Atmospheric corrosion of carbon steel in acid rain by accelerated weathering test

In this work, the accelerated weathering test of immersion-wet-dry combined cycles was carried ont. The artificial acid rain of NaHSO3-(NH4)2SO4-H2SO4 solution system was selected as immersion solution. Acidity of artificial acid rain affected corrossion weight loss of carbon steel, and pH 4.1 was found to be a critical point. Anodic reaction resistance of the samples during accelerated weathering test increased with exposed time by electrochemical measurement.     

Influence of acid deposition on atmospheric corrosion of zinc

Site exposure tests both open and sheltered have been carried out in acid deposition area in Southwest China. Results from six sites show that acid deposition exerts a great influence on atmospheric corrosion of Zn, and it is more serious in wet condition. Basically, Zn corrosion is directly proportional to time of exposure. While SO2 is the main pollutant of the atmosphere environment, Zn corrosion has a linear relationship to SO2 depositing rate and a hyperbolic to rain pH value.Observations by SEM, EDAX and X-ray diffraction show that under sheltered exposure condition, the corrosion products of Zn in heavy acid deposition area principally are sulphates.Based on the corrosion rates measured, the working life of galvanized steel can be predicated.     

长期定位施肥对土壤磷、钾素动态变化的影响

23年定位施肥试验的结果表明，不施肥和单施氮肥的土壤，其有效磷质量分数迅速下降，前3年比播前降低约50％，自第7年开始比播前降低2／3左右，降至4-5μg／g之后处于稳定状态。土壤全磷质量分数始终保持在0．40-0．50g／kg的水平，有机磷略有增加。施有机肥以及有机肥与氮肥配施的土壤，其有效磷和有机磷质量分数增加显著。单施氮肥的土壤，其速效钾、缓效钾质量分数均降低，全钾质量分数变化不明显。在每年每公顷单施含钾150．0kg、300．0kg的有机肥或与138kg、276kg氮素配施的土壤中，以单施含钾300．0kg的有机肥的土壤的钾素盈余量最多，并随配施氮量的增加而盈余量减少。试验23年后的土壤，其钾素盈余量与土壤速效钾、缓效钾质量分数均有极显著的相关性，而与全钾质量分数的相关性小大。     

多维地震作用下偏心结构动力反应的Simulink仿真分析

理论研究与震害经验表明,地震时结构会产生不可忽略的平动与扭转耦合的空间振动,因此,对结构进行平—扭耦联反应分析具有重要意义。本文首先建立多维地震动作用下偏心结构的空间力学模型和动力方程,并编制相应的MAT LAB程序,然后将动力方程所代表的动力学系统用控制理论中的状态空间法予以描述,根据其状态方程在SIMULINK环境下建立仿真分析模型,从而求解动力方程。对一双向水平地震作用下的6层偏心框架结构进行平—扭耦联反应数值仿真分析,得出了一些有益的结论。     

保护性耕作对土壤有机碳、氮储量的影响

以辽宁彰武县保护性耕作示范推广基地土壤为研究对象,通过实地调查和取样分析,对比研究了传统犁耕和6年免耕秸秆覆盖条件下的土壤有机碳、氮储量,为广泛评价保护性耕作的土壤碳、氮截获功能和合理选择农业耕作方式提供科学依据。研究结果表明,与犁耕相比,免耕覆盖不同程度地提高了0-5cm和5～15cm土层的有机碳、氮储量,对15cm以下土层没有影响,从而增加了0～100em土体总的有机碳、氮储量,证明了免耕覆盖的土壤碳、氮截获功能,年均截获率分别为1．37Mg·hm-2和0．84Mg·hm-2有机碳、氮在犁耕土壤0～30cm剖面的垂直分布较为均匀,免耕覆盖后则发生明显的分层,产生表聚现象。     

Study on the distribution characteristics and ecological risk of heavy metal elements in coal gangue taken from 25 mining areas of China

Environmental Science and Pollution Research - The long-term, high-yield production of coal has resulted in the large-scale accumulation of coal gangue on the ground surface, which causes serious...