and actinomycetous indicator PLFAs decreased in both rhizosphere and non-rhizosphere soils, while those of bacterial PLFAs increased. Thus the results proved that eO₃ concentration significantly changed the soil microbial community function and composition, which would influence the soil nutrient supply and carbon dynamics under O₃ exposure.     

Heterogeneous oxidation of SO2 by O3-aged black carbon and its dithiothreitol oxidative potential

Ozone (O₃) is an important atmospheric oxidant. Black carbon (BC) particles released into the atmosphere undergo an aging process via O₃ oxidation. O₃-aged BC particles may change their uptake ability toward trace reducing gases such as SO₂ in the atmosphere, leading to different environmental and health effects. In this paper, the heterogeneous reaction process between O₃-aged BC and SO₂ was explored via in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Combined with ion chromatography (IC), DRIFTS was used to qualitatively and quantitatively analyze the sulfate product. The results showed that O₃-aged BC had stronger SO₂ oxidation ability than fresh BC, and the reactive species/sites generated on the surface had an important role in the oxidation of SO₂. Relative humidity or 254 nm UV (ultraviolet) light illumination enhanced the oxidation uptake of SO₂ on O₃-aged BC. The oxidation potentials of the BC particles were detected via dithiothreitol (DTT) assay. The DTT activity over BC was decreased in the process of SO₂ reduction, with the consumption of oxidative active sites.     

龙江底栖硅藻群落特征及与环境因子的关系

2013年9月份龙江流域设20个采样点,共鉴定出硅藻30属163种。硅藻群落特征分析表明,上游河段的硅藻相对密度比下游河段的大,水质相对较好,硅藻种类数的变化与河流水质的变化没表现出明显的规律性。RDA分析表明8个环境因子共解释了硅藻群落变异的51.3%,并筛选出溶解氧、温度、电导率和海拔为影响硅藻群落变异和空间分布的显著因子,能解释硅藻群落结构变异的30.9%,占总环境因子解释量的60.23%。硅藻相对密度、硅藻种类数与环境因子的相关分析、聚类分析和回归分析表明,硅藻种类数与环境因子间不存在明显的相关关系,而硅藻相对密度则与海拔存在显著的相关关系。     

富里酸在土壤环境中的吸附研究

富里酸在土壤中的吸附影响着土壤肥力和土壤环境,本文比较了不同pH、离子强度下,富里酸对土壤环境吸附性能的影响,探究了高岭土对富里酸的吸附条件.结果表明吸附在高岭土上的富里酸可以改变高岭土的结构,与高岭土空白样相比,复合体的结构更加分散.高岭土的不同组分对富里酸的吸附容量不同,对富里酸不同官能团的亲和性也存在明显差异.富里酸在高岭土上的吸附及有机污染物在土壤环境中的吸附作用,与烷基、芳香基团呈正相关.     

基于致灾因子指标体系的海冰灾害风险评估和区划方法

中国是世界上受海冰危害严重的国家之一,历史上曾发生过多次严重海冰灾害,造成重大损失。根据我国结冰海区海冰灾害风险的自然过程、社会经济状况和成灾机制,综合考虑致灾因子危险性、承灾体分类、分布及脆弱性以及防灾减灾能力等因素,对海冰灾害发生的可能性及其不确定性等进行综合分析,提出了开展海冰灾害风险评估和区划的理论依据,同时给出了利用致灾因子指标体系对海冰灾害风险进行评估和区划的具体方法。     

Dosing low-level ferrous iron in coagulation enhances the removal of micropollutants, chlorite and chlorate during advanced water treatment

Drinking water utilities are interested in upgrading their treatment facilities to enhance micropollutant removal and byproduct control. Pre-oxidation by chlorine dioxide (ClO₂) followed by coagulation-flocculation-sedimentation and advanced oxidation processes (AOPs) is one of the promising solutions. However, the chlorite (ClO₂^–) formed from the ClO₂ pre-oxidation stage cannot be removed by the conventional coagulation process using aluminum sulfate. ClO₂^– negatively affects the post-UV/chlorine process due to its strong radical scavenging effect, and it also enhances the formation of chlorate (ClO₃^–). In this study, dosing micromolar-level ferrous iron (Fe(II)) into aluminum-based coagulants was proposed to eliminate the ClO₂^– generated from ClO₂ pre-oxidation and benefit the post-UV/chlorine process in radical production and ClO₃^– reduction. Results showed that the addition of 52.1-µmol/L FeSO₄ effectively eliminated the ClO₂^– generated from the pre-oxidation using 1.0 mg/L (14.8 µmol/L) of ClO₂. Reduction of ClO₂^– increased the degradation rate constant of a model micropollutant (carbamazepine) by 55.0% in the post-UV/chlorine process. The enhanced degradation was verified to be attributed to the increased steady-state concentrations of HO^· and ClO^· by Fe(II) addition. Moreover, Fe(II) addition also decreased the ClO₃^– formation by 53.8% in the UV/chlorine process and its impact on the formation of chloro-organic byproducts was rather minor. The findings demonstrated a promising strategy to improve the drinking water quality and safety by adding low-level Fe(II) in coagulation in an advanced drinking water treatment train.