Regional Environmental Change - Historical land use may shape landscapes for centuries into the future, but it remains unclear how much land-use legacies affect contemporary land use. Knowing for... 相似文献
Multi-regression analyses have often been used recently to detect trends, in particular in ozone or temperature data sets in the stratosphere. The confidence in detecting trends depends on a number of factors which generate uncertainties. Part of these uncertainties comes from the random variability and these are what is usually considered. They can be statistically estimated from residual deviations between the data and the fitting model. However, interferences between different sources of variability affecting the data set, such as the Quasi-Biennal Oscillation (QBO), volcanic aerosols, solar flux variability and the trend can also be a critical source of errors. This type of error has hitherto not been well quantified. In this work an artificial data series has been generated to carry out such estimates. The sources of errors considered here are: the length of the data series, the dependence on the choice of parameters used in the fitting model and the time evolution of the trend in the data series. Curves provided here, will permit future studies to test the magnitude of the methodological bias expected for a given case, as shown in several real examples. It is found that, if the data series is shorter than a decade, the uncertainties are very large, whatever factors are chosen to identify the source of the variability. However the errors can be limited when dealing with natural variability, if a sufficient number of periods (for periodic forcings) are covered by the analysed dataset. However when analysing the trend, the response to volcanic eruption induces a bias, whatever the length of the data series. The signal to noise ratio is a key factor: doubling the noise increases the period for which data is required in order to obtain an error smaller than 10%, from 1 to 3-4 decades. Moreover, if non-linear trends are superimposed on the data, and if the length of the series is longer than five years, a non-linear function has to be used to estimate trends. When applied to real data series, and when a breakpoint in the series occurs, the study reveals that data extending over 5 years are needed to detect a significant change in the slope of the ozone trends at mid-latitudes. 相似文献
Chemical-looping with oxygen uncoupling (CLOU) is a novel method to burn solid fuels in gas-phase oxygen without the need for an energy intensive air separation unit. The carbon dioxide from the combustion is inherently separated from the rest of the flue gases. CLOU is based on chemical-looping combustion (CLC) and involves three steps in two reactors, one air reactor where a metal oxide captures oxygen from the combustion air (step 1), and a fuel reactor where the metal oxide releases oxygen in the gas-phase (step 2) and where this gas-phase oxygen reacts with a fuel (step 3). In other proposed schemes for using chemical-looping combustion of solid fuels there is a need for an intermediate gasification step of the char with steam or carbon dioxide to form reactive gaseous compounds which then react with the oxygen carrier particles. The gasification of char with H2O and CO2 is inherently slow, resulting in slow overall rates of reaction. This slow gasification is avoided in the proposed process, since there is no intermediate gasification step needed and the char reacts directly with gas-phase oxygen. The process demands an oxygen carrier which has the ability to react with the oxygen in the combustion air in the air reactor but which decomposes to a reduced metal oxide and gas-phase oxygen in the fuel reactor. Three metal oxide systems with suitable thermodynamic properties have been identified, and a thermal analysis has shown that Mn2O3/Mn3O4 and CuO/Cu2O have suitable thermodynamic properties, although Co3O4/CoO may also be a possibility. However, the latter system has the disadvantage of an overall endothermic reaction in the fuel reactor. Results from batch laboratory fluidized bed tests with CuO and a gaseous and solid fuel are presented. The reaction rate of petroleum coke is approximately a factor 50 higher using CLOU in comparison to the reaction rate of the same fuel with an iron-based oxygen carrier in normal CLC. 相似文献
Biomass-based combined heat and power (CHP) generation with different
carbon capture approaches is investigated in this study. Only direct carbon dioxide
(CO2) emissions are considered. The selected processes
are (i) a circulating fluidized bed boiler for wood chips connected to an
extraction/condensation steam cycle CHP plant without carbon capture; (ii) plant
(i), but with post-combustion CO2 capture; (iii) chemical
looping combustion (CLC) of solid biomass connected to the steam cycle CHP plant;
(iv) rotary kiln slow pyrolysis of biomass for biochar soil storage and direct
combustion of volatiles supplying the steam cycle CHP plant with the
CO2 from volatiles combustion escaping to the atmosphere;
(v) case (iv) with additional post-combustion CO2 capture;
and (vi) case (iv) with CLC of volatiles. Reasonable assumptions based on literature
data are taken for the performance effects of the CO2 capture
systems and the six process options are compared. CO2
compression to pipeline pressure is considered. The results show that both bioenergy
with carbon capture and storage (BECCS) and biochar qualify as negative emission
technologies (NETs) and that there is an energy-based performance advantage of BECCS
over biochar because of the unreleased fuel energy in the biochar case. Additional
aspects of biomass fuels (ash content and ash melting behavior) and sustainable soil
management (nutrient cycles) for biomass production should be quantitatively
considered in more detailed future assessments, as there may be certain biomass
fuels, and environmental and economic settings where biochar application to soils is
indicated rather than the full conversion of the biomass to energy and
CO2.
Desert dust is one of the natural contributors to atmospheric particulate matter worldwide. Although particulate pollution has been shown to adversely affect pregnancy, the available evidence on the impact of dust episodes on pregnancy is very scarce. The aim of this study was to evaluate the impact of Saharan dust episodes on pregnancy complications (preeclampsia and bacteriuria) and outcomes (birth weight and gestational age at delivery). This study was based on a cohort of births (N = 3565) that occurred in a major university hospital in Barcelona during 2003-2005. To determine Saharan dust episodes, we developed a two-stage approach based on meteorological evidence of the presence of Saharan dust cloud over the region and unusually high levels of particulate levels on the ground while taking account of traffic sources. The associations between the number of Saharan dust episodes during whole pregnancy as well as each pregnancy trimester and pregnancy complications and outcomes were analysed. There were 152 days (out of 838 days) with Saharan dust cloud over the region from which 45 days were determined as episodic days. We did not observe any statistically significant harmful effect of Saharan dust episodes on our included pregnancy complications and outcomes. However, we observed a small but statistically significant increase in gestational age at delivery in association with the number of episodic days during the third trimester and whole pregnancy (0.8 and 0.5 days respectively). Our findings were not suggestive for any adverse effect of Saharan dust episodes on our included pregnancy complications and outcomes. 相似文献
During a period of heavy ranfall in Essex, Connecticut, on 4th and 5th June 1982, dams in the town along the Fall River were monitored for signs of braks. The observation of water spilling over one of teh dams at 10 p.m. in 5th June ld to the decision to evacuate community rsidents. The notification and avacuation process was conducted by the cvolunteer fire department over a two-hour periopd. At 12.30 a.m 6th June, the upper dam on the Fall River gave way, rsulting in a rapidly moving floodwave which sequentially destroyed four additional dams along the river. Although there was extensive property damage, gthere were no serious injuries and no deaths. The responsible actons of the town officials in monitoring the dams during the period of heavy rainfall permitted the evacuation order to be given in sufficient time to evacuate the residnts. The success of the evacuation was the result of good communication, trust, and co-operation between town officials and the community. 相似文献
Sludge from gullies, on two types of streets with different traffic intensity, was investigated using two recommended EU methods for leachability testing of waste: a two-stage batch test and an up-flow percolation test. The main purpose of this investigation was to gain more knowledge about these leaching test methods to be able to make future decisions on the general applicability of the proposed tests. A number of parameters were determined in the sludge as well as in the eluates obtained from the two leaching tests. These include pH, conductivity, dissolved organic carbon and inorganic ions as chloride ions. A number of metals as Cd, Cr, Cu, Hg, Ni and Zn, were determined by inductive coupled plasmamass spectrometry and organic compounds were screened by high performance liquid chromatography-diode array UV detection and gas chromatography-mass spectrometry. It was found that the concentrations of metals and organic compounds in the sludge were several orders of magnitudes higher than the actual eluate concentrations. For all metals the concentrations were well below the proposed limit values for non-hazardous waste included in the Council decision document 2003/33/EC. Generally, concentrations obtained in batch test were equal or higher than from percolation tests. The repeatability of the percolation and the batch test were in average 28 and 17%, respectively. 相似文献
Many organisms show differences between males and females in growth rate and crucial life history parameters, such as longevity.
Considering this, we may expect levels of toxic metabolic by-products of the respiratory chain, such as reactive oxygen species
(ROS), to vary with age and sex. Here, we analyse ROS levels in female Australian painted dragon lizards (Ctenophorus pictus) and their offspring using fluorescent probes and flow cytometry. Basal level of four ROS species (singlet oxygen, peroxynitrite,
superoxide and H2O2) measured with a combined marker, and superoxide measured specifically, varied significantly among families but not between
the sexes. When blood cells from offspring were chemically encouraged to accelerate the electron transport chain by mitochondrial
uncoupling, net superoxide levels were three times higher in daughters than sons (resulting in levels outside of the normal
ROS range) and varied among mothers depending on offspring sex (significant interaction between maternal identity and offspring
sex). In offspring, there were depressive effects on ROS of size-controlled relative clutch size, which relies directly on
circulating levels of vitellogenin, a confirmed antioxidant in some species. Thus, levels of reactive oxygen species varies
among females, offspring and in relation to reproductive investment in a manner that makes its regulatory processes likely
targets of selection. 相似文献