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891.
Markéta Julinová Marie Dvořáčková Jan Kupec Jitka Hubáčková Martina Kopčilová Jaromír Hoffmann Pavol Alexy Anna Nahálková Ida Vašková 《Journal of Polymers and the Environment》2008,16(4):241-249
Improving biodegradability of PVA/starch blends is a reality already documented by a number of works. Admittedly, mechanical
properties of products (for example, tensile strength) are somewhat worse, but suitable composition optimizing or chemical
modifying of starch may eliminate the problem to a large degree. This work is an attempt to find another potential effect
influencing biodegradability, that of technological procedure for producing films from these blends on an extruder. The procedure
with a so-called pre-extrusion step (two-stage) and dry-blend (single-stage) produced blends of slightest differences in achieved
biodegradability (virtually within limits of experimental error) in aerobic (76 vs. 79%) as well as anaerobic breakdown (48
vs. 52%). Conversely, morphological analysis exhibited superior homogeneity of films prepared by the two-stage process; their
tensile strength was also higher. 相似文献
892.
Sławomir Stelmach Ryszard Wasielewski 《Journal of Material Cycles and Waste Management》2008,10(2):110-115
More than 1.1 million tons of municipal and industrial sewage sludge is produced annually in Poland. Most of this sewage sludge
is landfilled or used for recultivation and fertilization of soil. After accession of Poland to the EU, large investments
are planned for wastewater treatment, so it is expected that the amount of sewage sludge produced in Poland will grow in the
near future. It is well known that the combustion of sewage sludge is becoming a more and more popular utilization method
of such waste. Unfortunately, the current situation in Poland makes it impossible to incinerate the sewage sludge because
of a lack of incinerators. One possible solution for Poland is the co-firing of dried sewage sludge in existing coal-fired
utility boilers. This article presents results of initial Polish industrial trials of dried municipal sewage sludge and hard
coal co-combustion in an OP-230 pulverized coal boiler. Such a solution was shown to be technically viable and not to require
changes to the existing technological system. Cocombustion of sewage sludge with coal in power plants seems to be the best
solution for sludge utilization in the near future in Poland. 相似文献
893.
Baked Foams Based on Cassava Starch Coated with Polyvinyl Alcohol with a Higher Degree of Hydrolysis
Fabíola Azanha de Carvalho Ana Paula Bilck Fabio Yamashita Suzana Mali 《Journal of Polymers and the Environment》2018,26(4):1445-1452
The aims of this work were to produce trays based on cassava starch, coated with polyvinyl alcohol (PVA) with a higher degree of hydrolysis (98%), and to study the effects of the coating on the mechanical and water sorption properties of the trays. Two types of PVA were tested: SELVOL? 325 (degree of polymerization?=?1000–1500) and SELVOL? 107 (degree of polymerization?=?350–650). A decrease in the water absorption capacity of 50% was observed when the coated samples were compared with the control sample after 30 min of immersion in water. It was observed in both coated samples a reduction of the initial rate of water adsorption sorption and a decrease in hydrophilicity compared with the control sample. Tensile strength and elongation were increased with application of the coatings. The use of the two types of PVA resulted in materials with similar mechanical and water sorption properties. 相似文献
894.
An investigation on the effect of epoxidation and maleated natural rubber (MNR) on fatigue and rubber-filler interaction properties
of paper sludge filled natural rubber composites was elucidated. Paper sludge loading was varied from 0 to 40 phr and conventional
vulcanisation system was used while compounding was carried out on a laboratory sized two roll mill. Two different types of
natural rubber, SMR L and ENR 50 having 0 and 50 mole% of epoxidation were used in order to investigate the effect of epoxidation
on the composites. Results indicate that, at a fixed filler loading, ENR 50 vulcanizates exhibit higher fatigue life than
SMR L vulcanizates especially at filler loading below 20 phr which might be associated with better rubber-filler interaction.
In the case of composites with the addition of maleated natural rubber (MNR), a higher fatigue life was observed due to presence
of physical and/or chemical linkages, which increases the interfacial adhesion. Scanning electron microscopy (SEM) micrographs
of fatigue fracture surfaces and rubber-filler interaction study supported the observed result on fatigue life. 相似文献
895.
Waste incineration is becoming increasingly necessary to tackle the rapidly rising amounts of municipal solid waste (MSW);
in China many large cities are already surrounded by a girdle of landfills. Still, the not-in-my-backyard (nimby) syndrome
holds strong. This attitude stems from fear of dioxins. These have been associated with incineration (‘dioxin factories’)
and at times also with polyvinylchloride. In this paper this issue is analysed. China should build additional trust in MSW
incineration, following promulgation of stricter emission standards, enforced by stringent controls. 相似文献
896.
K. Abdel Tawab M. M. Magida Sayeda M. Ibrahim 《Journal of Polymers and the Environment》2011,19(2):440-446
Blends of water—soluble polymers based on Poly vinyl alcohol (PVA) and Polyethylene glycol (PEG) have been prepared by the
solution casting technique. The effect of various doses of γ-radiation on the structural properties of PVA/PEG polymer blends
with all its compositions has been investigated. From the visual observation of all the blend compositions, it was found that,
the best compatibility of the blend is up to 40% PVA/60%PEG. The structure–Property behavior of all the prepared blends before
and after γ-irradiation was investigated by IR Spectroscopy, thermogravimetric analysis (TGA), mechanical properties and Scanning
electron microscope (SEM). The gel content and the swelling behavior of the PVA/PEG blends were investigated. It was found
that the gel content increases with increasing irradiation dose and PVA concentration in the blend. Swelling percent increased
as the composition of PEG increased in the blend. The results obtained by FTIR analysis and SEM confirm the existence of possible
interaction between PVA and PEG homopolymers. TGA of PVA/PEG blend, before and after γ-irradiation, showed that the unirradiated
and irradiated PVA/PEG blends are more stable against thermal decomposition than pure PVA. Improvement in tensile mechanical
properties of PVA/PEG blends was occurred. 相似文献
897.
Poly-β-hydroxybuyrate (PHB) is a carbon—energy storage material which is accumulated as intracellular granule in variety of
microorganism under nutrient starved conditions. Solid PHB is a biodegradable thermoplastic polymer and is utilizable in various
ways similar to many conventional plastics. Ralstonia eutropha (Alcaligenes sp.), a gram negative bacteria accumulates PHB as insoluble granules inside the cells when nutrients other than carbon are
limited. In this report effort has been made to analyze PHB granule synthesis inside Alcaligenes sp. NCIM 5085 by transmission electron microscopy and qualitative estimation of PHB was carried out by fourier transform
infrared spectroscopy which provide better precision compared to other conventional techniques previously applied for PHB
determination. Maximum PHB concentration of 2.20 ± 0.40 g/L and cell biomass of 3.42 ± 0.20 g/L was obtained after 48.0 h
of fermentation. Leudking-Piret equation deduced mixed growth associated product formation which varies from earlier reports. 相似文献
898.
Process,Characterization and Biodegradability of Aliphatic Aromatic Polyester/Sisal Fiber Composites
Chin-San Wu 《Journal of Polymers and the Environment》2011,19(3):706-713
The biodegradability, morphology, and mechanical properties of composite materials made of Poly(butylene adipate-co-terephthalate) (PBAT) and sisal fiber (SF) were evaluated. Composites containing acrylic acid-grafted PBAT (PBAT-g-AA/SF)
exhibited noticeably superior mechanical properties due to greater compatibility between the two components. The dispersion
of SF in the PBAT-g-AA matrix was highly homogeneous as a result of ester formation between the carboxyl groups of PBAT-g-AA
and hydroxyl groups in SF and the consequent creation of branched and cross-linked macromolecules. Each composite was subjected
to biodegradation tests in Rhizopus oryzae compost. Morphological observations indicated severe disruption of film structure after 60 days of incubation, and both the
PBAT and the PBAT-g-AA/SF composite films were eventually completely degraded. Water resistance of PBAT-g-AA/SF was higher
than that of PBAT/SF, although weight loss of composites buried in Rhizopus oryzae compost indicated that both were biodegradable, even at high levels of SF substitution. The PBAT-g-AA/SF films were more
biodegradable than those made of PBAT, implying a strong connection between these characteristics and biodegradability. 相似文献
899.
Hisanori Watanabe Hidekichi Yoshino 《Journal of Material Cycles and Waste Management》2011,13(2):113-117
Since hydrogen is a renewable energy source, biohydrogen has been researched in recent years. However, data on hydrogen fermentation
by a leachate from a waste landfill as inoculum are scarce. We investigated hydrogen production using a leachate from an industrial
waste landfill in Kanagawa Prefecture. The results showed no methane gas production, and the leachate was a suitable inoculum
for hydrogen fermentation. The maximum H2 yield was 2.67 mol of H2 per mol of carbohydrate added, obtained at 30°C and an initial pH of 7. The acetate and butyrate production was significant
when the H2 yield was higher. Oxidation–reduction potential analysis of the culture suggested that hydrogen-producing bacteria in the
leachate were facultative anaerobic. Scanning electron microscope observations revealed that the hydrogen-producing bacteria
comprised bacilli about 2 μm in length. 相似文献
900.
Guang Yang Bo Yang Chao Yuan Weiwei Geng Haizhou Li 《Journal of Polymers and the Environment》2011,19(1):146-151
The effects of manufacturing parameters on mechanical properties of medium density fibreboard (MDF) bonded with modified soy
protein-based glue were studied to find an appropriate manufacture technology. Physical properties of MDF made with different
amount of wax emulsion were measured. Results indicated that water repellent had no obvious influence on physical properties
of soy protein-based MDF boards. The fiberboards bonded with soy protein-based glue showed stronger water resistance properties
than those bonded with urea–formaldehyde (UF) resins. Furthermore, the soy protein-based MDF boards had good quality [25.2%
24 h soak thickness swell (TS), 29.9 MPa modulus of rupture (MOR), 3130 MPa modulus of elasticity (MOE)], which met requirements
of Chinese national standard. Practical processing parameters were obtained by orthogonal experiment, i.e., glue content 8.0%,
hot-press temperature 200 °C, and hot-press time 150 s. 相似文献