全文获取类型
收费全文 | 157篇 |
免费 | 3篇 |
专业分类
安全科学 | 3篇 |
废物处理 | 12篇 |
环保管理 | 4篇 |
综合类 | 3篇 |
基础理论 | 26篇 |
污染及防治 | 81篇 |
评价与监测 | 16篇 |
社会与环境 | 15篇 |
出版年
2023年 | 3篇 |
2022年 | 9篇 |
2021年 | 10篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 10篇 |
2017年 | 8篇 |
2016年 | 7篇 |
2015年 | 8篇 |
2014年 | 6篇 |
2013年 | 7篇 |
2012年 | 9篇 |
2011年 | 16篇 |
2010年 | 9篇 |
2009年 | 11篇 |
2008年 | 13篇 |
2007年 | 10篇 |
2006年 | 1篇 |
2005年 | 6篇 |
2004年 | 1篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 2篇 |
排序方式: 共有160条查询结果,搜索用时 15 毫秒
71.
Following the development of urban and industrial centres petrochemical products have become a widespread class of contaminants. The aim of this study was to investigate the effects of petrochemical contamination in wild populations of mussels (Mytilus galloprovincialis) along the NW Atlantic coast of Portugal by applying antioxidant and energetic metabolism parameters as biomarkers. For that, mussels were collected at five sampling sites presenting different petrochemical contamination levels. To evaluate the mussels' antioxidant status, enzymatic activities of catalase, superoxide dismutase, glutathione peroxidase, glutathione reductase, glutathione S-transferases, as well as glutathione redox status were evaluated in gills and digestive glands of mussels collected from the selected sites. Lipid peroxidation was determined in the same tissues to quantify cellular oxidative damage. Furthermore, to investigate how energetic processes may respond to these contaminants, the activity of NADP(+)-dependent isocitrate dehydrogenase was determined in mussels' digestive glands, and octopine dehydrogenase was determined in mussels' posterior adductor muscle. Furthermore, the concentrations of aliphatic hydrocarbons, unresolved complex mixture and polycyclic aromatic hydrocarbons (PAHs) were quantified in mussels' tissue, and abiotic parameters were quantified in water samples collected at each site. Several biomarkers showed statistically significant differences among sampling sites. The redundancy analysis (RDA) used to perform the integrated analysis of the data showed a clear separation of the sampling sites in three different assemblages, which are in agreement with the PAHs levels found in mussels tissues. In addition, the RDA indicated that some of the selected biomarkers may be influenced by abiotic parameters (e.g. salinity, pH, nitrates and ammonia). The approach selected for this study seems to be suitable for monitoring petrochemical contamination. 相似文献
72.
Biochemical mechanisms of resistance in Daphnia magna exposed to the insecticide fenitrothion 总被引:1,自引:0,他引:1
Resistance to fenitrothion and enzyme activities associated with the toxicity and metabolism of organophosphorus insecticides were measured in three genetically unique Daphnia magna clones collected from rice fields of Delta del Ebro (NE Spain) during the growing season and a lab sensitive clone. The studied clones showed up to sixfold differences in resistance to fenitrothion. The lack of correlation between in vitro sensitivity of acetylcholinesterase (AChE) to fenitrooxon and resistance to fenitrothion indicated that insensitivity of AChE to the most active oxon metabolite was not involved in the observed differences in resistance. Inhibition of mixed- function oxidases (MFOs) by piperonyl butoxide (PBO) increased the tolerance to fenitrothion by almost 20-fold in all clones without altering their relative ranking of resistance. Conversely, when exposed to fenitrooxon, the studied clones showed similar levels of tolerance, thus indicating that clonal differences in the conversion of fenitrothion to fenitrooxon by MFOs were involved in the observed resistance patterns. Despite that resistant clones showed over 1.5 higher activities of carboxilesterase (CbE) than sensitive ones, toxicity tests with 2-(O-cresyl)-4H-1,3,2-benzodioxaphosphorin-2 oxide, which is a specific inhibitor of these enzymes, evidenced that this system only contributed marginally to the observed clonal differences in tolerance. Glutathione-S-transferases activity (GST) varied across clones but not under exposure to fenitrothion, and was only related with tolerance levels in the field clones. In summary, our results indicate that MFO mediated differences on the bio-activation of the phosphorotionate OP pesticide to its active oxon metabolite contributed mostly in explaining the observed moderate levels of resistance, whereas the activities of CbE and GST had only a marginal role. 相似文献
73.
74.
Enchytraeids (Enchytraeus albidus) directly improve the pore structure of the soil and are indirectly involved in regulating the degradation of organic matter. Due to their behavior they are able to avoid unfavorable environmental conditions. Avoidance tests allow a first assessment of toxicity of a contaminated or spiked soil within 48 h, by using the reaction of the enchytraeids as measurement endpoint. In this period, the organisms can choose between the control soil and the test soil. In the tests reported here, enchytraeids were exposed to LUFA 2.2 soil spiked with the following set of toxic substances: copper chloride, zinc chloride, cadmium chloride, phenmedipham, benomyl, carbendazim, dimethoate, atrazine, pentachlorophenol, chlorpyriphos, lindane, TBTO, Linear Alkylbenzene Sulfonates (LAS) and boric acid. Different chemical concentrations were tested. EC50s ranged from 8 mg/kg (Carbendazim) to >1000 mg/kg (e.g. LAS). While the tested heavy metals showed clear dose-response relationships, the effect pattern differed considerably in the tests with organic chemicals, e.g. no avoidance behaviour was observed in LAS, even at very high doses. Here we proposed to standardize the Enchytraeid avoidance test in a way similar to what is currently done for the earthworm and collembolan avoidance tests by the International Standardisation Organisation (ISO). 相似文献
75.
Tisca Juliana F. dos Santos Karin Pessati Tomás B. Zacchi Flávia L. Soares Fabíola S. Oliveira Vanessa A. Bebianno Maria J. A. F. Bainy Afonso C. D. Razzera Guilherme 《Environmental science and pollution research international》2021,28(22):27823-27824
Environmental Science and Pollution Research - A Correction to this paper has been published: https://doi.org/10.1007/s11356-021-13135-x 相似文献
76.
Sandro José de Andrade Joyce Cristale Flávio Soares Silva Guilherme Julião Zocolo Mary R.R. Marchi 《Atmospheric environment (Oxford, England : 1994)》2010,44(24):2913-2919
In Brazil, sugar-cane crops are burned to facilitate harvesting, and this causes environmental pollution from the large amounts of smoke and soot that are released into the atmosphere. The smoke and soot contain numerous organic compounds such as PAHs. In this study, PM10 and PAH concentrations in the air of Araraquara (SE Brazil, with around 200,000 inhabitants and surrounded by sugar-cane plantations) were determined during the harvest and non-harvest seasons. The sampling strategy included two campaigns in each season, with 20 samples per season. PM10 was collected using a Hi-vol sampler with Teflon? – coated glass fiber filters. PM10 ranged from 41 to 181 μg m?3 during the harvest season, and from 12 to 47 μg m?3 during the non-harvest season. The mean total concentration of PAHs was 2.5 ng m?3 (non-harvest season) and 11.6 ng m?3 (harvest season). In all sampling periods, the most abundant polycyclic aromatic hydrocarbons were phenanthrene and fluoranthrene, and the least abundant was anthracene. The cluster analysis of the total PAH concentrations for each day of sampling and the corresponding meteorological data suggested that the atmospheric concentration of PAHs was independent of the differences in the weather between the seasons. For both sampling seasons, the statistical treatment (PCA, Varimax rotation and HCA) indicated the presence of vehicle sources (diesel, gasoline, and natural-gas engines); but for the harvest season, the main source was attributed to sugar-cane burning. The data generated by this study indicated the burning of sugar-cane as the main contributor to the high levels of PAHs detected in samples during the sugar-cane harvest season. 相似文献
77.
Nolasco Maria E. Lemos Viviane A. S. López Gina Soares Sandra A. Feitosa Johnny P. M. Araújo Bruno S. Ayala Alejandro P. de Azevedo Marleane M. F. Santos Francisco E. P. Cavalcante Rivelino M. 《Journal of Polymers and the Environment》2022,30(7):2862-2874
Journal of Polymers and the Environment - The aim of the present study was to perform morphological and chemical characterizations of microplastics (MPs) found in seawater samples from the coast of... 相似文献
78.
Teodoro Filipe Simões Soares Liliane Catone Filgueiras Jefferson Gonçalves de Azevedo Eduardo Ribeiro Patiño-Agudelo Álvaro Javier Adarme Oscar Fernando Herrera da Silva Luis Henrique Mendes Gurgel Leandro Vinícius Alves 《Environmental science and pollution research international》2022,29(18):26425-26448
Environmental Science and Pollution Research - A new one-pot synthesis method optimized by a 23 experimental design was developed to prepare a biosorbent, sugarcane bagasse cellulose succinate... 相似文献
79.
Non-homogeneous Poisson models with a change-point: an application to ozone peaks in Mexico city 总被引:1,自引:0,他引:1
Jorge Alberto Achcar Eliane R. Rodrigues Carlos Daniel Paulino Paulo Soares 《Environmental and Ecological Statistics》2010,17(4):521-541
In this paper, we use some non-homogeneous Poisson models in order to study the behavior of ozone measurements in Mexico City.
We assume that the number of ozone peaks follows a non-homogeneous Poisson process. We consider four types of rate function
for the Poisson process: power law, Musa–Okumoto, Goel–Okumoto, and a generalized Goel–Okumoto rate function. We also assume
that a change-point may or may not be present. The analysis of the problem is performed by using a Bayesian approach via Markov
chain Monte Carlo methods. The best model is chosen using the DIC criterion as well as graphical approach. 相似文献
80.
Summary. Individual variations in pheromone emission patterns were examined in a scarab beetle, Anomala cuprea Hope (Coleoptera: Scarabaeidae), by headspace collection of airborne volatiles from individual females. The amount of pheromone
obtained varied among virgin females, and about 16% of these females (“silent” females) did not emit detectable amount of
pheromone throughout the experimental period. There was no clear temporal pattern of peak pheromone emission for 19 days after
the onset. More than half of the laboratory mated females completely stopped releasing pheromone after the first mating, while
the rest of them continued releasing pheromone, frequently followed by additional mating.
Received 26 March 2001; accepted 28 January 2002. 相似文献