Emission-based static traffic assignment models

Tailpipe emissions in the road transportation system are a major source of air pollution and greenhouse gases. One of the possible approaches is to influence drivers’ routing decisions such that the emissions and fuel consumption is minimized. In order to evaluate such condition, we develop environmental traffic assignment (E-TA) models based on user equilibrium (UE) and system optimal (SO) behavioral principles. Extending the traditional travel time-based UE and SO principles to E-TA is not straightforward because, unlike travel time, the rate of emissions increases with the increase in vehicle speed beyond a certain point. The results of various TA models show a network-wide traffic control strategy in which vehicles are routed according to SO-based E-TA, can reduce system-wide emissions. However, a system in which drivers make routing decisions to minimize their own emissions (E-UE system) results in a paradoxical situation of increased individual as well as system-wide emissions.     

Assessment of drinking water quality using ICP-MS and microbiological methods in the Bholakpur area,Hyderabad, India

A total of 16 people died and over 500 people were hospitalized due to diarrhoeal illness in the Bholakpur area of Hyderabad, India on 6th May 2009. A study was conducted with immediate effect to evaluate the quality of municipal tap water of the Bholakpur locality. The study consists of the determination of physico-chemical properties, trace metals, heavy metals, rare earth elements and microbiological quality of drinking water. The data showed the variation of the investigated parameters in samples as follows: pH 7.14 to 8.72, EC 455 to 769 μS/cm, TDS 303.51 to 515.23 ppm and DO 1.01 to 6.83 mg/L which are within WHO guidelines for drinking water quality. The water samples were analyzed for 27 elements (Li, Be, B, Na, Mg, Al, Si, K, Ca, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Ba and Pb) using inductively coupled plasma-mass spectrometry (ICP-MS). The concentrations of Fe (0.12 to 1.13 mg/L), Pb (0.01 to 0.07 mg/L), Cu (0.01 to 0.19 mg/L), Ni (0.01 to 0.15 mg/L), Al (0.16 to 0.49 mg/L), and Na (38.36 to 68.69 mg/L) were obtained, which exceed the permissible limits of the World Health Organization (WHO) for drinking water quality guidelines. The remaining elements were within the permissible limits. The microbiological quality of water was tested using standard plate count, membrane filtration technique, thermotolerant coliform (TTC), and most probable number (MPN) methods. The total heterotrophic bacteria ranged from 1.0 × 10⁵ to 18 × 10⁷ cfu/ml. Total viable bacteria in all the water samples were found to be too numerable to count and total number of coliform bacteria in all water samples were found to be of order of 1,100 to >2,400 MPN index/100 ml. TTC tested positive for coliform bacteria at 44.2°C. All the water samples of the study area exceeded the permissible counts of WHO and that (zero and minimal counts) of the control site (National Geophysical Research Institute) water samples. Excessively high colony numbers indicate that the water is highly contaminated with microorganisms and is hazardous for drinking purposes. Bacteriological pollution of drinking water supplies caused diarrhoeal illness in Bholakpur, which is due to the infiltration of contaminated water (sewage) through cross connection, leakage points, and back siphoning.     

Green synthesis of symmetrical N, N′-disubstituted thiourea derivatives in water using solar energy

Thioureas are of importance in medicinal chemistry due to their biological activities such as antituberculosis, anti-HIV, analgesic, anti-inflammatory, antimicrobial, antiarrhythmic, fungicide, herbicides, rodenticides and as phenoloxidase enzymatic inhibitors. Treatment of primary and secondary amines with thiophosgene is the common method of making symmetrical disubstituted thioureas. However, this method is hazardous due to the toxic properties of thiophosgene. Here, we report a green, operationally simple approach for the synthesis of 1, 3-disubstituted thiourea derivatives in moderate to excellent yields of 57–99 %. We use primary amines and CS₂ in water without any catalyst and solar thermal energy. This method is more environmentally benign and energy-saving compared with previously reported methods.     

Modelling and analysis of recruitment distributions

Recruitment data for 18 marine fish stocks are smoothed using 10 parametric families of probability distributions. Comparative fit of the 10 families is assessed by means of the maximized log-likelihood. Results indicate that the gamma distribution provides an overall good fit in the right-hand tail of the data, but that some adjustment to the gamma distribution is called for in the left-hand tail. Weight functions and weighted distributions are suggested as one means of achieving the needed adjustment.     

Transport of Pollutant in Open Channel with Short Waves

This study examines the effect of short period water waves on the longitudinal mixing of pollutants in open channel flow. These waves create orbital motions and therefore increase the magnitude of the dispersion coefficient. Experiments are conducted for non-wavy and wavy flow. The values of the longitudinal dispersion coefficients are determined by applying the method of least squares to the measured solute concentrations at various time intervals. For non-wavy flow, the measured values of longitudinal dispersion coefficient match closely with those computed from the empirical equation given by Seo [1]. For wavy flow, a new factor called the wave parameter (a/TU _*, a=wave amplitude, T=wave period, U _*=shear velocity) is found important and a nonlinear multiple regression analysis is used to derive a new expression for the wave induced longitudinal dispersion coefficient (WILDC). An uncertainty analysis is conducted as per IS Code 5168 and the confidence interval is determined. Linear water wave theory is applied to modify the existing expression of the longitudinal dispersion coefficient of Seo [1] by including the effect of short waves. A mathematical model for WILDC is then developed. Comparative study between wavy and non-wavy flow cases has been conducted. The results clearly show an increase in the magnitude of longitudinal dispersion coefficient in the presence of waves.     

PULSE,progressive upper level set scan statistic for geospatial hotspot detection

This paper presents a scan statistic, progressive upper level set (PULSE) scan statistic, for geospatial hotspot detection and its software implementation. Like ULS, the PULSE scan statistic is based on the arbitrarily shaped scan window and can be adapted for a network setting. PULSE is a refinement of the upper level set (ULS) scan statistic. Like some other likelihood based scanning devices, the ULS scan statistic identifies maximum likelihood estimate (MLE) zones that tend to be ‘stringy’ and sprawling. Its search path increases possibility of inclusion of extraneous cells in its MLE zones and, to a smaller extent, of exclusion of cells that belong to a true hotspot from its MLE zone. The PULSE scan statistic achieves improvement over the ULS scan statistic in two ways. First, it begins its search for a most likely zone with a large population of candidate zones obtained by modifying the ULS tree structure and continues its search using a genetic algorithm. Secondly, to reduce chances of generating an MLE that is excessively stringy and that includes extraneous cells in the MLE zone, PULSE uses cardinality and compactness of zones along with their likelihoods as the fitness function in the genetic algorithm and uses several pertinent criteria including evenness of intra-zone cellular response ratios to determine the MLE zone. To reduce computation, Gumbel distribution of extreme values is used to determine the p-value of the MLE zone. Better results come at the cost of increased processing time. An evaluative performance study is presented.     

Next-generation sequencing in the biodiversity conservation of endangered medicinal plants

Environmental Science and Pollution Research - Medicinal plants have been used as traditional herbal medicines in the treatment of various types of diseases. However, the increased demand for these...     

Physicochemical and Antibacterial Evaluation of Poly (Vinyl Alcohol)/Guar Gum/Silver Nanocomposite Films for Food Packaging Applications

Journal of Polymers and the Environment - In this study, we prepared Poly (vinyl alcohol) (PVA)/Guar gum (GG) based nanocomposite films with a different weight ratio of silver nanoparticles (AgNPs)...