The Precautionary Principle and the Prevention of Marine Pollution

This paper argues that the environmental changes witnessed in the past decade call for a new approach to environmental management; an approach based not on the principle of the assimilative capacity of the environment but on the precautionary principle, and the emerging preventive environmental paradigm. Uncertainties in scientific knowledge and complexities in ecological systems have presented specific failures of the assimilative capacity methodology. It is argued that these failures are not circumstantial in nature, nor are they the result of misapplication of science by scientists. Rather, they represent inherent problems in the use of the assimilative capacity concept in environmental management. The emergence of the precautionary principle is discussed and a formulation of the principle is presented. In conjunction with the operational approach of clean production, we believe that this principle offers a sounder basis for the prevention of marine pollution in the next decade.     

Kinetic studies of the reaction of hydroxyl radicals with trichloroethylene and tetrachloroethylene

Rate coefficients are reported for the gas-phase reaction of the hydroxyl radical (OH) with C2HCl3 (k(1)) and C2Cl4 (k2) over an extended temperature range at 740+/-10 Torr in a He bath gas. These absolute rate measurements were accomplished using a laser photolysis/laser-induced fluorescence (LP/LIF) technique under slow flow conditions. The simple Arrhenius equation adequately describes the low temperature data for k1 (<650 K) and the entire data set for k2 and is given by (in units of cm3 molecule(-1) s(-1)): k1(291 - 650 K) = (9.73+/-1.15) x 10(-13) exp (158.7+/-44.0)/T, k2(293 - 720 K ) = (1.53+/-0.14) x 10(-12) exp (-688.2+/-67.5)/T. Error limits are 2sigma values. The room temperature values for k1 and k2 are within +/-2sigma of previous data using different techniques. The Arrhenius activation energies for k1 and k2 are a factor of 2-3 lower than previously reported values. The experimental measurements for both k1 and k2 in conjunction with transition state and variation transition state theory calculations infer an OH addition mechanism. The lack of a measurable kinetic isotope effect for k1 is consistent with this mechanism. Insight into the subsequent reactions of the chemically activated intermediate are presented in the form of potential energy diagrams derived from ab initio calculations.     

Small-scale spatial and temporal variance in the concentration of heavy metals in aquatic sediments: a review and some new concepts.

Uncertainty associated with data derived by the analyses of heavy metals in aquatic sediment is due to variance produced in the laboratory (precision), plus 'natural', small-scale spatial variance, (or field variance) at the sampling site. Precision is easily determined and is usually reported in contaminant studies, but field variance is poorly understood and seldom documented. It is important to have an understanding of the field variance because if small-scale spatial variance in the concentration of heavy metals is excessive, regional trends may be limited value. Similarly, if temporal change is large, the results of single synoptic surveys may be questionable and the ability to demonstrate anthropogenic contributions over time will be difficult. However, it is evident from the literature that the information needed to address problems of spatial and temporal variance in the field is beyond the resources of most researchers. Analytical precision of about 5% relative standard deviation (RSD) for heavy metal analysis is typical of a well-managed laboratory. Many studies of small-scale spatial variability made during the current investigation indicate that field variance is related to ambient energy and to the type of sedimentological environment. Total variance (analytical plus field variance) is approximately 10% RSD (mean for a suite of nine trace elements) for depositional parts of estuaries and the marine environment, but increases to about 20-35% RSD for the more dynamic parts of the estuarine environment and the fluvial system. Repeated sampling over periods of up to 7 years undertaken during the present study, indicate a similar order of magnitude for temporal variability in these sedimentological environments. A proposed scheme to provide information on field variance is to undertake small-scale spatial and temporal studies in discrete sedimentological environments in the study area after sediment sampling and characterisation has been completed. The comparatively large proportion of total variance associated with small-scale spatial and temporal variability in the field questions the often excessive cost and effort made in attempting minor reductions in analytical precision in contaminant investigations.     

A comparative analysis of the psychosocial impacts of waste disposal facilities

This paper reports the results of a comparative analysis of the psychosocial impacts of municipal solid waste disposal facilities (both landfills and incinerators) in six communities in the provinces of Ontario and British Columbia, Canada. Telephone surveys were administered to random samples of residents living around each facility between 1990 and 1995 (total n=1203). The results of logistic regression analyses show that type of facility was the strongest predictor of residents' awareness, concern, and actions taken in response to site concerns. Essentially, residents living in close proximity to a landfill had a higher probability of reporting awareness, concern or actions than residents living around an incinerator site. There was little evidence of differences in reactions between Ontario and British Columbia (BC) residents, despite variations in provincial policies on waste disposal. The effects of other predictors, with the exception of involvement in the local community, were not consistent, supporting previous findings that the determinants of facility impacts are outcome‐specific. It is essential that environmental managers take this constellation of factors into account in the operation of existing, or siting of new, facilities.     

Invisible men and women: A status report on race as a variable in organization behavior research

Twenty-five years after passage of the Civil Rights Act, the full integration of racial minorities in the Unites States workforce has still not been achieved. Recent demographic trends indicating that the workforce will be increasingly composed of racial minorities make this a critical issue for academics and practitioners alike. This paper reports on a review of journal research addressing issues of race in organizations. Articles published in twenty major outlets for organization behavior research between 1964 and 1989 were reviewed. Data on the quantity, types and topics of published work are presented. Results indicate that the amount of total published research is small relative to the importance of the topic, that the recent trend is for less rather than more research, that the designs and research questions have been very narrow, and that the topics covered are not representative of the domain of organization behavior. Based upon the findings, some suggestions for future research are offered.     

NEGOTIATION TECHNIQUES TO RESOLVE WESTERN WATER DISPUTES1

ABSTRACT: There is a growing literature on the resolution of natural resources conflicts. Much of it is practical, focusing on guidelines for hands-on negotiation. This literature can be a guide in water conflicts. This is especially true for negotiations over new environmental values such as instream flow. The concepts of competitive, cooperative, and integrative styles of conflict resolution are applied to three cases of water resource bargaining. Lessons for the effective use of these ideas include: break a large number of parties into small working groups, approach value differences in small steps, be cautious in the presence of an attentive public, keep decisions at the local level, and understand the opponent's interests.     

Additive and antagonistic effects of ozone and salinity on the growth, ion contents and gas exchange of five varieties of rice (Oryza sativa L.)

Five varieties of rice (Oryza sativa L.) of varying salinity resistance were grown in non-saline and in saline conditions, with and without a repeated exposure to ozone at a concentration of 83 nmol mol(-1) giving an AOT40 (cumulative exposure above 40 nmol mol(-1)) of 3600 nmol mol(-1) h. Salinity caused a substantial reduction in shoot and root dry weight in all varieties, but the effect on root growth was proportionately less than on shoot growth. Ozone reduced root dry weight but the treatment used did not significantly affect shoot dry weight. Both salinity and ozone reduced plant height. The potassium concentration in the leaves of all five varieties was reduced by salinity, and by ozone in both saline and non-saline treatments. Ozone reduced the sodium concentration in plants grown at 50 mM NaCl but had no effect upon the chloride concentration. Carbon dioxide assimilation, transpiration and stomatal conductance were all reduced by salinity and by ozone and there was close quantitative similarity between the effects of ozone and/or salinity upon assimilation, stomatal conductance and transpiration. There were some antagonistic effects but there were additive effects of salinity and of ozone on root dry weight, plant height, shoot potassium concentration, photosynthesis, transpiration and stomatal conductance. The possible basis of the additive effects of salinity and ozone on gas exchange and mineral uptake are discussed.